{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360002219102113152.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/bcsj.56.775"}},{"identifier":{"@type":"URI","@value":"https://academic.oup.com/bcsj/article-pdf/56/3/775/55672452/bcsj.56.775.pdf"}},{"identifier":{"@type":"NAID","@value":"130001985414"}}],"dc:title":[{"@value":"The Synthesis of 2,7-Bis(dimethylamino)pyrene and -tetrahydropyrene and the Electrical Conductivities of Their Complexes"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title>\n               <jats:p>New π-donors containing a pyrene or a tetrahydropyrene ring were synthesized by means of a unique transannular reaction of the corresponding [2.2]metacylcophane derivatives. The CT complexes of these donors with a series of TCNQ derivatives different in electron affinity were prepared, and their electrical conductivities on single crystals were measured. The highest conductivity (0.36 Ω−1 cm−1) was that of the tetrahydropyrene derivative-TCNQ complex. It was reconfirmed that the partial charge-transfer from a donor to an acceptor is very important for high conductivity.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1420001326216826368","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"10193806"},{"@type":"NRID","@value":"1000010193806"},{"@type":"NRID","@value":"9000003649205"},{"@type":"NRID","@value":"9000021772925"},{"@type":"NRID","@value":"9000364939008"},{"@type":"NRID","@value":"9000021833718"},{"@type":"NRID","@value":"9000283788043"},{"@type":"NRID","@value":"9000008573120"}],"foaf:name":[{"@value":"Naomi Ueda"}],"jpcoar:affiliationName":[{"@value":"The Institute of Scientific and Industrial Research, Osaka University"}]},{"@id":"https://cir.nii.ac.jp/crid/1582261552642899584","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000021833724"}],"foaf:name":[{"@value":"Bunji Natsume"}],"jpcoar:affiliationName":[{"@value":"The Institute of Scientific and Industrial Research, Osaka University"}]},{"@id":"https://cir.nii.ac.jp/crid/1582261552642899585","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000021833729"}],"foaf:name":[{"@value":"Kazumi Yanagiuchi"}],"jpcoar:affiliationName":[{"@value":"The Institute of Scientific and Industrial Research, Osaka University"}]},{"@id":"https://cir.nii.ac.jp/crid/1582261552642899590","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000021833736"}],"foaf:name":[{"@value":"Yoshiteru Sakata"}],"jpcoar:affiliationName":[{"@value":"The Institute of Scientific and Industrial Research, Osaka University"}]},{"@id":"https://cir.nii.ac.jp/crid/1582261552642899588","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000021833742"}],"foaf:name":[{"@value":"Toshiaki Enoki"}],"jpcoar:affiliationName":[{"@value":"The Institute for Molecular Science"}]},{"@id":"https://cir.nii.ac.jp/crid/1582261552642899587","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000021833749"}],"foaf:name":[{"@value":"Gunzi Saito"}],"jpcoar:affiliationName":[{"@value":"The Institute for Molecular Science"}]},{"@id":"https://cir.nii.ac.jp/crid/1582261552642899586","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000021833755"}],"foaf:name":[{"@value":"Hiroo Inokuchi"}],"jpcoar:affiliationName":[{"@value":"The Institute for Molecular Science"}]},{"@id":"https://cir.nii.ac.jp/crid/1582261552642899591","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000021833761"}],"foaf:name":[{"@value":"Soichi Misumi"}],"jpcoar:affiliationName":[{"@value":"The Institute of Scientific and Industrial Research, Osaka University"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00092673"},{"@type":"EISSN","@value":"13480634"}],"prism:publicationName":[{"@value":"Bulletin of the Chemical Society of Japan"}],"dc:publisher":[{"@value":"Oxford University Press (OUP)"}],"prism:publicationDate":"1983-03-01","prism:volume":"56","prism:number":"3","prism:startingPage":"775","prism:endingPage":"779"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","dc:rights":["https://academic.oup.com/pages/standard-publication-reuse-rights"],"url":[{"@id":"https://academic.oup.com/bcsj/article-pdf/56/3/775/55672452/bcsj.56.775.pdf"}],"createdAt":"2006-07-26","modifiedAt":"2024-01-18","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002219096779520","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Ionicity Phase Diagram of Trifluoromethyl-TCNQ (CF3TCNQ) Charge-Transfer Solids"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002219100497792","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Solvent Inclusion Effects on the Structure and Electrical Conductivity of Benzidine-TCNQ Complex"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011145462637184","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Some chemistry of compounds related to [2.2]metacyclophane"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283694078064000","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Requirements for an “Organic Metal”"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699993446835456","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Degree of charge transfer in organic conductors by infrared absorption spectroscopy"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981469438726400","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"<b>Substituted Quinodimethans. 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