{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360002219098890112.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/bcsj.42.1481"}},{"identifier":{"@type":"URI","@value":"https://academic.oup.com/bcsj/article-pdf/42/6/1481/55942518/bcsj.42.1481.pdf"}},{"identifier":{"@type":"NAID","@value":"130001978107"}}],"dc:title":[{"@value":"Photoemission from Polycyclic Aromatic Crystals in the Vacuum Ultraviolet Region. III. Aromatic Crystals and Charge-transfer Complexes"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title>\n               <jats:p>The photoemission from various types of charge-transfer complexes, quinolinium-tetra-cyanoquinodimethane Q(TCNQ2 (I), dibenzophenothiazine (DBP)-dicyanodichloro-p-benzoquinone (DDQ)[(DBP)(DDQ)(II) and (DBP)2(DDQ)(III)], trinitrobenzene (TNB)-coronene (IV), and TNB-perylene (V),and also large polycyclic aromatic hydrocarbons, violanthrene A (VI), violanthrene B (VII), coronene (VIII), pyranthrene (IX), and pyranthrone (X), was observed in the vacuum ultraviolet region. The experimental equation Y ∝(E–E*)3, where Y is the quantum yield of photoemission; E, the incident photon energy, and E*, the threshold energy, was used to determine the ionization potential. The E*-values, as estimated from the experimental equation, were I=4.85 eV, II 4.99, III 4.75, IV 5.62, V 5.52, VI 5.06, VII 5.13, VIII 5.58, IX 5.04, and X=5.71 eV. A band structure scheme for these organic semiconductors was introduced to analyse the emission mechanism.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1581698602700084096","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000021817359"}],"foaf:name":[{"@value":"Tomohiko Hirooka"}],"jpcoar:affiliationName":[{"@value":"The Institute for Solid State Physics, The University of Tokyo"}]},{"@id":"https://cir.nii.ac.jp/crid/1581698602700084098","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000021817364"}],"foaf:name":[{"@value":"Masakatsu Kochi"}],"jpcoar:affiliationName":[{"@value":"The Institute for Solid State Physics, The University of Tokyo"}]},{"@id":"https://cir.nii.ac.jp/crid/1581698602700084099","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000021817367"}],"foaf:name":[{"@value":"Jun-ichi Aihara"}],"jpcoar:affiliationName":[{"@value":"The Institute for Solid State Physics, The University of Tokyo"}]},{"@id":"https://cir.nii.ac.jp/crid/1581698602700084097","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000021817371"}],"foaf:name":[{"@value":"Hiroo Inokuchi"}],"jpcoar:affiliationName":[{"@value":"The Institute for Solid State Physics, The University of Tokyo"}]},{"@id":"https://cir.nii.ac.jp/crid/1581698602700084100","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000021817374"}],"foaf:name":[{"@value":"Yoshiya Harada"}],"jpcoar:affiliationName":[{"@value":"The Institute for Solid State Physics, The University of Tokyo"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00092673"},{"@type":"EISSN","@value":"13480634"}],"prism:publicationName":[{"@value":"Bulletin of the Chemical Society of Japan"}],"dc:publisher":[{"@value":"Oxford University Press (OUP)"}],"prism:publicationDate":"1969-06-01","prism:volume":"42","prism:number":"6","prism:startingPage":"1481","prism:endingPage":"1486"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","dc:rights":["https://academic.oup.com/pages/standard-publication-reuse-rights"],"url":[{"@id":"https://academic.oup.com/bcsj/article-pdf/42/6/1481/55942518/bcsj.42.1481.pdf"}],"createdAt":"2006-07-20","modifiedAt":"2024-01-19","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=General%20Chemistry","dc:title":"General Chemistry"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002219099758592","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Photoemission of Ion Radical Salts. Benzonitrile- and Triphenylene-Alkali Metal Complexes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011143884097408","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Solid State Ionization Potentials of Some Aromatic Organic Compounds"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292618817825920","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Photoelectric Emission from Donor-Acceptor Solids and Donor Molecules"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565169051711232","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Photoelectric Emission and Electrical Conductivity of the Cesium Complex with Pyrene Derivatives"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565169052606720","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Photoemission from Organic Crystal in Vacuum Ultraviolet Region. IV"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846644030665728","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Solid-state Properties of Evaporated Methyl Viologen"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846644036326656","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"VACUUM DEPOSITION OF A QUINOLINIUM(TCNQ)2 THIN FILM"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544421176635904","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"�ber das lichtelektrische Verhalten zusammengesetzter Oberfl�chenschichten bei tiefen Temperaturen"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107370928785408","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Theory of Photoelectric Emission from Semiconductors"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670319349461504","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Direct and Indirect Excitation Processes in Photoelectric Emission from Silicon"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670320088794880","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"�ber den Ursprung der an zusammengesetzten Photokathoden beobachteten mehrfachen spektralen Maxima auf Grund von spektralen Empfindlichkeitskurven bei 2930 und bei 830 abs"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951793636551168","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Photoelectric Emission of the Complexes between Cæsium and Polycyclic Aromatic Compounds"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204120307712","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Photoemission from Polycyclic Aromatic Crystals in the Vacuum Ultraviolet Region"},{"@value":"Photoemission from Polycyclic Aromatic Crystals in the Vacuum Ultraviolet Region. II"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204137462784","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Photoemission from Pyrene and its Derivatives"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679165368064","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Photoemission from an Anthracene Single Crystal Doped with Alkali-Metals"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1246/bcsj.42.1481"},{"@type":"CIA","@value":"130001978107"},{"@type":"OPENAIRE","@value":"doi_dedup___::24489aa74582a794e375aea5455cae69"},{"@type":"CROSSREF","@value":"10.1143/jpsj.28.701_references_DOI_TFmypaXnMNlmbbTWJ1guk7WzNl9"},{"@type":"CROSSREF","@value":"10.1246/bcsj.49.2407_references_DOI_TFmypaXnMNlmbbTWJ1guk7WzNl9"},{"@type":"CROSSREF","@value":"10.1246/cl.1972.835_references_DOI_TFmypaXnMNlmbbTWJ1guk7WzNl9"},{"@type":"CROSSREF","@value":"10.1246/bcsj.45.710_references_DOI_TFmypaXnMNlmbbTWJ1guk7WzNl9"},{"@type":"CROSSREF","@value":"10.1246/bcsj.48.1133_references_DOI_TFmypaXnMNlmbbTWJ1guk7WzNl9"},{"@type":"CROSSREF","@value":"10.1246/bcsj.43.2690_references_DOI_TFmypaXnMNlmbbTWJ1guk7WzNl9"}]}