{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360002216660261120.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/jacs.7b02553"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/jacs.7b02553"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Synthesis, Structure, and Catalysis of Palladium Complexes Bearing a Group 13 Metalloligand: Remarkable Effect of an Aluminum-Metalloligand in Hydrosilylation of CO<sub>2</sub>"}],"description":[{"notation":[{"@value":"Efficient synthesis and catalysis of a series of palladium complexes having a group 13 metalloligand (Al, Ga, In) are reported utilizing 6,6″-bis(phosphino)terpyridine as a new scaffold for Pd–E bonds (E = Al, Ga, In). Systematic investigation revealed unique characteristics of the Al-metalloligand in both structure and reactivity, which exhibited the highest catalytic activity for hydrosilylation of CO2 ever reported (TOF = 19 300 h–1). This study demonstrated fine-tuning of catalyst activity by the precisely designed metalloligand is a promising approach for new catalyst development in synthetic organometallic chemistry."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1420845751163999488","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"60401535"},{"@type":"NRID","@value":"1000060401535"},{"@type":"NRID","@value":"9000016416483"},{"@type":"NRID","@value":"9000257714023"},{"@type":"NRID","@value":"9000018990709"},{"@type":"NRID","@value":"9000257727250"},{"@type":"NRID","@value":"9000107384921"},{"@type":"NRID","@value":"9000261677273"},{"@type":"NRID","@value":"9000257720671"},{"@type":"NRID","@value":"9000006766082"},{"@type":"NRID","@value":"9000257736031"},{"@type":"NRID","@value":"9000025110885"},{"@type":"NRID","@value":"9000001898636"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0134152"}],"foaf:name":[{"@value":"Jun Takaya"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry,\rSchool of Science, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8551, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380002216660261120","@type":"Researcher","foaf:name":[{"@value":"Nobuharu Iwasawa"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry,\rSchool of Science, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8551, Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00027863"},{"@type":"EISSN","@value":"15205126"}],"prism:publicationName":[{"@value":"Journal of the American Chemical Society"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"2017-04-25","prism:volume":"139","prism:number":"17","prism:startingPage":"6074","prism:endingPage":"6077"},"reviewed":"false","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/jacs.7b02553"}],"createdAt":"2017-04-20","modifiedAt":"2023-04-23","project":[{"@id":"https://cir.nii.ac.jp/crid/1040000781956299264","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"17H03019"},{"@type":"JGN","@value":"JP17H03019"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17H03019/"}],"notation":[{"@language":"ja","@value":"金属元素を配位子として活用する新触媒・新反応の開発"},{"@language":"en","@value":"Development of precisely designed metalloligands for new transition metal 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Ligands"}]},{"@id":"https://cir.nii.ac.jp/crid/1040282256844430208","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"15KT0059"},{"@type":"JGN","@value":"JP15KT0059"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-15KT0059/"}],"notation":[{"@language":"ja","@value":"遷移状態制御を基盤とする多金属協同作用系触媒の理論設計"},{"@language":"en","@value":"Development of Rationally Designed Multimetallic Catalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1040282257170236544","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"24245019"},{"@type":"JGN","@value":"JP24245019"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-24245019/"}],"notation":[{"@language":"ja","@value":"実用化を指向した二酸化炭素固定化反応の高度化"},{"@language":"en","@value":"Exploration of Efficient Carbon Dioxide 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