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Our approach provides an efficient entry to the azaspirocycle via a cascade Wacker-allylation sequence followed by a highly stereoselective Claisen rearrangement. This azaspirocycle, bearing all of the requisite functionality with pivotal stereogenic centers, is considered to be a versatile precursor useful for the fawcettimine-type Lycopodium alkaloids."}]},{"type":"Other","notation":[{"@language":"ja","@value":"ファイル公開：2019-09-21"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1070845763743976962","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000399769345"}],"foaf:name":[{"@language":"en","@value":"Huang, Wen-Yu"}]},{"@id":"https://cir.nii.ac.jp/crid/1420282801202431360","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"90208158"},{"@type":"NRID","@value":"1000090208158"},{"@type":"NRID","@value":"9000018475035"},{"@type":"NRID","@value":"9000399769346"},{"@type":"NRID","@value":"9000256027566"},{"@type":"NRID","@value":"9000257733250"},{"@type":"NRID","@value":"9000004250697"},{"@type":"NRID","@value":"9000406057098"},{"@type":"NRID","@value":"9000257735254"},{"@type":"NRID","@value":"9000000196387"},{"@type":"NRID","@value":"9000001861499"},{"@type":"NRID","@value":"9000018232035"},{"@type":"NRID","@value":"9000255702857"},{"@type":"NRID","@value":"9000257701582"},{"@type":"NRID","@value":"9000016387069"},{"@type":"NRID","@value":"9000240523259"},{"@type":"NRID","@value":"9000376922949"},{"@type":"NRID","@value":"9000409313775"},{"@type":"NRID","@value":"9000414749571"},{"@type":"NRID","@value":"9000382233279"},{"@type":"NRID","@value":"9000411398605"},{"@type":"NRID","@value":"9000259831850"},{"@type":"NRID","@value":"9000413909748"},{"@type":"NRID","@value":"9000346962738"},{"@type":"NRID","@value":"9000004177005"},{"@type":"NRID","@value":"9000412366197"},{"@type":"NRID","@value":"9000257708525"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0011498"}],"foaf:name":[{"@language":"en","@value":"Nishikawa, Toshio"}]},{"@id":"https://cir.nii.ac.jp/crid/1420001326215989120","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"00366428"},{"@type":"NRID","@value":"1000000366428"},{"@type":"NRID","@value":"9000006709949"},{"@type":"NRID","@value":"9000399769347"},{"@type":"NRID","@value":"9000391974414"},{"@type":"NRID","@value":"9000362823457"},{"@type":"NRID","@value":"9000018795765"},{"@type":"NRID","@value":"9000257733248"},{"@type":"NRID","@value":"9000006365769"},{"@type":"NRID","@value":"9000262362130"},{"@type":"NRID","@value":"9000019948245"},{"@type":"NRID","@value":"9000406057099"},{"@type":"NRID","@value":"9000391966766"},{"@type":"NRID","@value":"9000257726297"},{"@type":"NRID","@value":"9000241448955"},{"@type":"NRID","@value":"9000362823467"},{"@type":"NRID","@value":"9000006656625"},{"@type":"NRID","@value":"9000257729478"},{"@type":"NRID","@value":"9000391969297"},{"@type":"NRID","@value":"9000404530413"},{"@type":"NRID","@value":"9000413946951"},{"@type":"NRID","@value":"9000376922945"},{"@type":"NRID","@value":"9000382233278"},{"@type":"NRID","@value":"9000391968050"},{"@type":"NRID","@value":"9000410652118"},{"@type":"NRID","@value":"9000391972822"},{"@type":"NRID","@value":"9000240034508"},{"@type":"NRID","@value":"9000346962735"},{"@type":"NRID","@value":"9000391966840"},{"@type":"NRID","@value":"9000391960825"},{"@type":"NRID","@value":"9000015311530"},{"@type":"NRID","@value":"9000297492937"},{"@type":"NRID","@value":"9000020879288"},{"@type":"NRID","@value":"9000391964545"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0110331"}],"foaf:name":[{"@language":"en","@value":"Nakazaki, Atsuo"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00223263"},{"@type":"EISSN","@value":"15206904"}],"prism:publicationName":[{"@language":"en","@value":"The Journal of Organic Chemistry"}],"dc:publisher":[{"@value":"ACS Publications"}],"prism:publicationDate":"2018-09-21","prism:volume":"83","prism:number":"18","prism:startingPage":"11108","prism:endingPage":"11117"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","dc:rights":["“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [The Journal of Organic Chemistry], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-BeWqHcS67iRJzc2hBadn].”"],"url":[{"@id":"https://nagoya.repo.nii.ac.jp/records/27056"},{"@id":"https://pubs.acs.org/doi/pdf/10.1021/acs.joc.8b01719"},{"@id":"http://hdl.handle.net/2237/00029256"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050571948037518720","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Total Synthesis of Lyconesidine B, a Lycopodium Alkaloid with an Oxygenated, Amine-Type Fawcettimine Core"},{"@value":"Total Synthesis of Lyconesidine B, a <i>Lycopodium</i> Alkaloid with an Oxygenated, Amine-Type Fawcettimine Core"}]},{"@id":"https://cir.nii.ac.jp/crid/1883398393089834752","@type":"Dataset","relationType":["isSupplementedBy"],"jpcoar:relatedTitle":[{"@value":"CCDC 1849784: Experimental Crystal Structure Determination"}]},{"@id":"https://cir.nii.ac.jp/crid/2051151842062065792","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Total synthesis of lyconesidine B : approach to a three-dimensional tetracyclic skeleton of amine-type fawcettimine core and studies of asymmetric synthesis"}]}],"dataSourceIdentifier":[{"@type":"IRDB","@value":"oai:irdb.nii.ac.jp:01152:0003275377"},{"@type":"CROSSREF","@value":"10.1021/acs.joc.8b01719"},{"@type":"CIA","@value":"120006554479"},{"@type":"OPENAIRE","@value":"doi_dedup___::7ccf5bc73b66c80f804bbe7d2a9c95b8"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20220049_references_DOI_TGY4AAlXyDgM6PHAYqGYdJKgpAs"},{"@type":"CROSSREF","@value":"10.1021/acs.orglett.0c03816_references_DOI_TGY4AAlXyDgM6PHAYqGYdJKgpAs"}]}