{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360002219104043136.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/bcsj.67.2336"}},{"identifier":{"@type":"URI","@value":"https://academic.oup.com/bcsj/article-pdf/67/8/2336/56226925/bcsj.67.2336.pdf"}},{"identifier":{"@type":"DOI","@value":"10.1002/chin.199504092"}},{"identifier":{"@type":"NAID","@value":"130004148901"}}],"dc:title":[{"@value":"Side-Chain Bromination of Diphenylmethanes, 1,2-Diphenylethanes, and 10,11-Dihydro-5<i>H</i>-dibenzo[<i>a</i>,<i>d</i>]cycloheptenes with <i>N</i>-Bromosuccinimide under Irradiation of a Tungsten Lamp"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title>\n               <jats:p>The photothermal bromination of diphenylmethane and methyl derivatives with N-bromosuccinimide afforded benzophenone and (polybromomethyl)benzophenones via the hydrolysis of dibromodiphenylmethanes. 1,2-Diphenylethane and p-t-butyl derivative gave dibromostilbenes, while the o-methyl derivative afforded bis(dibromomethyl)dibromodiphenylethane. 10,11-Dihydro-5H-dibenzo[a,d]cycloheptene gave 9-bromodibenzocycloheptenone, which was also obtained in the bromination of 10,11-dihydro-5H-dibenzo[a,d]cyclohepten-5-one.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1582824503280145664","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000256012410"}],"foaf:name":[{"@value":"Shuntaro Mataka"}],"jpcoar:affiliationName":[{"@value":"Institute of Advanced Material Study, Kyushu University6-1 Kasuga-kohen, Kasuga 816"}]},{"@id":"https://cir.nii.ac.jp/crid/1582824503280145666","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000256012411"}],"foaf:name":[{"@value":"Guo-Bin Liu"}],"jpcoar:affiliationName":[{"@value":"Department of Molecular Science and Technology, Graduate School of Engineering Sciences, Kyushu University6-1 Kasuga-kohen, Kasuga 816"}]},{"@id":"https://cir.nii.ac.jp/crid/1582824503280145665","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000256012412"}],"foaf:name":[{"@value":"Akiyoshi Tori-i"}],"jpcoar:affiliationName":[{"@value":"Kurume National College of Technology1342, Komorino, Kurume 830"}]},{"@id":"https://cir.nii.ac.jp/crid/1582824503280145667","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000256012413"}],"foaf:name":[{"@value":"Masashi Tashiro"}],"jpcoar:affiliationName":[{"@value":"Institute of Advanced Material Study, Kyushu University6-1 Kasuga-kohen, Kasuga 816"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00092673"},{"@type":"EISSN","@value":"13480634"},{"@type":"PISSN","@value":"09317597"},{"@type":"EISSN","@value":"15222667"}],"prism:publicationName":[{"@value":"Bulletin of the Chemical Society of Japan"}],"dc:publisher":[{"@value":"Oxford University Press (OUP)"}],"prism:publicationDate":"1994-08-01","prism:volume":"67","prism:number":"8","prism:startingPage":"2336","prism:endingPage":"2338"},"reviewed":"false","dc:rights":["https://academic.oup.com/pages/standard-publication-reuse-rights"],"url":[{"@id":"https://academic.oup.com/bcsj/article-pdf/67/8/2336/56226925/bcsj.67.2336.pdf"}],"createdAt":"2006-07-28","modifiedAt":"2024-01-19","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360011143761704064","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"<b>The Identity of the Chain-Carrying Species in Brominations with N-Bromosuccinimide: Selectivity of Substituted N-Bromosuccinimides toward Substituted Toluenes</b>"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846644034118784","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Photothermal Side-Chain Bromination of Methyl-, Dimethyl-, and Trimethylbenzenes with <i>N</i>-Bromosuccinimide"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981469640601984","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Über das 2.3;6.7‐Dibenz‐suberon‐(1), II. Mitteil.Synthese des 2.3;6.7‐Dibenz‐suberen‐(4)‐ons‐(1) und des 2.3;6.7‐Dibenz‐suberens‐(4)"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262945514976128","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"<b>Directive Effects in Aliphatic Substitutions. XIX. Photobromination with N-Bromosuccinimide</b>"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107368424227584","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"N-Bromosuccinimide as a Dehydrogenating Agent<sup>1</sup>"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001205122721280","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Synthesis and Reactions of Polymers Containing <I>N</I>-Bromosuccinimide Structure"},{"@value":"高分子<I>N</I>-ブロム化合物の合成と反応"},{"@language":"ja-Kana","@value":"コウブンシ N-ブロム カゴウブツ ノ ゴウセイ ト ハンノウ"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1246/bcsj.67.2336"},{"@type":"CIA","@value":"130004148901"},{"@type":"OPENAIRE","@value":"doi_dedup___::91f9a63cf955ed3a75edd7f7bd23d153"}]}