{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360002219102484992.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/bcsj.58.447"}},{"identifier":{"@type":"URI","@value":"https://academic.oup.com/bcsj/article-pdf/58/2/447/55712116/bcsj.58.447.pdf"}},{"identifier":{"@type":"NAID","@value":"130001983905"}},{"identifier":{"@type":"URI","@value":"https://search.jamas.or.jp/link/ui/1985142045"}}],"dc:title":[{"@value":"A New Synthetic Model for Myoglobin: “Tulip Garden” Porphyrin"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title>\n               <jats:p>A new model compound “tulip garden” porphyrin, has a long half-lifetime, thus satisfying the demand for the synthetic analogue of myoglobin. At the same time, “tulip garden” porphyrin has high O2 affinities as compared to other protected porphyrins; especially, its Co(II) complex shows almost the same affinity (P1/2O2) as coboglobins. The difference in oxygen affinities between “tulip garden” and “picket fence-type” porphyrins can be ascribed to the bulkiness of pendant groups. The strong “side” influence of the adamantyl group can be expected to bring about a high O2 affinity.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1420845751142540672","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"70206720"},{"@type":"NRID","@value":"1000070206720"},{"@type":"NRID","@value":"9000000818463"},{"@type":"NRID","@value":"9000318158342"},{"@type":"NRID","@value":"9000388508650"},{"@type":"NRID","@value":"9000253126900"},{"@type":"NRID","@value":"9000010703186"},{"@type":"NRID","@value":"9000241517216"},{"@type":"NRID","@value":"9000257720488"},{"@type":"NRID","@value":"9000004630196"},{"@type":"NRID","@value":"9000256837641"},{"@type":"NRID","@value":"9000401734635"},{"@type":"NRID","@value":"9000257718463"},{"@type":"NRID","@value":"9000412120923"},{"@type":"NRID","@value":"9000257699599"},{"@type":"NRID","@value":"9000258179499"},{"@type":"NRID","@value":"9000021808588"},{"@type":"NRID","@value":"9000402620053"},{"@type":"NRID","@value":"9000256030953"},{"@type":"NRID","@value":"9000021865038"},{"@type":"NRID","@value":"9000020990532"},{"@type":"NRID","@value":"9000009786401"},{"@type":"NRID","@value":"9000388508642"},{"@type":"NRID","@value":"9000001423274"},{"@type":"NRID","@value":"9000107392068"},{"@type":"NRID","@value":"9000021804483"},{"@type":"NRID","@value":"9000256012690"},{"@type":"NRID","@value":"9000241575925"},{"@type":"NRID","@value":"9000402442832"},{"@type":"NRID","@value":"9000256024028"},{"@type":"NRID","@value":"9000408802918"},{"@type":"NRID","@value":"9000252802572"},{"@type":"NRID","@value":"9000007296649"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0011646"}],"foaf:name":[{"@value":"Shigeru 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