{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1050283688376192000.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"URI","@value":"https://iwate-u.repo.nii.ac.jp/records/14923"}},{"identifier":{"@type":"DOI","@value":"10.1177/1934578x19878930"}},{"identifier":{"@type":"NAID","@value":"120006820156"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Synthesis of Functionalized Chiral Imidazole Derivatives Based on a Bornane Skeleton Bearing a Sterically Crowded Spirocyclic Substituent at the C-3 Position"}],"dc:language":"en","description":[{"type":"Other","notation":[{"@value":"10-Imidazolylbornane-2-one bearing a sterically crowded spirocyclic substituent at the C-3 position was prepared from d-camphor through the procedure involving the formation of 10-bromobornane-2-thiones or 10-iodobornane-2-thiones and the subsequent conversion into the corresponding 10-imidazolylbornane-2-thiones followed by an efficient oxidative S-O exchange via thione S-oxides."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1070283688376192001","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000408668738"}],"foaf:name":[{"@value":"SHIMADA, Kazuaki"}]},{"@id":"https://cir.nii.ac.jp/crid/1070283688376192002","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000408668739"}],"foaf:name":[{"@value":"FUKUMA, 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Toshinobu"}]}],"publication":{"publicationIdentifier":[{"@type":"ISSN","@value":"1934578X"},{"@type":"ISSN","@value":"15559475"},{"@type":"PISSN","@value":"1934578X"},{"@type":"EISSN","@value":"15559475"}],"prism:publicationName":[{"@value":"Natural Product Communications"}],"dc:publisher":[{"@value":"SAGE"}],"prism:publicationDate":"2019-09-29","prism:volume":"14","prism:number":"9","prism:startingPage":"1","prism:endingPage":"9"},"dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","dc:rights":["©The Author(s) 2019","Creative Commons Non Commercial CC BY-NC: This article is distributed under the terms of the Creative Commons Attribution-NonCommercial 4.0 License (http://www. creativecommons. org/ licenses/ by- nc/ 4. 0/) which permits non-commercial use, reproduction and distribution of the work without further permission provided the original work is attributed as specified on the SAGE and Open Access pages (https:// us. sagepub. com/ en- us/ nam/ open- access- atsage)."],"url":[{"@id":"https://iwate-u.repo.nii.ac.jp/records/14923"},{"@id":"http://id.nii.ac.jp/1399/00014906/"}],"foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=10-halobornane-2-thione","dc:title":"10-halobornane-2-thione"},{"@id":"https://cir.nii.ac.jp/all?q=10-imidazolylbornane-2-thione","dc:title":"10-imidazolylbornane-2-thione"},{"@id":"https://cir.nii.ac.jp/all?q=thione%20S-oxides","dc:title":"thione S-oxides"},{"@id":"https://cir.nii.ac.jp/all?q=10-imidazolylbornan-2-one","dc:title":"10-imidazolylbornan-2-one"},{"@id":"https://cir.nii.ac.jp/all?q=functionalized%20imidazolium%20salt","dc:title":"functionalized imidazolium salt"}],"dcterms:subject":[{"subjectScheme":"Other","notation":[{"@language":"en","@value":"10-halobornane-2-thione"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"10-imidazolylbornane-2-thione"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"thione S-oxides"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"10-imidazolylbornan-2-one"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"functionalized imidazolium salt"}]}],"dataSourceIdentifier":[{"@type":"IRDB","@value":"oai:irdb.nii.ac.jp:01335:0004422341"},{"@type":"CIA","@value":"120006820156"},{"@type":"OPENAIRE","@value":"doi_dedup___::9f4734734697f63d4e18448f3d893649"}]}