{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1050574953673354752.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"URI","@value":"https://iwate-u.repo.nii.ac.jp/records/15787"}},{"identifier":{"@type":"DOI","@value":"10.1039/d1sc02122b"}},{"identifier":{"@type":"URI","@value":"http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC02122B"}},{"identifier":{"@type":"PMID","@value":"34447532"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Dynamic parallel kinetic resolution of α-ferrocenyl cation initiated by chiral Brønsted acid catalyst"}],"dc:language":"en","description":[{"type":"Abstract","notation":[{"@value":"The dynamic parallel kinetic resolution (DPKR) of an α-ferrocenyl cation intermediate under the influence of a chiral conjugate base of a chiral phosphoric acid catalyst has been demonstrated in an SN1 type substitution reaction of a racemic ferrocenyl derivative with a nitrogen nucleophile. The present method provides efficient access to a ferrocenylethylamine derivative in a highly enantioselective manner, which is potentially useful as a key precursor of chiral ligands for metal catalysis. The mechanism of the present intriguing resolution system was elucidated by control experiments using the enantio-pure precursor of relevant α-ferrocenyl cation intermediates and the hydroamination of vinylferrocene. Further theoretical studies enabled the elucidation of the origin of the stereochemical outcome as well as the efficient DPKR. The present DPKR, which opens a new frontier for kinetic resolution, involves the racemization process through the formation of vinylferrocene and the chemo-divergent parallel kinetic resolution of the enantiomeric α-ferrocenyl cations generated by the protonation/deprotonation sequence of vinylferrocene."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1070574953673354752","@type":"Researcher","foaf:name":[{"@value":"TODA, Yasunori"}]},{"@id":"https://cir.nii.ac.jp/crid/1420845751153889920","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"70335579"},{"@type":"NRID","@value":"1000070335579"},{"@type":"NRID","@value":"9000005195150"},{"@type":"NRID","@value":"9000258420829"},{"@type":"NRID","@value":"9000258420374"},{"@type":"NRID","@value":"9000409486161"},{"@type":"NRID","@value":"9000369734663"},{"@type":"NRID","@value":"9000248213388"},{"@type":"NRID","@value":"9000258419368"},{"@type":"NRID","@value":"9000000037205"},{"@type":"NRID","@value":"9000000842232"},{"@type":"NRID","@value":"9000408668737"},{"@type":"NRID","@value":"9000258420536"},{"@type":"NRID","@value":"9000256024238"},{"@type":"NRID","@value":"9000254710955"},{"@type":"NRID","@value":"9000258419375"},{"@type":"NRID","@value":"9000387917072"},{"@type":"NRID","@value":"9000240082920"},{"@type":"NRID","@value":"9000256022795"},{"@type":"NRID","@value":"9000388500180"},{"@type":"NRID","@value":"9000258420694"},{"@type":"NRID","@value":"9000024954419"},{"@type":"NRID","@value":"9000404149182"},{"@type":"NRID","@value":"9000258420932"},{"@type":"NRID","@value":"9000309169262"},{"@type":"NRID","@value":"9000010714494"},{"@type":"NRID","@value":"9000408668740"},{"@type":"NRID","@value":"9000256023003"},{"@type":"NRID","@value":"9000018970637"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0074450"}],"foaf:name":[{"@value":"KORENAGA, Toshinobu"}]},{"@id":"https://cir.nii.ac.jp/crid/1070574953673354756","@type":"Researcher","foaf:name":[{"@value":"OBAYASHI, Ren"}]},{"@id":"https://cir.nii.ac.jp/crid/1420564276183397760","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"20802656"},{"@type":"NRID","@value":"1000020802656"},{"@type":"NRID","@value":"9000396146699"},{"@type":"NRID","@value":"9000399852548"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/7000022474"}],"foaf:name":[{"@value":"KIKUCHI, Jun"}]},{"@id":"https://cir.nii.ac.jp/crid/1420845751162563968","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"50217428"},{"@type":"NRID","@value":"1000050217428"},{"@type":"NRID","@value":"9000404635283"},{"@type":"NRID","@value":"9000001997026"},{"@type":"NRID","@value":"9000359904620"},{"@type":"NRID","@value":"9000016983044"},{"@type":"NRID","@value":"9000000842246"},{"@type":"NRID","@value":"9000002973172"},{"@type":"NRID","@value":"9000010501110"},{"@type":"NRID","@value":"9000000591557"},{"@type":"NRID","@value":"9000242696620"},{"@type":"NRID","@value":"9000314078157"},{"@type":"NRID","@value":"9000243765902"},{"@type":"NRID","@value":"9000018280393"},{"@type":"NRID","@value":"9000257707899"},{"@type":"NRID","@value":"9000017673735"},{"@type":"NRID","@value":"9000002974971"},{"@type":"NRID","@value":"9000411211076"},{"@type":"NRID","@value":"9000356639312"},{"@type":"NRID","@value":"9000010624443"},{"@type":"NRID","@value":"9000018232051"},{"@type":"NRID","@value":"9000404110042"},{"@type":"NRID","@value":"9000256027887"},{"@type":"NRID","@value":"9000021435525"},{"@type":"NRID","@value":"9000404850556"},{"@type":"NRID","@value":"9000020964490"},{"@type":"NRID","@value":"9000020997382"},{"@type":"NRID","@value":"9000399852546"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/terada0214"}],"foaf:name":[{"@value":"TERADA, Masahiro"}]}],"publication":{"publicationIdentifier":[{"@type":"ISSN","@value":"20416520"},{"@type":"PISSN","@value":"20416520"},{"@type":"EISSN","@value":"20416539"}],"prism:publicationName":[{"@value":"Chemical Science"}],"dc:publisher":[{"@value":"The Royal Society of Chemistry"}],"prism:publicationDate":"2021-06-29","prism:volume":"12","prism:number":"30","prism:startingPage":"10306","prism:endingPage":"10312"},"reviewed":"false","dc:rights":["© 2021 The Author(s).","https://creativecommons.org/licenses/by-nc/3.0/"],"url":[{"@id":"https://iwate-u.repo.nii.ac.jp/records/15787"},{"@id":"http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC02122B"}],"project":[{"@id":"https://cir.nii.ac.jp/crid/1040282256936464128","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"17H06447"},{"@type":"JGN","@value":"JP17H06447"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PLANNED-17H06447/"}],"notation":[{"@language":"ja","@value":"「金属錯体／キラルブレンステッド酸」ハイブリッド触媒による効率的物質変換系の開拓"},{"@language":"en","@value":"Development of efficient molecular transformation system using [metal complexes/chiral Brønsted acids] hybrid catalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1040287907238200064","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"21K05064"},{"@type":"JGN","@value":"JP21K05064"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21K05064/"}],"notation":[{"@language":"ja","@value":"計算化学を駆使した単純ケトンの高選択的不斉水素化を実現するメタルフリー触媒の開発"},{"@language":"en","@value":"Development of metal-free catalyst for the reduction of simple ketones using computational chemistry."}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050001335816330240","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Organocatalytic Activation of the Leaving Group in the Intramolecular Asymmetric S(N) 2' Reaction."},{"@value":"Organocatalytic Activation of the Leaving Group in the Intramolecular Asymmetric S<sub>N</sub>2′ Reaction"}]},{"@id":"https://cir.nii.ac.jp/crid/1050564288800321664","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Enantioselective Intramolecular Nicholas Reaction Catalyzed by Chiral Phosphoric Acid: Enantioconvergent Synthesis of Seven‐Membered Cyclic Ethers from Racemic Diols"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004233216200704","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Enantioconvergent Nucleophilic Substitution Reaction of Racemic Alkyne–Dicobalt Complex (Nicholas Reaction) Catalyzed by Chiral Brønsted Acid"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004233217024640","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Chiral Phosphoric Acid Catalyzed Enantioselective Ring Expansion Reaction of 1,3-Dithiane Derivatives: Case Study of the Nature of Ion-Pairing Interaction"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004233590065792","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Secondary stereocontrolling interactions in chiral Brønsted acid catalysis: study of a Petasis–Ferrier-type rearrangement catalyzed by chiral phosphoric acids"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004233631615744","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"F<sub>10</sub>BINOL-derived chiral phosphoric acid-catalyzed enantioselective carbonyl-ene reaction: theoretical elucidation of stereochemical outcomes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011146301950208","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"An Organocatalytic Asymmetric Allylic Alkylation Allows Enantioselective Total Synthesis of Hydroxymetasequirin-A and Metasequirin-B Tetramethyl Ether Diacetates"}]},{"@id":"https://cir.nii.ac.jp/crid/1360013168859558528","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Development of chiral bisphosphoric acid/boronic acid co-catalyst system for enantioselective SN2’ reaction"}]},{"@id":"https://cir.nii.ac.jp/crid/1360013172128796800","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The 13C NMR spectra and structure of ferrocenylcarbenium ions"}]},{"@id":"https://cir.nii.ac.jp/crid/1360013173252707072","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Experimental and DFT study of cyclodehydration and acetylation of ferrocenyl diols"}]},{"@id":"https://cir.nii.ac.jp/crid/1360021390766111616","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Intermolecular\n                    <i>exo</i>\n                    -selective Diels–Alder reaction catalysed by dual-functional Brønsted acid: conformational restriction of transition states by hydrogen bonds as the key interaction"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285708608200192","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Chiral Brønsted acid-catalyzed intramolecular S<sub>N</sub>2′ reaction for enantioselective construction of a quaternary stereogenic center"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292618739071872","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Enantioselective Mannich‐Type Reaction Catalyzed by a Chiral Brønsted Acid"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292619590324736","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Metallocenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292620969402624","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Catalytic, Asymmetric Halofunctionalization of Alkenes—A Critical Perspective"}]},{"@id":"https://cir.nii.ac.jp/crid/1360294647680509056","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Enzymatic resolution of 1‐ferrocenylethanol and 1‐ferrocenyl‐2,2,2‐trifluoroethanol using lipases"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183167217536","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Mechanistic Studies of Highly Enantio- and Diastereoselective Aza-Petasis–Ferrier Rearrangement Catalyzed by Chiral Phosphoric Acid"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574092892313088","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574093667313152","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Stronger Brønsted Acids"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574093913213056","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574095875610752","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Brønsted Acid Catalyzed Asymmetric S<sub>N</sub>2‐Type O‐Alkylations"}]},{"@id":"https://cir.nii.ac.jp/crid/1360576121616392064","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"α-Metallocenylmethylium Ions and Their Isoelectronic Congeners: A Comparison Based on DFT Calculations"}]},{"@id":"https://cir.nii.ac.jp/crid/1360588381063714048","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"DFT calculation-aided optimisation of a chiral phosphoric acid catalyst: case study of kinetic resolution of racemic secondary alcohols through lactonisation"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846641588698112","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Enantioselective Synthesis of Multisubstituted Biaryl Skeleton by Chiral Phosphoric Acid Catalyzed Desymmetrization/Kinetic Resolution Sequence"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846645767644544","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Recent Progress in Organocatalytic Asymmetric Halocyclization"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855569693023744","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Asymmetric phosphoric acid–catalyzed four-component Ugi reaction"}]},{"@id":"https://cir.nii.ac.jp/crid/1360857595858964736","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Enantioconvergent Substitution Reactions of Racemic Electrophiles by Organocatalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1360857624624634752","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Metal-Catalyzed Kinetic Resolution Processes"}]},{"@id":"https://cir.nii.ac.jp/crid/1361131414472189312","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Mechanism and Origin of Stereoselectivity in Chiral Phosphoric Acid‐Catalyzed Aldol‐Type Reactions of Azlactones with Vinyl Ethers"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137046080154752","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A Novel Easily Accessible Chiral Ferrocenyldiphosphine for Highly Enantioselective Hydrogenation, Allylic Alkylation, and Hydroboration Reactions"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418519610673024","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Chiral Brønsted acid catalyzed enantioselective intermolecular allylic aminations"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418520322547072","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Kinetic Resolution"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418521473961984","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Chiral Organic Contact Ion Pairs in Metal-Free Catalytic Asymmetric Allylic Substitutions"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699993566218240","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Parallel Kinetic Resolutions"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699993649867648","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Studies of the Mechanism and Origins of Enantioselectivity for the Chiral Phosphoric Acid-Catalyzed Stereoselective Spiroketalization Reactions"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699994075248384","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Practical Considerations in Kinetic Resolution Reactions"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981469232913792","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Quantum Calculation of Molecular Energies and Energy Gradients in Solution by a Conductor Solvent Model"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262943606222720","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Recent Advances in Organocatalytic Kinetic Resolution for the Synthesis of Functionalized Products"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262943896939136","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262944385576064","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Disparate Catalytic Scaffolds for Atroposelective Cyclodehydration"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544419121953280","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Recent Applications of Chiral Ferrocene Ligands in Asymmetric Catalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544420619610368","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Chiral phosphoric acid catalysis: from numbers to insights"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544421088460288","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Dynamic Thermodynamic Resolution: Advantage by Separation of Equilibration and Resolution"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825893407065856","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Selective Syntheses of Planar-Chiral Ferrocenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825894578428160","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Understanding the Mechanism of the Asymmetric Propargylation of Aldehydes Promoted by 1,1′-Bi-2-naphthol-Derived Catalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107368766108672","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Asymmetric Counteranion‐Directed Catalysis: Concept, Definition, and Applications"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107369755913472","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Chiral Brønsted Acid-Catalyzed Direct Mannich Reactions via Electrophilic Activation"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107370780491776","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Chiral Brønsted Acids for Asymmetric Organocatalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388843620084224","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Enantioselective Selenocyclization via Dynamic Kinetic Resolution of Seleniranium Ions by Hydrogen-Bond Donor Catalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388844809094272","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Facile Access to Optically Active Ferrocenyl Derivatives with Direct Substitution of the Hydroxy Group Catalyzed by Indium Tribromide"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388845051834240","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Parallel kinetic resolution of racemic mixtures: a new strategy for the preparation of enantiopure compounds?"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388846283626752","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Asymmetric Ion‐Pairing Catalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670318309455488","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Dynamic Thermodynamic Resolution:  Control of Enantioselectivity through Diastereomeric Equilibration"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670319451857280","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Chiral Brønsted Acid Catalyzed Kinetic Resolutions"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670320524182784","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Efficiency in Nonenzymatic Kinetic Resolution"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670321081842944","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Density-functional exchange-energy approximation with correct asymptotic behavior"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951794362548224","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: two new functionals and systematic testing of four M06-class functionals and 12 other functionals"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233269364893568","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The progression of chiral anions from concepts to applications in asymmetric catalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233269938297856","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A Brønsted acid-promoted asymmetric intramolecular allylic amination of alcohols"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233270384663168","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations"}]}],"dataSourceIdentifier":[{"@type":"IRDB","@value":"oai:irdb.nii.ac.jp:01335:0005511387"},{"@type":"CROSSREF","@value":"10.1039/d1sc02122b"},{"@type":"KAKEN","@value":"PRODUCT-24702865"},{"@type":"KAKEN","@value":"PRODUCT-24030458"},{"@type":"OPENAIRE","@value":"doi_dedup___::284f36e337f9e11a30d6b2f88afb4e6a"},{"@type":"CROSSREF","@value":"10.1016/j.tet.2021.132412_references_DOI_AYYtlVkIXkEeEZ6mOmJ7FFe05Ig"},{"@type":"CROSSREF","@value":"10.1039/d3ra07688a_references_DOI_AYYtlVkIXkEeEZ6mOmJ7FFe05Ig"},{"@type":"CROSSREF","@value":"10.1039/d4cy01029a_references_DOI_AYYtlVkIXkEeEZ6mOmJ7FFe05Ig"}]}