Intramolecular Ynamide–Benzyne (3+2) Cycloadditions
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- 田渡, 司
- Graduate School of Pharmaceutical Sciences, Kyoto University
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- 加藤, 律希
- Graduate School of Pharmaceutical Sciences, Kyoto University
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- 工藤, 陸
- Graduate School of Pharmaceutical Sciences, Kyoto University
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- 高須, 清誠
- Graduate School of Pharmaceutical Sciences, Kyoto University
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- 瀧川, 紘
- Graduate School of Pharmaceutical Sciences, Kyoto University
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説明
We report herein intramolecular (3+2) cycloaddition reactions between ynamides as three-atom components and benzyne. In these intramolecular reactions, the two-bond formation is realized by exploiting benzyne precursors that contain a chlorosilyl group as a linking functionality. This method thus highlights the ambivalent character of the intermediate indolium ylide, which exhibits both nucleophilic and electrophilic properties at its C2 atom.
収録刊行物
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- Angewandte Chemie International Edition
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Angewandte Chemie International Edition 62 (19), 2023-05-02
Wiley
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詳細情報 詳細情報について
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- CRID
- 1050014481143312384
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- ISSN
- 15213773
- 15213757
- 14337851
- 00448249
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- HANDLE
- 2433/281793
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- PubMed
- 36895082
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- 本文言語コード
- en
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- 資料種別
- journal article
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- データソース種別
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