{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1050869456410683264.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"HDL","@value":"https://hdl.handle.net/2115/51776"}},{"identifier":{"@type":"DOI","@value":"10.1063/1.4759498"}},{"identifier":{"@type":"URI","@value":"https://pubs.aip.org/aip/adv/article-pdf/doi/10.1063/1.4759498/12942497/042113_1_online.pdf"}},{"identifier":{"@type":"HANDLE","@value":"2115/51776"}},{"identifier":{"@type":"NAID","@value":"120005183189"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@language":"en","@value":"High temperature oxidation event of gelatin nanoskin-coated copper fine particles observed by in situ TEM"},{"@value":"High temperature oxidation event of gelatin nanoskin-coated copper fine particles observed by <i>in situ</i> TEM"}],"dc:language":"en","description":[{"type":"Abstract","notation":[{"@language":"en","@value":"Metallic copper fine particles were prepared using CuO slurry by hydrazine reduction in the presence of gelatin. To observe a behavior of these particles at high temperature, in situ heating TEM observations were carried out. Oxygen gas was introduced and the pressure of the TEM column was kept at 10^[-3] Pa, corresponding the pressure around the sample at 10^[-1] Pa. The gelatin, which acts as a protective nanoskin on the particle surface was gradually decomposed. Around approximately 140℃, it was observed that Cu2O dots formed on the surface of the copper particle. This result is well consistent with the behavior of the TG-DTA curve of the copper fine particles under ambient conditions, and provides key information of oxidative behavior of copper fine particles."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410001206481515010","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000283232166"},{"@type":"NRID","@value":"9000261652906"},{"@type":"NRID","@value":"9000272241634"},{"@type":"NRID","@value":"9000404105356"},{"@type":"NRID","@value":"9000019136934"},{"@type":"NRID","@value":"9000401766666"},{"@type":"NRID","@value":"9000259834343"},{"@type":"NRID","@value":"9000356675006"},{"@type":"NRID","@value":"9000257858761"},{"@type":"NRID","@value":"9000024430757"},{"@type":"NRID","@value":"9000025033287"},{"@type":"NRID","@value":"9000257783328"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/takashi_narushima"}],"foaf:name":[{"@language":"en","@value":"Narushima, Takashi"}]},{"@id":"https://cir.nii.ac.jp/crid/1410859370680166528","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000351083217"},{"@type":"NRID","@value":"9000317557763"},{"@type":"NRID","@value":"9000304623394"},{"@type":"NRID","@value":"9000312252620"},{"@type":"NRID","@value":"9000356913743"},{"@type":"NRID","@value":"9000402025983"},{"@type":"NRID","@value":"9000314057687"},{"@type":"NRID","@value":"9000322107821"},{"@type":"NRID","@value":"9000346936780"},{"@type":"NRID","@value":"9000307260947"},{"@type":"NRID","@value":"9000340465355"},{"@type":"NRID","@value":"9000024430764"},{"@type":"NRID","@value":"9000356648967"},{"@type":"NRID","@value":"9000314057672"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/htsukamo"}],"foaf:name":[{"@language":"en","@value":"Tsukamoto, Hiroki"}]},{"@id":"https://cir.nii.ac.jp/crid/1420001326236922496","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"90284538"},{"@type":"NRID","@value":"1000090284538"},{"@type":"CINII_AUTHOR_ID","@value":"DA16141442"},{"@type":"URI","@value":"https://ci.nii.ac.jp/author/DA16141442#entity"},{"@type":"URI","@value":"https://viaf.org/viaf/NII%7CDA16141442"},{"@type":"NRID","@value":"9000002106570"},{"@type":"NRID","@value":"9000016909894"},{"@type":"NRID","@value":"9000016923264"},{"@type":"NRID","@value":"9000414501395"},{"@type":"NRID","@value":"9000351083214"},{"@type":"NRID","@value":"9000256432927"},{"@type":"NRID","@value":"9000283371875"},{"@type":"NRID","@value":"9000009599053"},{"@type":"NRID","@value":"9000010575823"},{"@type":"NRID","@value":"9000241786390"},{"@type":"NRID","@value":"9000000218721"},{"@type":"NRID","@value":"9000024448742"},{"@type":"NRID","@value":"9000317557762"},{"@type":"NRID","@value":"9000255703655"},{"@type":"NRID","@value":"9000258179228"},{"@type":"NRID","@value":"9000332697735"},{"@type":"NRID","@value":"9000343344167"},{"@type":"NRID","@value":"9000340465361"},{"@type":"NRID","@value":"9000340952678"},{"@type":"NRID","@value":"9000403582145"},{"@type":"NRID","@value":"9000391396588"},{"@type":"NRID","@value":"9000317561804"},{"@type":"NRID","@value":"9000254934065"},{"@type":"NRID","@value":"9000261652909"},{"@type":"NRID","@value":"9000356625146"},{"@type":"NRID","@value":"9000025082900"},{"@type":"NRID","@value":"9000001650476"},{"@type":"NRID","@value":"9000272241637"},{"@type":"NRID","@value":"9000391844209"},{"@type":"NRID","@value":"9000384339092"},{"@type":"NRID","@value":"9000258259503"},{"@type":"NRID","@value":"9000257718329"},{"@type":"NRID","@value":"9000257732659"},{"@type":"NRID","@value":"9000300218314"},{"@type":"NRID","@value":"9000304623393"},{"@type":"NRID","@value":"9000391885341"},{"@type":"NRID","@value":"9000312252619"},{"@type":"NRID","@value":"9000000773017"},{"@type":"NRID","@value":"9000311495169"},{"@type":"NRID","@value":"9000356913747"},{"@type":"NRID","@value":"9000283573740"},{"@type":"NRID","@value":"9000370243603"},{"@type":"NRID","@value":"9000006908879"},{"@type":"NRID","@value":"9000391396431"},{"@type":"NRID","@value":"9000402012350"},{"@type":"NRID","@value":"9000399852711"},{"@type":"NRID","@value":"9000015259715"},{"@type":"NRID","@value":"9000001221857"},{"@type":"NRID","@value":"9000331445154"},{"@type":"NRID","@value":"9000242730421"},{"@type":"NRID","@value":"9000409876523"},{"@type":"NRID","@value":"9000412128594"},{"@type":"NRID","@value":"9000363173193"},{"@type":"NRID","@value":"9000414843861"},{"@type":"NRID","@value":"9000309999988"},{"@type":"NRID","@value":"9000404334873"},{"@type":"NRID","@value":"9000391844217"},{"@type":"NRID","@value":"9000257719880"},{"@type":"NRID","@value":"9000317550686"},{"@type":"NRID","@value":"9000018118792"},{"@type":"NRID","@value":"9000242109309"},{"@type":"NRID","@value":"9000311495141"},{"@type":"NRID","@value":"9000020514882"},{"@type":"NRID","@value":"9000402025984"},{"@type":"NRID","@value":"9000410323642"},{"@type":"NRID","@value":"9000258119222"},{"@type":"NRID","@value":"9000257729058"},{"@type":"NRID","@value":"9000257735127"},{"@type":"NRID","@value":"9000257723041"},{"@type":"NRID","@value":"9000257717621"},{"@type":"NRID","@value":"9000262357521"},{"@type":"NRID","@value":"9000006653905"},{"@type":"NRID","@value":"9000314057685"},{"@type":"NRID","@value":"9000391845395"},{"@type":"NRID","@value":"9000308727534"},{"@type":"NRID","@value":"9000399224214"},{"@type":"NRID","@value":"9000398301671"},{"@type":"NRID","@value":"9000409209750"},{"@type":"NRID","@value":"9000258667062"},{"@type":"NRID","@value":"9000001995740"},{"@type":"NRID","@value":"9000019059304"},{"@type":"NRID","@value":"9000018233426"},{"@type":"NRID","@value":"9000003721027"},{"@type":"NRID","@value":"9000322107823"},{"@type":"NRID","@value":"9000020302362"},{"@type":"NRID","@value":"9000346936783"},{"@type":"NRID","@value":"9000323296175"},{"@type":"NRID","@value":"9000307260948"},{"@type":"NRID","@value":"9000259834345"},{"@type":"NRID","@value":"9000398958520"},{"@type":"NRID","@value":"9000018463685"},{"@type":"NRID","@value":"9000356675007"},{"@type":"NRID","@value":"9000340465352"},{"@type":"NRID","@value":"9000254934948"},{"@type":"NRID","@value":"9000024430774"},{"@type":"NRID","@value":"9000310740200"},{"@type":"NRID","@value":"9000410265770"},{"@type":"NRID","@value":"9000412191712"},{"@type":"NRID","@value":"9000259841553"},{"@type":"NRID","@value":"9000242731828"},{"@type":"NRID","@value":"9000410745630"},{"@type":"NRID","@value":"9000010642534"},{"@type":"NRID","@value":"9000356648968"},{"@type":"NRID","@value":"9000414839119"},{"@type":"NRID","@value":"9000250178162"},{"@type":"NRID","@value":"9000302392460"},{"@type":"NRID","@value":"9000256260738"},{"@type":"NRID","@value":"9000241840421"},{"@type":"NRID","@value":"9000009825946"},{"@type":"NRID","@value":"9000302392490"},{"@type":"NRID","@value":"9000321629073"},{"@type":"NRID","@value":"9000314057670"},{"@type":"NRID","@value":"9000391851023"},{"@type":"NRID","@value":"9000401745278"},{"@type":"NRID","@value":"9000259841434"},{"@type":"NRID","@value":"9000257783334"},{"@type":"NRID","@value":"9000397852675"},{"@type":"NRID","@value":"9000410630644"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/tetsuyonezawa"}],"foaf:name":[{"@language":"en","@value":"Yonezawa, Tetsu"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"21583226"},{"@type":"EISSN","@value":"21583226"}],"prism:publicationName":[{"@language":"en","@value":"AIP Advances"}],"dc:publisher":[{"@value":"American Institute of Physics"}],"prism:publicationDate":"2012-12","prism:volume":"2","prism:number":"4","prism:startingPage":"042113"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","dc:rights":["Creative Commons Attribution 3.0 Unported"],"url":[{"@id":"https://pubs.aip.org/aip/adv/article-pdf/doi/10.1063/1.4759498/12942497/042113_1_online.pdf"},{"@id":"http://hdl.handle.net/2115/51776"}],"foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=copper","dc:title":"copper"},{"@id":"https://cir.nii.ac.jp/all?q=differential%20thermal%20analysis","dc:title":"differential thermal analysis"},{"@id":"https://cir.nii.ac.jp/all?q=gelatin","dc:title":"gelatin"},{"@id":"https://cir.nii.ac.jp/all?q=nanofabrication","dc:title":"nanofabrication"},{"@id":"https://cir.nii.ac.jp/all?q=nanostructured%20materials","dc:title":"nanostructured materials"},{"@id":"https://cir.nii.ac.jp/all?q=oxidation","dc:title":"oxidation"},{"@id":"https://cir.nii.ac.jp/all?q=protective%20coatings","dc:title":"protective coatings"},{"@id":"https://cir.nii.ac.jp/all?q=pyrolysis","dc:title":"pyrolysis"},{"@id":"https://cir.nii.ac.jp/all?q=reduction%20(chemical)","dc:title":"reduction (chemical)"},{"@id":"https://cir.nii.ac.jp/all?q=transmission%20electron%20microscopy","dc:title":"transmission electron microscopy"}],"dcterms:subject":[{"subjectScheme":"NDC","notation":[{"@value":"426"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"copper"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"differential thermal analysis"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"gelatin"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"nanofabrication"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"nanostructured materials"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"oxidation"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"protective coatings"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"pyrolysis"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"reduction (chemical)"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"transmission electron microscopy"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360848658086470528","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Double-Wall TiO<sub>2</sub>Nanotube Arrays: Enhanced Photocatalytic Activity and<i>In Situ</i>TEM Observations at High Temperature"}]},{"@id":"https://cir.nii.ac.jp/crid/1361975843346288256","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"<i>In situ</i> TEM observation of liquid-state Sn nanoparticles vanishing in a SiO<sub>2</sub> structure: a potential synthetic tool for controllable morphology evolution from core–shell to yolk–shell and hollow structures"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001288065505408","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"電子材料への応用のためのナノ粒子の表面デザイン"},{"@language":"en","@value":"Surface Design and Functional Prediction of Inorganic Nanoparticles for Electronic Material Applications"},{"@language":"ja-Kana","@value":"デンシ ザイリョウ エ ノ オウヨウ ノ タメ ノ ナノ リュウシ ノ ヒョウメン デザイン"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679230284672","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Wet Preparation of Organic-Stabilizer-Free Urchin Structured Nickel Fine Particles and Their <i>In Situ</i> TEM Observation at High Temperatures"},{"@language":"ja","@value":"有機保護分子をもたないウニ型 Ni 微粒子の湿式合成とその場 TEM による高温挙動観察"},{"@language":"ja-Kana","@value":"ユウキ ホゴ ブンシ オ モタナイ ウニガタ Ni ビリュウシ ノ シッシキ ゴウセイ ト ソノ バ TEM ニ ヨル コウオン キョドウ カンサツ"},{"@value":"Wet Preparation of Organic-Stabilizer-Free Urchin Structured Nickel Fine Particles and Their In Situ TEM Observation at High Temperatures"},{"@value":"Wet Preparation of Organic Stabilizer Free Urchin Structured Nickel Fine Particles and Their In-Situ TEM Observation at High Temperature"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679566522368","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"In Situ Transmission Electron Microscopic Observation of Double-wall TiO<sub>2</sub> Nanotube Arrays at High Temperature"},{"@value":"In Situ Transmission Electron Microscopic Observation of Double-wall TiO2 Nanotube Arrays at High Temperature"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282681502875520","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Use of a Bio-Polymer as Protective Reagent for the Metal Particles for Electronic Parts"},{"@language":"ja","@value":"生体関連高分子を電子部品につかう材料粒子の保護剤とする"},{"@language":"ja-Kana","@value":"セイタイ カンレン コウブンシ オ デンシ ブヒン ニ ツカウ ザイリョウ リュウシ ノ ホゴザイ ト スル"}]},{"@id":"https://cir.nii.ac.jp/crid/1390854882571918592","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Copper Materials for Low Temperature Sintering"}]},{"@id":"https://cir.nii.ac.jp/crid/1522825130629283328","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Effect of Glass Transition Temperature of Stabilizing Polymer of Air-Stable Gelatin-Stabilized Copper Fine Particles during Redox Two-Step Low-Temperature Sintering Process"}]}],"dataSourceIdentifier":[{"@type":"IRDB","@value":"oai:irdb.nii.ac.jp:01364:0007169782"},{"@type":"CROSSREF","@value":"10.1063/1.4759498"},{"@type":"CIA","@value":"120005183189"},{"@type":"OPENAIRE","@value":"doi_dedup___::d70e680000fe4569f7e3a726b3133b2e"},{"@type":"CROSSREF","@value":"10.2320/jinstmet.j2013073_references_DOI_YFeg8MQ8kDRusllsrojbp2v8PLF"},{"@type":"CROSSREF","@value":"10.1021/am505333v_references_DOI_YFeg8MQ8kDRusllsrojbp2v8PLF"},{"@type":"CROSSREF","@value":"10.2320/matertrans.m2014176_references_DOI_YFeg8MQ8kDRusllsrojbp2v8PLF"},{"@type":"CROSSREF","@value":"10.4164/sptj.55.325_references_DOI_YFeg8MQ8kDRusllsrojbp2v8PLF"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20150305_references_DOI_YFeg8MQ8kDRusllsrojbp2v8PLF"},{"@type":"CROSSREF","@value":"10.2320/matertrans.mt-n2021004_references_DOI_YFeg8MQ8kDRusllsrojbp2v8PLF"},{"@type":"CROSSREF","@value":"10.1246/cl.140486_references_DOI_YFeg8MQ8kDRusllsrojbp2v8PLF"},{"@type":"CROSSREF","@value":"10.1295/koron.70.684_references_DOI_YFeg8MQ8kDRusllsrojbp2v8PLF"},{"@type":"CROSSREF","@value":"10.1039/c9na00782b_references_DOI_YFeg8MQ8kDRusllsrojbp2v8PLF"}]}