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Copper salts play a crucial role as a catalyst to achieve allylic perfluoroalkylation with the in situ generated bis(perfluoroacyl) peroxides. Furthermore, carboperfluoroalkylation of alkene bearing an aromatic ring at an appropriate position on the carbon side chain was found to proceed under metal‐free conditions to afford carbocycles or heterocycles bearing a perfluoroalkyl group. This method, which makes use of readily available perfluoroalkyl sources, offers a convenient and powerful tool for introducing a perfluoroalkyl group onto an sp3 carbon to construct synthetically useful skeletons."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1420282801199834752","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"60732956"},{"@type":"NRID","@value":"1000060732956"},{"@type":"ORCID","@value":"0000-0002-7422-837X"},{"@type":"NRID","@value":"9000305636313"},{"@type":"NRID","@value":"9000019141566"},{"@type":"NRID","@value":"9000248231007"},{"@type":"NRID","@value":"9000399851872"},{"@type":"NRID","@value":"9000403282467"},{"@type":"NRID","@value":"9000018773651"},{"@type":"NRID","@value":"9000303993398"},{"@type":"NRID","@value":"9000239229810"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/skawamura"}],"foaf:name":[{"@value":"Shintaro Kawamura"}],"jpcoar:affiliationName":[{"@value":"Synthetic Organic Chemistry Laboratory RIKEN 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