{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1050587981431997696.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"HDL","@value":"https://hdl.handle.net/2115/60503"}},{"identifier":{"@type":"DOI","@value":"10.1039/c5ra21402e"}},{"identifier":{"@type":"URI","@value":"http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA21402E"}},{"identifier":{"@type":"HANDLE","@value":"2115/60503"}},{"identifier":{"@type":"NAID","@value":"120005690895"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@language":"en","@value":"Proton-assisted low-temperature sintering of Cu fine particles stabilized by a proton-initiating degradable polymer"}],"dc:language":"en","description":[{"type":"Abstract","notation":[{"@language":"en","@value":"Metallic copper fine particles were prepared by chemical reduction of CuO in the presence of thermally degradable poly-1,4-butanediol-divinylether (BDVE). Because a BDVE thin layer formed on the particle surfaces, the obtained copper particles were stable and did not undergo obvious oxidation under ambient conditions. The ether groups of BDVE were hydrolyzed with protons, and this generated small fragment molecules. The BDVE-stabilized copper fine particles and their pastes can be therefore sintered at 150 degrees C in the presence of protons. Electro-conductive films with a relatively low resistivity of 8.5 x 10(-5) Omega cm were obtained on a alumina substrate in the presence of formic acid, and hot pressed conductive pellets with a resistivity of 2.9 x 10(-5) Omega cm were also obtained without any pre-oxidative annealing in the presence of proton generator molecules at very low temperatures. The hot pressed pellets show a high anti-oxidative ability and their corrosion tests revealed their good anti-corrosion property."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1420001326232060288","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"40746111"},{"@type":"NRID","@value":"1000040746111"},{"@type":"NRID","@value":"9000351083216"},{"@type":"NRID","@value":"9000409015765"},{"@type":"NRID","@value":"9000239601715"},{"@type":"NRID","@value":"9000317557766"},{"@type":"NRID","@value":"9000340952677"},{"@type":"NRID","@value":"9000403582143"},{"@type":"NRID","@value":"9000317561806"},{"@type":"NRID","@value":"9000258393527"},{"@type":"NRID","@value":"9000345438011"},{"@type":"NRID","@value":"9000412318036"},{"@type":"NRID","@value":"9000304623395"},{"@type":"NRID","@value":"9000312252618"},{"@type":"NRID","@value":"9000346926983"},{"@type":"NRID","@value":"9000403418856"},{"@type":"NRID","@value":"9000331445153"},{"@type":"NRID","@value":"9000345437887"},{"@type":"NRID","@value":"9000396108010"},{"@type":"NRID","@value":"9000363173194"},{"@type":"NRID","@value":"9000314804160"},{"@type":"NRID","@value":"9000398135736"},{"@type":"NRID","@value":"9000314057684"},{"@type":"NRID","@value":"9000402796250"},{"@type":"NRID","@value":"9000398958521"},{"@type":"NRID","@value":"9000412318067"},{"@type":"NRID","@value":"9000414493617"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/m_matu"}],"foaf:name":[{"@language":"en","@value":"Matsubara, Masaki"}]},{"@id":"https://cir.nii.ac.jp/crid/1420001326236922496","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"90284538"},{"@type":"NRID","@value":"1000090284538"},{"@type":"CINII_AUTHOR_ID","@value":"DA16141442"},{"@type":"URI","@value":"https://ci.nii.ac.jp/author/DA16141442#entity"},{"@type":"URI","@value":"https://viaf.org/viaf/NII%7CDA16141442"},{"@type":"NRID","@value":"9000002106570"},{"@type":"NRID","@value":"9000016909894"},{"@type":"NRID","@value":"9000016923264"},{"@type":"NRID","@value":"9000414501395"},{"@type":"NRID","@value":"9000351083214"},{"@type":"NRID","@value":"9000256432927"},{"@type":"NRID","@value":"9000283371875"},{"@type":"NRID","@value":"9000009599053"},{"@type":"NRID","@value":"9000010575823"},{"@type":"NRID","@value":"9000241786390"},{"@type":"NRID","@value":"9000000218721"},{"@type":"NRID","@value":"9000024448742"},{"@type":"NRID","@value":"9000317557762"},{"@type":"NRID","@value":"9000255703655"},{"@type":"NRID","@value":"9000258179228"},{"@type":"NRID","@value":"9000332697735"},{"@type":"NRID","@value":"9000343344167"},{"@type":"NRID","@value":"9000340465361"},{"@type":"NRID","@value":"9000340952678"},{"@type":"NRID","@value":"9000403582145"},{"@type":"NRID","@value":"9000391396588"},{"@type":"NRID","@value":"9000317561804"},{"@type":"NRID","@value":"9000254934065"},{"@type":"NRID","@value":"9000261652909"},{"@type":"NRID","@value":"9000356625146"},{"@type":"NRID","@value":"9000025082900"},{"@type":"NRID","@value":"9000001650476"},{"@type":"NRID","@value":"9000272241637"},{"@type":"NRID","@value":"9000391844209"},{"@type":"NRID","@value":"9000384339092"},{"@type":"NRID","@value":"9000258259503"},{"@type":"NRID","@value":"9000257718329"},{"@type":"NRID","@value":"9000257732659"},{"@type":"NRID","@value":"9000300218314"},{"@type":"NRID","@value":"9000304623393"},{"@type":"NRID","@value":"9000391885341"},{"@type":"NRID","@value":"9000312252619"},{"@type":"NRID","@value":"9000000773017"},{"@type":"NRID","@value":"9000311495169"},{"@type":"NRID","@value":"9000356913747"},{"@type":"NRID","@value":"9000283573740"},{"@type":"NRID","@value":"9000370243603"},{"@type":"NRID","@value":"9000006908879"},{"@type":"NRID","@value":"9000391396431"},{"@type":"NRID","@value":"9000402012350"},{"@type":"NRID","@value":"9000399852711"},{"@type":"NRID","@value":"9000015259715"},{"@type":"NRID","@value":"9000001221857"},{"@type":"NRID","@value":"9000331445154"},{"@type":"NRID","@value":"9000242730421"},{"@type":"NRID","@value":"9000409876523"},{"@type":"NRID","@value":"9000412128594"},{"@type":"NRID","@value":"9000363173193"},{"@type":"NRID","@value":"9000414843861"},{"@type":"NRID","@value":"9000309999988"},{"@type":"NRID","@value":"9000404334873"},{"@type":"NRID","@value":"9000391844217"},{"@type":"NRID","@value":"9000257719880"},{"@type":"NRID","@value":"9000317550686"},{"@type":"NRID","@value":"9000018118792"},{"@type":"NRID","@value":"9000242109309"},{"@type":"NRID","@value":"9000311495141"},{"@type":"NRID","@value":"9000020514882"},{"@type":"NRID","@value":"9000402025984"},{"@type":"NRID","@value":"9000410323642"},{"@type":"NRID","@value":"9000258119222"},{"@type":"NRID","@value":"9000257729058"},{"@type":"NRID","@value":"9000257735127"},{"@type":"NRID","@value":"9000257723041"},{"@type":"NRID","@value":"9000257717621"},{"@type":"NRID","@value":"9000262357521"},{"@type":"NRID","@value":"9000006653905"},{"@type":"NRID","@value":"9000314057685"},{"@type":"NRID","@value":"9000391845395"},{"@type":"NRID","@value":"9000308727534"},{"@type":"NRID","@value":"9000399224214"},{"@type":"NRID","@value":"9000398301671"},{"@type":"NRID","@value":"9000409209750"},{"@type":"NRID","@value":"9000258667062"},{"@type":"NRID","@value":"9000001995740"},{"@type":"NRID","@value":"9000019059304"},{"@type":"NRID","@value":"9000018233426"},{"@type":"NRID","@value":"9000003721027"},{"@type":"NRID","@value":"9000322107823"},{"@type":"NRID","@value":"9000020302362"},{"@type":"NRID","@value":"9000346936783"},{"@type":"NRID","@value":"9000323296175"},{"@type":"NRID","@value":"9000307260948"},{"@type":"NRID","@value":"9000259834345"},{"@type":"NRID","@value":"9000398958520"},{"@type":"NRID","@value":"9000018463685"},{"@type":"NRID","@value":"9000356675007"},{"@type":"NRID","@value":"9000340465352"},{"@type":"NRID","@value":"9000254934948"},{"@type":"NRID","@value":"9000024430774"},{"@type":"NRID","@value":"9000310740200"},{"@type":"NRID","@value":"9000410265770"},{"@type":"NRID","@value":"9000412191712"},{"@type":"NRID","@value":"9000259841553"},{"@type":"NRID","@value":"9000242731828"},{"@type":"NRID","@value":"9000410745630"},{"@type":"NRID","@value":"9000010642534"},{"@type":"NRID","@value":"9000356648968"},{"@type":"NRID","@value":"9000414839119"},{"@type":"NRID","@value":"9000250178162"},{"@type":"NRID","@value":"9000302392460"},{"@type":"NRID","@value":"9000256260738"},{"@type":"NRID","@value":"9000241840421"},{"@type":"NRID","@value":"9000009825946"},{"@type":"NRID","@value":"9000302392490"},{"@type":"NRID","@value":"9000321629073"},{"@type":"NRID","@value":"9000314057670"},{"@type":"NRID","@value":"9000391851023"},{"@type":"NRID","@value":"9000401745278"},{"@type":"NRID","@value":"9000259841434"},{"@type":"NRID","@value":"9000257783334"},{"@type":"NRID","@value":"9000397852675"},{"@type":"NRID","@value":"9000410630644"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/tetsuyonezawa"}],"foaf:name":[{"@language":"en","@value":"Yonezawa, Tetsu"}]},{"@id":"https://cir.nii.ac.jp/crid/1070587981431997570","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000314057686"}],"foaf:name":[{"@language":"en","@value":"Minoshima, Takato"}]},{"@id":"https://cir.nii.ac.jp/crid/1410859370680166528","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000351083217"},{"@type":"NRID","@value":"9000317557763"},{"@type":"NRID","@value":"9000304623394"},{"@type":"NRID","@value":"9000312252620"},{"@type":"NRID","@value":"9000356913743"},{"@type":"NRID","@value":"9000402025983"},{"@type":"NRID","@value":"9000314057687"},{"@type":"NRID","@value":"9000322107821"},{"@type":"NRID","@value":"9000346936780"},{"@type":"NRID","@value":"9000307260947"},{"@type":"NRID","@value":"9000340465355"},{"@type":"NRID","@value":"9000024430764"},{"@type":"NRID","@value":"9000356648967"},{"@type":"NRID","@value":"9000314057672"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/htsukamo"}],"foaf:name":[{"@language":"en","@value":"Tsukamoto, Hiroki"}]},{"@id":"https://cir.nii.ac.jp/crid/1070587981431997696","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000314057688"}],"foaf:name":[{"@language":"en","@value":"Yong, Yingqiong"}]},{"@id":"https://cir.nii.ac.jp/crid/1420845751157767424","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"00726713"},{"@type":"NRID","@value":"1000000726713"},{"@type":"NRID","@value":"9000017552745"},{"@type":"NRID","@value":"9000414501394"},{"@type":"NRID","@value":"9000406295491"},{"@type":"NRID","@value":"9000020056353"},{"@type":"NRID","@value":"9000009715976"},{"@type":"NRID","@value":"9000332697734"},{"@type":"NRID","@value":"9000343344166"},{"@type":"NRID","@value":"9000340465360"},{"@type":"NRID","@value":"9000340952675"},{"@type":"NRID","@value":"9000391396587"},{"@type":"NRID","@value":"9000261652907"},{"@type":"NRID","@value":"9000005180869"},{"@type":"NRID","@value":"9000272241635"},{"@type":"NRID","@value":"9000384339091"},{"@type":"NRID","@value":"9000254225431"},{"@type":"NRID","@value":"9000300218312"},{"@type":"NRID","@value":"9000391835822"},{"@type":"NRID","@value":"9000014623567"},{"@type":"NRID","@value":"9000388477578"},{"@type":"NRID","@value":"9000331445150"},{"@type":"NRID","@value":"9000274311604"},{"@type":"NRID","@value":"9000001632442"},{"@type":"NRID","@value":"9000391835834"},{"@type":"NRID","@value":"9000406207698"},{"@type":"NRID","@value":"9000317550685"},{"@type":"NRID","@value":"9000311495139"},{"@type":"NRID","@value":"9000243732221"},{"@type":"NRID","@value":"9000388497164"},{"@type":"NRID","@value":"9000314057689"},{"@type":"NRID","@value":"9000239644340"},{"@type":"NRID","@value":"9000308727531"},{"@type":"NRID","@value":"9000322107822"},{"@type":"NRID","@value":"9000404848860"},{"@type":"NRID","@value":"9000307260945"},{"@type":"NRID","@value":"9000340465354"},{"@type":"NRID","@value":"9000361706664"},{"@type":"NRID","@value":"9000415048024"},{"@type":"NRID","@value":"9000310740197"},{"@type":"NRID","@value":"9000410265769"},{"@type":"NRID","@value":"9000302392459"},{"@type":"NRID","@value":"9000312257482"},{"@type":"NRID","@value":"9000391831540"},{"@type":"NRID","@value":"9000321629072"},{"@type":"NRID","@value":"9000410630643"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/kumajuurou"}],"foaf:name":[{"@language":"en","@value":"Ishida, Yohei"}]},{"@id":"https://cir.nii.ac.jp/crid/1070587981431997568","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000314057690"}],"foaf:name":[{"@language":"en","@value":"Mai Thanh Nguyen"}]},{"@id":"https://cir.nii.ac.jp/crid/1070587981431997698","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000314057691"}],"foaf:name":[{"@language":"en","@value":"Tanaka, Hiroki"}]},{"@id":"https://cir.nii.ac.jp/crid/1070587981431997572","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000314057692"}],"foaf:name":[{"@language":"en","@value":"Okamoto, Kazuki"}]},{"@id":"https://cir.nii.ac.jp/crid/1070587981431997571","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000314057693"}],"foaf:name":[{"@language":"en","@value":"Osaka, Takuya"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"20462069"},{"@type":"EISSN","@value":"20462069"}],"prism:publicationName":[{"@language":"en","@value":"RSC advances"}],"dc:publisher":[{"@value":"Royal Society of Chemistry"}],"prism:publicationDate":"2015","prism:volume":"5","prism:number":"124","prism:startingPage":"102904","prism:endingPage":"102910"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","dc:rights":["Creative Commons Attribution 3.0 Unported"],"url":[{"@id":"http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA21402E"},{"@id":"http://hdl.handle.net/2115/60503"}],"foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=500","dc:title":"500"},{"@id":"https://cir.nii.ac.jp/all?q=430","dc:title":"430"}],"dcterms:subject":[{"subjectScheme":"NDC","notation":[{"@value":"430"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050025031478432384","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"A new approach for additive-free room temperature sintering of conductive patterns using polymer-stabilized Sn nanoparticles"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001288065505408","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"電子材料への応用のためのナノ粒子の表面デザイン"},{"@language":"en","@value":"Surface Design and Functional Prediction of Inorganic Nanoparticles for Electronic Material Applications"},{"@language":"ja-Kana","@value":"デンシ ザイリョウ エ ノ オウヨウ ノ タメ ノ ナノ リュウシ ノ ヒョウメン デザイン"}]},{"@id":"https://cir.nii.ac.jp/crid/1390301949907859200","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Review: Copper Fine Particle/Nanoparticle-Based Sintering Joining Material"},{"@language":"ja","@value":"レビュー：銅微粒子・ナノ粒子を用いた焼結性接合材料"}]},{"@id":"https://cir.nii.ac.jp/crid/1390303321513000832","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Review: Copper Fine Particle/Nanoparticle-Based Sintering Joining Material"}]},{"@id":"https://cir.nii.ac.jp/crid/1390854882571918592","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Copper Materials for Low Temperature Sintering"}]},{"@id":"https://cir.nii.ac.jp/crid/1390869688554275712","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"電子部品部材に用いるナノ粒子の実用化に向けた最新研究開発動向"},{"@language":"en","@value":"Recent Trends in Research and Development for the Practical Application of Nanoparticles in Electronic Component Materials"}]},{"@id":"https://cir.nii.ac.jp/crid/1523388080039106816","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Preparation of Water-Dispersible Palladium Nanoparticles Stabilized by Carbon-Palladium Bonds and Application to Suzuki-Miyaura Coupling in Water"}]}],"dataSourceIdentifier":[{"@type":"IRDB","@value":"oai:irdb.nii.ac.jp:01364:0007177396"},{"@type":"CROSSREF","@value":"10.1039/c5ra21402e"},{"@type":"CIA","@value":"120005690895"},{"@type":"OPENAIRE","@value":"doi_dedup___::172df7515fb546d7cbce4c4b3f20d770"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20160238_references_DOI_aT79ZBtkg8Sy6e1b3cuj2iUqlaA"},{"@type":"CROSSREF","@value":"10.4164/sptj.55.325_references_DOI_aT79ZBtkg8Sy6e1b3cuj2iUqlaA"},{"@type":"CROSSREF","@value":"10.2320/jinstmet.j2023042_references_DOI_aT79ZBtkg8Sy6e1b3cuj2iUqlaA"},{"@type":"CROSSREF","@value":"10.2320/matertrans.mt-n2021004_references_DOI_aT79ZBtkg8Sy6e1b3cuj2iUqlaA"},{"@type":"CROSSREF","@value":"10.4139/sfj.76.306_references_DOI_aT79ZBtkg8Sy6e1b3cuj2iUqlaA"},{"@type":"CROSSREF","@value":"10.2320/matertrans.mt-m2024157_references_DOI_aT79ZBtkg8Sy6e1b3cuj2iUqlaA"},{"@type":"CROSSREF","@value":"10.1039/c6tc00161k_references_DOI_aT79ZBtkg8Sy6e1b3cuj2iUqlaA"}]}