{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360002216645662464.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/ie401082a"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/ie401082a"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Interfacial Polymerization of Functional Paper: Morphology of the Nylon Film Prepared on Paper Surfaces"}],"description":[{"notation":[{"@value":"The aim of this study was to control the preparation of novel functional papers. The morphology of the polyamide (nylon-2,8) prepared on the paper surface using interfacial polymerization was investigated. After impregnation with ethylenediamine (EDA) solution and NaOH solution, filter paper was placed in a beaker containing organic solvent (cyclohexane, chloroform, or cyclohexane–chloroform solvents (volume ratio = 3:1, 1:1, 1:3), a mixture of terephthaloyl chloride, and trimesoyl chloride. When cyclohexane was used as the organic solvent, a nylon-2,8 capsule structure formed on the paper surface. For cyclohexane–chloroform solvents, the nylon-2,8 morphologies were fibrous or porous according to the EDA concentration and the organic solvent type. These results were attributed to differences in the spreading coefficient (S) of the organic EDA solution adsorbed on the paper surface and the partition coefficient (P) shown by the dispersion of EDA fixed on the paper from the aqueous phase to the organic phas..."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1420001326230643328","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"30448394"},{"@type":"NRID","@value":"1000030448394"},{"@type":"NRID","@value":"9000019227950"},{"@type":"NRID","@value":"9000005388952"},{"@type":"NRID","@value":"9000006317080"},{"@type":"NRID","@value":"9000010524238"},{"@type":"NRID","@value":"9000356889893"},{"@type":"NRID","@value":"9000016972911"},{"@type":"NRID","@value":"9000010631529"},{"@type":"NRID","@value":"9000338425277"},{"@type":"NRID","@value":"9000356625384"},{"@type":"NRID","@value":"9000017668165"},{"@type":"NRID","@value":"9000292867928"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/ichiura-16"}],"foaf:name":[{"@value":"Hideaki Ichiura"}],"jpcoar:affiliationName":[{"@value":"Faculty of Agriculture, Kochi University, 200 Monobe-Otsu, Nankoku, Kochi 783-8502, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380566394785429249","@type":"Researcher","foaf:name":[{"@value":"Takenori Seike"}],"jpcoar:affiliationName":[{"@value":"Faculty of Agriculture, Kochi University, 200 Monobe-Otsu, Nankoku, Kochi 783-8502, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380566394785429250","@type":"Researcher","foaf:name":[{"@value":"Yoshito Ohtani"}],"jpcoar:affiliationName":[{"@value":"Faculty of Agriculture, Kochi University, 200 Monobe-Otsu, Nankoku, Kochi 783-8502, Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"08885885"},{"@type":"EISSN","@value":"15205045"}],"prism:publicationName":[{"@value":"Industrial & Engineering Chemistry Research"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"2013-06-20","prism:volume":"52","prism:number":"26","prism:startingPage":"9137","prism:endingPage":"9144"},"reviewed":"false","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/ie401082a"}],"createdAt":"2013-06-07","modifiedAt":"2023-04-06","project":[{"@id":"https://cir.nii.ac.jp/crid/1040000782211154432","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"24580247"},{"@type":"JGN","@value":"JP24580247"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-24580247/"}],"notation":[{"@language":"ja","@value":"紙表面上でナノファイバーを直接合成する手法の確立とその機能解析"},{"@language":"en","@value":"Direct preparation of polyamide nano-fiber on paper surface and its perfomance"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050564287496778240","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Paper-paraffin composites prepared by interfacial 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