{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360002219098445440.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/bcsj.39.316"}},{"identifier":{"@type":"URI","@value":"https://academic.oup.com/bcsj/article-pdf/39/2/316/55791078/bcsj.39.316.pdf"}},{"identifier":{"@type":"NAID","@value":"130001963237"}}],"dc:title":[{"@value":"The Reactions of <i>cis, trans, trans</i>-1, 5, 9-Cyclododecatriene. IV. Selective Reactions with <i>cis</i>-Addition Reagents"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title>\n               <jats:p>The addition reactions of cis, trans, trans-1, 5, 9-cyclododecatriene with cis-addition reagents, such as osmium tetroxide, potassium permanganate, diimide, and nitrosyl chloride, have been investigated. It has been shown that the first attack of each reagent preferentially takes place at one of the trans double bonds. The reactions with osmium tetroxide and potassium permanganate at room temperature afforded cis-5, trans-9-cyclododecadiene-trans-1, 2-diol in 89 and 59% yields respectively. The glycol was then further oxidized with osmium tetroxide into cis-y-9-cyclo-dodecene-1, 2, 5, 6-tetrol in a 60% yield. The reduction of the cyclotriene with diimide, generated in situ by the oxidation of hydrazine, afforded cis-cyclododecene in 60—82% yields. The addition of nitrosyl chloride in the presence of hydrochloric acid afforded 2-chlorocyclodode-cadienone oxime in a quantitative yield; this was then reduced into cyclododecanone oxime, obtained in a quantitative yield, by catalytic reduction with palladium-charcoal.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1582824502589406976","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020169468"}],"foaf:name":[{"@value":"Masaji Ohno"}],"jpcoar:affiliationName":[{"@value":"Basic Research Laboratories, Toyo Rayon Company Ltd"}]},{"@id":"https://cir.nii.ac.jp/crid/1582824502589406977","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020169477"}],"foaf:name":[{"@value":"Masaru Okamoto"}],"jpcoar:affiliationName":[{"@value":"Basic Research Laboratories, Toyo Rayon Company Ltd"}]},{"@id":"https://cir.nii.ac.jp/crid/1582824502589406978","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020169485"}],"foaf:name":[{"@value":"Seiichi Torimitsu"}],"jpcoar:affiliationName":[{"@value":"Basic Research Laboratories, Toyo Rayon Company Ltd"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00092673"},{"@type":"EISSN","@value":"13480634"}],"prism:publicationName":[{"@value":"Bulletin of the Chemical Society of Japan"}],"dc:publisher":[{"@value":"Oxford University Press (OUP)"}],"prism:publicationDate":"1966-02-01","prism:volume":"39","prism:number":"2","prism:startingPage":"316","prism:endingPage":"320"},"reviewed":"false","dc:rights":["https://academic.oup.com/pages/standard-publication-reuse-rights"],"url":[{"@id":"https://academic.oup.com/bcsj/article-pdf/39/2/316/55791078/bcsj.39.316.pdf"}],"createdAt":"2006-07-19","modifiedAt":"2024-01-18","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360855570366667008","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Selektive Hydroborierung von Olefinen"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137044197594240","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Reduktionen mit Diimid II"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137046298716544","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The Addition of Nitrosyl Halides to Olefins. Dependence of Steric Course on Olefin Structure"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544418619449344","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Equilibration of cis- and trans-Cycloalkenes<sup>1</sup>"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825894349900032","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Oligomerization of 1,3‐diolefines with ziegler‐type catalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825894655287680","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Notes- Method for the Cleavage of Osmate Esters"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107368467643264","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Elimination and Replacement Reactions of dl-erythro- and dl-threo-2-Deutero-1,2-diphenylethanol and Derivatives<sup>1,2</sup>"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107371078460288","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"CHEMISTRY OF DIIMIDE. II. STEREOCHEMISTRY OF HYDROGEN TRANSFER TO CARBON-CARBON MULTIPLE BONDS"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670319900153856","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Hydroboration. X. Rates of Reaction of Bis-3-methyl-2-butylborane with Representative Cycloalkenes and Isomeric cis-trans Alkenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951794382097536","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Zur Kenntnis des Kohlenstoffringes. 69. Mitteilung. Über die Reaktion von Cyclododecenen mit Perameisensäure"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1246/bcsj.39.316"},{"@type":"CIA","@value":"130001963237"}]}