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Their butterfly‐shapes, conformations, photophysical properties (UV‐vis absorption, fluorescence), and redox properties were elucidated by X‐ray analysis, DFT calculations, spectral and electrochemical measurements. Fluorescent hydrazine‐embedded biphenothiazine sulfoxides and bicarbazoles were applied to cell imaging of HeLa cells. The bicarbazoles exhibited high fluorescence signals in the cells with low toxicity.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380004229894870150","@type":"Researcher","foaf:name":[{"@value":"Yuri Shindo"}],"jpcoar:affiliationName":[{"@value":"Department of Applied Chemistry Faculty of Science and Technology Keio University  3-14-1 Hiyoshi, Kohoku-ku Yokohama 223-8522 Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004229894870160","@type":"Researcher","foaf:name":[{"@value":"Shogo Nomura"}],"jpcoar:affiliationName":[{"@value":"Biofunctional Synthetic Chemistry Laboratory RIKEN Cluster for Pioneering Research, RIKEN  2-1 Hirosawa, Wako-shi Saitama 351-0198 Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004229894870017","@type":"Researcher","foaf:name":[{"@value":"Yoko Saikawa"}],"jpcoar:affiliationName":[{"@value":"Department of Applied Chemistry Faculty of Science and Technology Keio University  3-14-1 Hiyoshi, Kohoku-ku Yokohama 223-8522 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