{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360002215435454080.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1007/s11243-013-9771-z"}},{"identifier":{"@type":"URI","@value":"http://link.springer.com/content/pdf/10.1007/s11243-013-9771-z.pdf"}},{"identifier":{"@type":"URI","@value":"http://link.springer.com/article/10.1007/s11243-013-9771-z/fulltext.html"}},{"identifier":{"@type":"URI","@value":"http://link.springer.com/content/pdf/10.1007/s11243-013-9771-z"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Synthesis and characterization of supramolecular complexes of a tetranuclear metallocycle with platinum(II) bis-ethynylphenylethynylpyridine organometallic complexes"}],"description":[{"notation":[{"@value":"A novel Pt(II) organometallic complex with 4-(4-ethynyl-phenylethynyl)-pyridine (DEBPy-H), namely [Pt(dppp)(DEBPy)2] (dppp = 1,3-bis-(diphenylphosphino)-propane), has been prepared by two synthetic routes. The DEBPy-H ligand was prepared by a shorter synthetic pathway and in higher yield than the method of previous reports. New Pt(II) organometallic complexes with DEBPy-H and four bidentate ligands [Pt(L–L)(DEBPy)2] (L–L = 1,2-bis-(diphenylphosphino)-benzene, bis-(dicyclohexyl)-ethane, 4,4′-dimethyl-2,2′-bipyridine, or 5,5′-dimethyl-2,2′-bipyridine) have also been prepared. These five Pt(II) complexes have two pyridyl units as an available coordination site that can operate as a metalloligand in nanoscale tectonics. A supramolecular complex of a tetranuclear metallocycle, [Pt(dppp)(DEBPy)2]2[Pt(dppp)]2(OTf)4, was synthesized from [Pt(dppp)(DEBPy)2] and [Pt(dppp)(OTf)2] as a corner connection through coordination-driven self-assembly. This supramolecular Pt(II) complex exists as a tetranuclear structure of the square type according to the interpretation of the ESI-mass and NMR spectra in solution. Five Pt(II) organometallics demonstrated the formation of similar tetranuclear metallocycles with [Pt(dppp)(OTf)2], as indicated by their ESI-mass and UV–vis spectra in solution."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1420282801211460608","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"70293743"},{"@type":"NRID","@value":"1000070293743"},{"@type":"NRID","@value":"9000001210083"},{"@type":"NRID","@value":"9000283123799"},{"@type":"NRID","@value":"9000257721506"},{"@type":"NRID","@value":"9000000548774"},{"@type":"NRID","@value":"9000240539283"},{"@type":"NRID","@value":"9000257734657"},{"@type":"NRID","@value":"9000000544657"},{"@type":"NRID","@value":"9000283122807"},{"@type":"NRID","@value":"9000283122819"},{"@type":"NRID","@value":"9000257707169"},{"@type":"NRID","@value":"9000258600358"},{"@type":"NRID","@value":"9000283124204"},{"@type":"NRID","@value":"9000409990356"},{"@type":"NRID","@value":"9000403595153"},{"@type":"NRID","@value":"9000403599058"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0190089"}],"foaf:name":[{"@value":"Michito Shiotsuka"}]},{"@id":"https://cir.nii.ac.jp/crid/1380284918572642947","@type":"Researcher","foaf:name":[{"@value":"Takafumi Toda"}]},{"@id":"https://cir.nii.ac.jp/crid/1380284918572642945","@type":"Researcher","foaf:name":[{"@value":"Kenta Matsubara"}]},{"@id":"https://cir.nii.ac.jp/crid/1380284918572642944","@type":"Researcher","foaf:name":[{"@value":"Yuki Itou"}]},{"@id":"https://cir.nii.ac.jp/crid/1380284918572642948","@type":"Researcher","foaf:name":[{"@value":"Takuto Hashimoto"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"03404285"},{"@type":"EISSN","@value":"1572901X"}],"prism:publicationName":[{"@value":"Transition Metal Chemistry"}],"dc:publisher":[{"@value":"Springer Science and Business Media LLC"}],"prism:publicationDate":"2013-10-18","prism:volume":"38","prism:number":"8","prism:startingPage":"913","prism:endingPage":"922"},"reviewed":"false","dc:rights":["http://www.springer.com/tdm"],"url":[{"@id":"http://link.springer.com/content/pdf/10.1007/s11243-013-9771-z.pdf"},{"@id":"http://link.springer.com/article/10.1007/s11243-013-9771-z/fulltext.html"},{"@id":"http://link.springer.com/content/pdf/10.1007/s11243-013-9771-z"}],"createdAt":"2013-10-17","modifiedAt":"2019-07-30","project":[{"@id":"https://cir.nii.ac.jp/crid/1040282257138437504","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"23550074"},{"@type":"JGN","@value":"JP23550074"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23550074/"}],"notation":[{"@language":"ja","@value":"光応答性複合超分子錯体の構築と金属基板上への配列制御"},{"@language":"en","@value":"Construction of photoactive supramolecular complexes and the arrangement control of the supramolecular on metallic 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