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Here, we report C–H amidation/cyclization reactions of sulfondiimines with dioxazolones catalyzed by the combination of a cobalt(III) catalyst and a pseudo C₂-symmetric chiral carboxylic acid, leading to the formation of unprecedented 1,2,4-benzothiadiazine-1-imine structures in high enantioselectivity."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1070586499778570498","@type":"Researcher","foaf:name":[{"@language":"en","@value":"Murata, Ayami"}]},{"@id":"https://cir.nii.ac.jp/crid/1070586499778570500","@type":"Researcher","foaf:name":[{"@language":"en","@value":"Endo, Tomonori"},{"@language":"ja","@value":"遠藤, 智倫"}]},{"@id":"https://cir.nii.ac.jp/crid/1030859912489039232","@type":"Researcher","foaf:name":[{"@language":"en","@value":"Hirata, Yuki"},{"@language":"ja","@value":"平田, 裕己"}]},{"@id":"https://cir.nii.ac.jp/crid/1070586499778570497","@type":"Researcher","foaf:name":[{"@language":"en","@value":"Higashida, Kosuke"},{"@language":"ja","@value":"東田, 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Licence."],"url":[{"@id":"http://pubs.rsc.org/en/content/articlepdf/2025/QO/D5QO00355E"}],"project":[{"@id":"https://cir.nii.ac.jp/crid/1040014327101576192","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"23H00293"},{"@type":"JGN","@value":"JP23H00293"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23H00293/"}],"notation":[{"@language":"ja","@value":"キラル２核金属触媒の２金属間協働機能に基づく遠隔位C-H結合の不斉官能基化"},{"@language":"en","@value":"Asymmetric Remote C~H Functionalization based on Synergy of Two Metals under Chiral Dinuclear Catalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1040569382226976256","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"21K05046"},{"@type":"JGN","@value":"JP21K05046"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21K05046/"}],"notation":[{"@language":"ja","@value":"キラル2-ピリドン誘導体と第9族金属による不斉C(sp3)-H官能基化"},{"@language":"en","@value":"Enantioselective C(sp3)-H functionalization using a group 9 metal 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