{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360002219097413632.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/bcsj.29.894"}},{"identifier":{"@type":"URI","@value":"https://academic.oup.com/bcsj/article-pdf/29/8/894/55797670/bcsj.29.894.pdf"}},{"identifier":{"@type":"NAID","@value":"130001959745"}}],"dc:title":[{"@value":"Spectrochemical Study of Microscopic Crystals. XIII. The Structure of Wolffram’s Red Salt, Pt(NH2·C2H5)4Cl3·2H3O and a Related Compound"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title>\n               <jats:p>Polarized absorption spectra of Wolffram’s red salt, Pt(EA)4Cl3·2H2O, and a related compound, Pt(EA)4Br3·2H2O, EA being ethylamine, have been determined by Tsuchida-Kobayashi’s microscopic method in the regions covering from 2400 to 7500 Å.</jats:p>\n               <jats:p>Both the compounds, which are supposed to be formulated by [Pt(EA)4][Pt(EA)4X2]X4·4H2O, have been found to show an absorption band that has not been observed with either of the components alone. Moreover, this band is strongly polarized along the needle axis. These relationships may be understood on the assumption that the crystals of these compounds involve infinite chains of ---X—PtIV—X---PtII---X—PtIV—X--- along the needle axis, X being chlorine or bromine.</jats:p>\n               <jats:p>The new absorption at the longer wavelength may be considered as a charge transfer band along the infinite chains as assumed above.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1583387452547840512","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020266793"}],"foaf:name":[{"@value":"Shoichiro Yamada"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Faculty of Science, Osaka University"}]},{"@id":"https://cir.nii.ac.jp/crid/1583387452547840513","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020266805"}],"foaf:name":[{"@value":"Ryutaro Tsuchida"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Faculty of Science, Osaka University"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00092673"},{"@type":"EISSN","@value":"13480634"}],"prism:publicationName":[{"@value":"Bulletin of the Chemical Society of Japan"}],"dc:publisher":[{"@value":"Oxford University Press (OUP)"}],"prism:publicationDate":"1956-08-01","prism:volume":"29","prism:number":"8","prism:startingPage":"894","prism:endingPage":"898"},"reviewed":"false","dc:rights":["https://academic.oup.com/pages/standard-publication-reuse-rights"],"url":[{"@id":"https://academic.oup.com/bcsj/article-pdf/29/8/894/55797670/bcsj.29.894.pdf"}],"createdAt":"2006-07-19","modifiedAt":"2024-01-17","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=General%20Chemistry","dc:title":"General Chemistry"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002219096638080","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Spectrochemical Study of Microscopic Crystals. I. Application of Microscopes in Spectrography"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283694074956032","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"A New Red Platinum(II)-Platinum(IV) Compound"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283694077658624","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Studies on Mixed Valence Complexes of Platinum and Palladium. I. Preparation and Characterization of Pt(II)–Pt(IV), Pd(II)–Pt(IV), and Pd(II)–Pd(IV) Complexes of the General Formula, [M(AA)2][M′X2(AA)2]Y4"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285708102539008","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Neutral-Type One-Dimensional Mixed-Valence Halogen-Bridged Platinum Chain Complexes with Large Charge-Transfer Band Gaps"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285708168092800","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"On the Nature of the Multiple Ground States of the MMX Mixed-Valence Chain Compound, [Pt<sup>II/III</sup><sub>2</sub>(<i>n</i>-PenCS<sub>2</sub>)<sub>4</sub>I]<sub>∞</sub>"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565169050887168","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Spectrochemical Study of Microscopic Crystals. XIV. Absorption Spectra and Structure of Dibenzene-chromium(I) Iodide"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565169057415680","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Intercalation of [Pt(en)2]2+ and [PtCl2(en)2]2+ Ions by Na-Montmorillonite"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574096553279616","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Structures of Complexes Formed by Halogen Molecules with Aromatic and with Oxygenated Solvents<sup>1</sup>"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846644031154176","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Studies on Mixed Valence Complexes of Platinum and Palladium. II. The Crystal Structures of [Pt(tn)2][PtCl2(tn)2](BF4)4, [Pt(tn)2][PtBr2(tn)2](ClO4)4, and [Pt(tn)2][PtBr2(tn)2](BF4)4"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699994316706176","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Molecular Compounds and their Spectra. III. The Interaction of Electron Donors and Acceptors"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825895432221568","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Molecular Compounds and their Spectra. II"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670320748847616","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Interaction between Metal Ions through Anions"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204131676800","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Spedrochemical Study of Microscopic Crystals. XII. Polarized Absorption Spectra of Cupric Complexes with Tropolone and Related Compounds"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204182718976","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Relaxation of Electron-Phonon System in Optically Excited Quasi-1-D Mixed Valence Crystal Wolffram’s Red Salt"},{"@value":"Relaxation of Electron-Phonon System in Optically Excited Quasi-1-D Mixed Valence Crystal Wolffram′s Red Salt"},{"@language":"ja-Kana","@value":"Relaxation of Electron Phonon System in"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204183644928","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"X-Ray Diffuse Scattering in Wolffram’s Red Salt"},{"@value":"X-Ray Diffuse Scattering in Wolffram′s Red Salt"},{"@language":"ja-Kana","@value":"X Ray Diffuse Scattering in Wolffram s"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204187182976","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Uniaxial Stress-Effect on the One-Dimensional Band Structure of [Pt(en)<SUB>2</SUB>][Pt(en)<SUB>2</SUB>Cl<SUB>2</SUB>](ClO<SUB>4</SUB>)<SUB>4</SUB> (en=ethylenediamine)"},{"@value":"Uniaxial Stress-Effect on the One-Dimensional Band Structure of〔Pt(en)2〕〔Pt(en)2Cl2〕(ClO4)4(en=ethylenediamine)"},{"@language":"ja-Kana","@value":"Uniaxial Stress Effect on the One Dimen"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679119788160","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Exploration of Boundary between Charge-Density-Wave and Mott-Hubbard States in Quasi-One-Dimensional Halogen-Bridged Metal Complexes"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679159566464","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Photo-Induced Absorption Band in One-Dimensional Halogen-Bridged Mixed-Valence Platinum Complex: [Pt(en)<SUB>2</SUB>][PtI<SUB>2</SUB>(en)<SUB>2</SUB>](SO<SUB>4</SUB>)<SUB>2</SUB>·6H<SUB>2</SUB>O and its Au-Doped Complex: [Au<I><SUB>x</SUB></I>Pt<SUB>1−<I>x</I></SUB>I(en)<SUB>2</SUB>]SO<SUB>4</SUB>·3H<SUB>2</SUB>O"},{"@value":"Photo-Induced Absorption Band in One-Dimensional Halogen-Bridged Mixed-Valence Platinum Complex:〔Pt(en)2〕〔PtI2(en)2〕(SO4)2・6H2O and its Au-Doped Complex:〔AuxPt1-xI(en)2〕SO4・3H2O"},{"@language":"ja-Kana","@value":"Photo Induced Absorption Band in One Di"},{"@value":"Photo-Induced Absorption Band in One-Dimensional Halogen-Bridged Mixed-Valence Platinum Complex: [Pt(en)<sub>2</sub>][PtI<sub>2</sub>(en)<sub>2</sub>](SO<sub>4</sub>)<sub>2</sub>·6H<sub>2</sub>O and its Au-Doped Complex: [Au<sub><i>x</i></sub>Pt<sub>1-<i>x</i></sub>I(en)<sub>2</sub>]SO<sub>4</sub>·3H<sub>2</sub>O"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679159578112","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Photo-Induced Defect States in a Quasi One-Dimensional Mixed-Valence Platinum Complex"},{"@language":"ja-Kana","@value":"Photo Induced Defect States in a Quasi"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679161627904","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"EXAFS and XANES Studies of Wolffram’s Red Salt"},{"@value":"EXAFS and XANES Studies of Wolffram′s Red Salt"},{"@language":"ja-Kana","@value":"EXAFS and XANES Studies of Wolffram s R"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679163634816","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Raflectance Spectra and Band Structures of Quasi-One-Dimensional [Pt(en)<SUB>2</SUB>][Pt(en)<SUB>2</SUB>X<SUB>2</SUB>](ClO<SUB>4</SUB>)<SUB>4</SUB> (X=I and Cl, en=ethylenediamine) Crystals"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282680274876288","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"電荷双安定性に由来する擬一次元ハロゲン架橋金属錯体の動的挙動創出と可視化"},{"@language":"en","@value":"Creation and Visualization of the Charge Dynamics in Quasi-One-Dimensional Halogen-Bridged Metal Complexes Driven by the Charge Bistability"},{"@value":"Award Accounts 電荷双安定性に由来する擬一次元ハロゲン架橋金属錯体の動的挙動創出と可視化"},{"@language":"ja-Kana","@value":"Award Accounts デンカソウアンテイセイ ニ ユライ スル ギ1ジゲン ハロゲン カキョウ キンゾク サクタイ ノ ドウテキ キョドウ ソウシュツ ト カシカ"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1246/bcsj.29.894"},{"@type":"CIA","@value":"130001959745"},{"@type":"OPENAIRE","@value":"doi_dedup___::dd8824bab20d8d666bd236b4f881663b"},{"@type":"CROSSREF","@value":"10.1246/bcsj.51.3514_references_DOI_D9mGMziBQ75YrU7PiJy7smsnKsx"},{"@type":"CROSSREF","@value":"10.1143/jpsj.52.1446_references_DOI_D9mGMziBQ75YrU7PiJy7smsnKsx"},{"@type":"CROSSREF","@value":"10.1143/jpsj.54.3632_references_DOI_D9mGMziBQ75YrU7PiJy7smsnKsx"},{"@type":"CROSSREF","@value":"10.1143/jpsj.52.2769_references_DOI_D9mGMziBQ75YrU7PiJy7smsnKsx"},{"@type":"CROSSREF","@value":"10.1143/jpsj.57.1789_references_DOI_D9mGMziBQ75YrU7PiJy7smsnKsx"},{"@type":"CROSSREF","@value":"10.1246/bcsj.38.1804_references_DOI_D9mGMziBQ75YrU7PiJy7smsnKsx"},{"@type":"CROSSREF","@value":"10.1143/jpsj.56.1197_references_DOI_D9mGMziBQ75YrU7PiJy7smsnKsx"},{"@type":"CROSSREF","@value":"10.1143/jpsj.56.3808_references_DOI_D9mGMziBQ75YrU7PiJy7smsnKsx"},{"@type":"CROSSREF","@value":"10.1246/bcsj.67.1281_references_DOI_D9mGMziBQ75YrU7PiJy7smsnKsx"},{"@type":"CROSSREF","@value":"10.1143/jpsj.52.3700_references_DOI_D9mGMziBQ75YrU7PiJy7smsnKsx"},{"@type":"CROSSREF","@value":"10.1021/ic102461z_references_DOI_D9mGMziBQ75YrU7PiJy7smsnKsx"},{"@type":"CROSSREF","@value":"10.1246/bcsj.30.647_references_DOI_D9mGMziBQ75YrU7PiJy7smsnKsx"},{"@type":"CROSSREF","@value":"10.1246/bcsj.51.2334_references_DOI_D9mGMziBQ75YrU7PiJy7smsnKsx"},{"@type":"CROSSREF","@value":"10.4019/bjscc.57.36_references_DOI_D9mGMziBQ75YrU7PiJy7smsnKsx"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20110199_references_DOI_D9mGMziBQ75YrU7PiJy7smsnKsx"},{"@type":"CROSSREF","@value":"10.1021/acs.inorgchem.5b02980_references_DOI_D9mGMziBQ75YrU7PiJy7smsnKsx"}]}