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This transformation of one aromatic framework into another consists of 1) 4-chlorobutylation of the dibenzothiophene to form the corresponding sulfonium salt, 2) palladium-catalyzed arylative ring opening of the sulfonium salt with a sodium tetraarylborate, 3) an intramolecular S(N)2 reaction to form a teraryl sulfonium salt, and 4) palladium-catalyzed intramolecular C-S/C-H coupling through electrophilic palladation. Symmetrical as well as unsymmetrical triphenylenes of interest were synthesized in a tailor-made fashion in satisfactory overall yields."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1070282810793041025","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000310741448"}],"foaf:name":[{"@language":"en","@value":"Vasu, 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英樹"}]},{"@id":"https://cir.nii.ac.jp/crid/1893962440477553282","@type":"Researcher","foaf:name":[{"@value":"00372566"}]},{"@id":"https://cir.nii.ac.jp/crid/1893962440477553281","@type":"Researcher","foaf:name":[{"@value":"80127886"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"14337851"},{"@type":"EISSN","@value":"15213773"},{"@type":"PISSN","@value":"00448249"},{"@type":"EISSN","@value":"15213757"},{"@type":"NCID","@value":"AA0052535X"}],"prism:publicationName":[{"@language":"en","@value":"Angewandte Chemie"}],"dc:publisher":[{"@value":"wiley"}],"prism:publicationDate":"2015-05-04","prism:volume":"54","prism:number":"24","prism:startingPage":"7162","prism:endingPage":"7166"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","invited":"false","dc:rights":["This is the peer reviewed version of the following article: Vasu, D., Yorimitsu, H. and Osuka, A. (2015), Palladium-Assisted \"Aromatic Metamorphosis\" of Dibenzothiophenes into Triphenylenes. Angew. Chem. Int. Ed., 54: 7162–7166, which has been published in final form at http://dx.doi.org/10.1002/anie.201501992. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.","The full-text file will be made open to the public on 4 May 2016 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.","This is not the published version. Please cite only the published version.","この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201501992"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201501992"},{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fange.201501992"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/ange.201501992"},{"@id":"http://hdl.handle.net/2433/201550"}],"foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=C%5BBOND%5DH%20arylation","dc:title":"C[BOND]H arylation"},{"@id":"https://cir.nii.ac.jp/all?q=C%5BBOND%5DS%20cleavage","dc:title":"C[BOND]S cleavage"},{"@id":"https://cir.nii.ac.jp/all?q=cross-coupling","dc:title":"cross-coupling"},{"@id":"https://cir.nii.ac.jp/all?q=palladium","dc:title":"palladium"},{"@id":"https://cir.nii.ac.jp/all?q=sulfur","dc:title":"sulfur"}],"dcterms:subject":[{"subjectScheme":"Other","notation":[{"@language":"en","@value":"C[BOND]H 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