{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1050305488937848192.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"HDL","@value":"https://hdl.handle.net/2324/7337521"}},{"identifier":{"@type":"DOI","@value":"10.1021/acs.biomac.4c00493"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/acs.biomac.4c00493"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@language":"en","@value":"Detailed Study of the Interactions between Glycopolymers in the Presence of Metal Ions through Quartz Crystal Microbalance Method"}],"dc:language":"en","description":[{"type":"Abstract","notation":[{"@language":"en","@value":"Polymer self-assemblies driven by enthalpic interactions, such as hydrogen bonding and electrostatic interactions, exhibit distinct properties compared to those driven by hydrophobic interactions. Carbohydrate–carbohydrate interactions, which are observed in physiological phenomena, also fall under enthalpic interactions. Our group previously reported on self-assemblies of methacrylate-type glycopolymers carrying mannose units in the presence of calcium ions; however, a detailed study of these interactions was lacking. In this work, we investigated the interactions between glycopolymers using the quartz crystal microbalance (QCM) method. Our quantitative analysis revealed that the interactions between the glycopolymers were influenced by the carbohydrate structures in the side chains, the types of divalent metal ions, and the structures of the polymer main chains. Notably, the strongest interaction was observed in the combination of methacrylate-type glycopolymers carrying mannose units and calcium ions, demonstrating their potential as a driving force for polymer self-assembly."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1070305488937848197","@type":"Researcher","foaf:name":[{"@language":"en","@value":"Sumura, Tomoya"},{"@language":"ja","@value":"洲村, 知弥"},{"@language":"ja-Kana","@value":"スムラ, トモヤ"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Chemical Engineering, Kyushu 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To access the final edited and published work see \"Related DOI\"."],"url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/acs.biomac.4c00493"}],"foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Calcium","dc:title":"Calcium"},{"@id":"https://cir.nii.ac.jp/all?q=Ions","dc:title":"Ions"},{"@id":"https://cir.nii.ac.jp/all?q=Metals","dc:title":"Metals"},{"@id":"https://cir.nii.ac.jp/all?q=Polymers","dc:title":"Polymers"},{"@id":"https://cir.nii.ac.jp/all?q=Sensors","dc:title":"Sensors"}],"dcterms:subject":[{"subjectScheme":"Other","notation":[{"@language":"en","@value":"Calcium"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"Ions"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"Metals"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"Polymers"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"Sensors"}]}],"project":[{"@id":"https://cir.nii.ac.jp/crid/1040018351904067200","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"23K26708"},{"@type":"JGN","@value":"JP23K26708"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23K26708/"}],"notation":[{"@language":"ja","@value":"精密重合を駆使した分子認識性糖鎖高分子の確立と高分子医薬の創製"},{"@language":"en","@value":"Development of glycopolymer nanomedicine with molecular recognition ability based on the precise polymerization"}]},{"@id":"https://cir.nii.ac.jp/crid/1040581224890450944","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"24K17560"},{"@type":"JGN","@value":"JP24K17560"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-24K17560/"}],"notation":[{"@language":"ja","@value":"やわらかい高分子に固定された再利用可能な触媒によるメカノケミカル合成の開発"},{"@language":"en","@value":"Development of Mechaochemical Organic Reactions with Flexible and Recyclable Polymer-Supported Catalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1040581224890523648","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"24K17726"},{"@type":"JGN","@value":"JP24K17726"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-24K17726/"}],"notation":[{"@language":"ja","@value":"精密高分子のダイナミクス制御による優れた単分子機能の発現"}]},{"@id":"https://cir.nii.ac.jp/crid/1860020984041248643","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"23H02015"},{"@type":"JGN","@value":"JP23H02015"}],"notation":[{"@language":"en","@value":"Molecular Recognition Glycopolymers by Controlled Polymerization and Development of Polymer Drugs"},{"@language":"ja","@value":"精密重合を駆使した分子認識性糖鎖高分子の確立と高分子医薬の創製"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360004233138231808","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Self-Assembly of a Double Hydrophilic Block Glycopolymer and the Investigation of Its Mechanism"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011144496997248","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The crystal and molecular structure of α-glucose"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011146200008576","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The use of ionization potentials Part 1. 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