<i>O</i>-Alkylation of Dihydroxo(tetraarylporphyrinato)phosphorus(V) and Antimony(V) Complexes with Alkyl Halides
書誌事項
- タイトル別名
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- O-Alkylation of Dihydroxo(tetraarylporphyrinato)phosphorus(V) and Antimony(V) Complexes with Alkyl Halides
- 公開日
- 2002-08-01
- 資源種別
- journal article
- 権利情報
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- Copyright (c) 2002 The Chemical Society of Japan
- DOI
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- 10.1246/bcsj.75.1757
- 公開者
- 日本化学会
この論文をさがす
説明
The O-alkylation of dihydroxo(tetraarylporphyrinato)phosphorus(V) complexes with several kinds of alkyl bromide in MeCN in the presence of K2CO3 and 18-crown-6 ether produced dialkoxo(tetraarylporphyrinato)phosphorus(V) complexes in-moderate-good yields. Similar O-alkylation was applied to dihydroxo(tetraarylporphyrinato)antimony(V) complexes. The O-alkylation proceeded by the occurrence of an SN2 attack of the alkoxide anion of the complexes at the carbon substituted with halides.
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 75 (8), 1757-1760, 2002-08-01
日本化学会
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詳細情報 詳細情報について
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- CRID
- 1050282813888649600
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- NII論文ID
- 10010675618
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- NII書誌ID
- AA00580132
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- ISSN
- 13480634
- 00092673
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- HANDLE
- 10228/00006646
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- NDL書誌ID
- 6265124
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- 本文言語コード
- en
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- 資料種別
- journal article
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- データソース種別
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