{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360002219101415552.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/bcsj.53.3154"}},{"identifier":{"@type":"URI","@value":"https://academic.oup.com/bcsj/article-pdf/53/11/3154/56101608/bcsj.53.3154.pdf"}},{"identifier":{"@type":"NAID","@value":"130001988410"}}],"dc:title":[{"@value":"Hydrogenation Activity and Selectivity of Cobalt Boride and Cobalt Nickel Binary Boride Catalysts"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title>\n               <jats:p>Co–B catalyst has higher selectivity than Ni–B catalyst for the formation of α,β-unsaturated alcohols from α,β-unsaturated aldehydes and lower selectivity for the formation of olefins from acetylenes. The differences between the two catalysts can be ascribed to the differences in the adsorption strength of reactants on Co and Ni metals. The hydrogenation activities of the Co–Ni–B catalysts vary through a maximum, but the selectivities vary monotonously with nickel content. These features are explained in terms of the surface composition measured by XPS and of the surface area of the catalysts. The enrichment of nickel on the surface and the increase of the surface area are observed for the Co–Ni–B catalysts. Co–B catalysts modified by a small amount of metal salts (Fe, Cr, Cu, etc.) are more effective for the selective hydrogenation of α,β-unsaturated aldehydes than co-precipitated binary boride catalysts.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1580009752829285376","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020993087"}],"foaf:name":[{"@value":"Yuriko Nitta"}],"jpcoar:affiliationName":[{"@value":"Department of Chemical Engineering, Faculty of Engineering Science, Osaka University"}]},{"@id":"https://cir.nii.ac.jp/crid/1580009752829285378","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020993094"}],"foaf:name":[{"@value":"Toshinobu Imanaka"}],"jpcoar:affiliationName":[{"@value":"Department of Chemical Engineering, Faculty of Engineering Science, Osaka University"}]},{"@id":"https://cir.nii.ac.jp/crid/1580009752829285377","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020993099"}],"foaf:name":[{"@value":"Shiichiro Teranishi"}],"jpcoar:affiliationName":[{"@value":"Department of Chemical Engineering, Faculty of Engineering Science, Osaka University"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00092673"},{"@type":"EISSN","@value":"13480634"}],"prism:publicationName":[{"@value":"Bulletin of the Chemical Society of Japan"}],"dc:publisher":[{"@value":"Oxford University Press (OUP)"}],"prism:publicationDate":"1980-11-01","prism:volume":"53","prism:number":"11","prism:startingPage":"3154","prism:endingPage":"3158"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","dc:rights":["https://academic.oup.com/pages/standard-publication-reuse-rights"],"url":[{"@id":"https://academic.oup.com/bcsj/article-pdf/53/11/3154/56101608/bcsj.53.3154.pdf"}],"createdAt":"2006-07-20","modifiedAt":"2024-01-17","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002219101639680","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Partial Hydrogenation of Acetylenes on Modified Nickel Boride Catalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002219102756992","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Chemo-Selectivity of Group-VIII Metal Catalysts in Hydrogenation of Nonconjugated Enones"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002219109693952","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Excellent Activity of Ultrafine Co-B Amorphous Alloy Catalyst in Glucose Hydrogenation"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283694075596288","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Liquid-phase Selective Hydrogenation of an Aliphatic α,β-Unsaturated Aldehyde over Raney Cobalt Catalyst Modified with Ferrous Chloride"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565169053117696","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Kinetics of Liquid-phase Hydrogenation of Aliphatic α,β-Unsaturated Aldehyde over Raney Cobalt Catalyst Modified with Co-, Mn-, Ni-, and PdCl2"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565169053212160","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Study of the Poisoning Effect on Nickel and Nickel Boride Catalysts by Means of a Flow Microcalorimeter"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565169053762304","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Effects of Solvents and Added Amines on the Selective Hydrogenation of 2-Naphthol over Urushibara Nickel and Cobalt Catalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565169054577024","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A Comparative Study of Nickel and Cobalt Catalysts in the Hydrogenation of Substituted Acetophenones. Dependence of Hydrogenation Rate and Adsorption Strength on Substituents and Solvents"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565169060794368","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"HYDROGENATION OF 7-METHYLENEBICYCLO[3.3.1]NONAN-3-ONE OVER GROUP VIII METAL CATALYSTS. NOVEL REDUCTIVE CYCLIZATION"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846644035406080","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Influence of Residual Chloride Ions in Alumina-Supported Cobalt Catalysts on Catalytic Activity in Ketone and Aldehyde Hydrogenation"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855571155877248","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Surface state and catalytic activity and selectivity of nickel catalysts in hydrogenation reactions III. Electronic and catalytic properties of nickel catalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137045056856832","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Kinetics of liquid-phase hydrogenation of acetone over Raney nickel catalyst"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699994617396864","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Infrared spectral observation of the interaction of acetone with silica-supported Ni and Co"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825893722122752","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Hydrogenation of Aliphatic Nitriles over Transition Metal Borides"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233269070328192","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Surface characterisation of nickel boride and nickel phosphide catalysts by X-ray photoelectron spectroscopy"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001205122644096","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"ホウ化ニッケル触媒の耐被毒性"},{"@language":"en","@value":"Resistivity to the Poisoning of Nickel Boride Catalyst"},{"@language":"ja-Kana","@value":"ホウカ ニッケル ショクバイ ノ タイヒドクセイ ノート"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679099545216","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"The effect of crystallite size of nickel on the enantioselectivity of modified nickel catalysts."}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679114412544","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Kinetics of Liquid-phase Hydrogenation of Aliphatic α,β-Unsaturated Aldehyde over Raney Cobalt Catalyst"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282680098561280","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Selective Hydrogenation of Crotonal dehyde over Platinum Boride Catalyst"},{"@value":"ホウ化白金触媒の水素化活性とクロトンアルデヒドの選択的水素化反応"},{"@language":"ja-Kana","@value":"ホウカ ハッキン ショクバイ ノ スイソカ カッセイ ト クロトンアルデヒド ノ センタクテキ スイソカ ハンノウ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282680125828608","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Hydrogenation of Carbon Monoxide in the Presence of Borides of Nickel, Cobalt and Iron"},{"@value":"ニッケル,コパルト,および鉄のホウ化物を触媒とする一酸化炭素の還元"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282680126512384","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Adsorbed Hydrogen on Nickel Boride. Catalyst and Its Catalytic Activities in Hydrogenation Reactions"},{"@value":"ホウ化ニッケル触媒の水素化活性と吸着水素"}]},{"@id":"https://cir.nii.ac.jp/crid/1520291855788804224","@type":"Article","relationType":["isCitedBy"],"jpcoar:relatedTitle":[{"@value":"Influence of residual chloride ions in alumina-supported cobalt catalysts on catalytic activity in ketone and aldehyde hydrogenation"},{"@language":"ja-Kana","@value":"Influence of residual chloride ions in alumina supported cobalt catalysts on catalytic activity in ketone and aldehyde hydrogenation"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1246/bcsj.53.3154"},{"@type":"CIA","@value":"130001988410"},{"@type":"OPENAIRE","@value":"doi_dedup___::0aedd9203656e99226ba9dfa307e74cb"},{"@type":"CROSSREF","@value":"10.1246/bcsj.54.3579_references_DOI_YH3of5YNgXzEePyOZNQ2LgiShsd"},{"@type":"CROSSREF","@value":"10.1246/bcsj.81.653_references_DOI_YH3of5YNgXzEePyOZNQ2LgiShsd"},{"@type":"CROSSREF","@value":"10.1246/bcsj.60.1721_references_DOI_YH3of5YNgXzEePyOZNQ2LgiShsd"},{"@type":"CROSSREF","@value":"10.1246/cl.1999.629_references_DOI_YH3of5YNgXzEePyOZNQ2LgiShsd"},{"@type":"CROSSREF","@value":"10.1246/cl.1983.771_references_DOI_YH3of5YNgXzEePyOZNQ2LgiShsd"},{"@type":"CROSSREF","@value":"10.1246/bcsj.54.980_references_DOI_YH3of5YNgXzEePyOZNQ2LgiShsd"}]}