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Complexation of L<jats:sup>1</jats:sup>H<jats:sub>2</jats:sub> with Pd(OAc)<jats:sub>2</jats:sub> was demonstrated to afford the dipeptide–palladium(II) conjugated complex [(L<jats:sup>1</jats:sup>)Pd(MeCN)] (<jats:bold>1</jats:bold>) with an ancillary acetonitrile ligand. In the crystal packing of <jats:bold>1</jats:bold>, a right‐handed helical‐like molecular arrangement was observed, wherein each assembly is connected through continuous intermolecular hydrogen bonds together with water molecules. The dipeptide–palladium(II) conjugated complex <jats:bold>1</jats:bold> was studied as a metalloreceptor through metal coordination to accommodate a guest ligand, 4‐aminopyridine, resulting in the formation of the dipeptide–palladium(II) conjugated complex [(L<jats:sup>1</jats:sup>)Pd(4APy)] (<jats:bold>2</jats:bold>). Each preorganized helical molecule of <jats:bold>2</jats:bold> is packed in a right‐handed helical‐like molecular arrangement in the crystal packing. The dipeptide–palladium(II) conjugated complex <jats:bold>2</jats:bold> was found to exhibit emission with a maximum at 652 nm in the solid state.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380004230098416521","@type":"Researcher","foaf:name":[{"@value":"Toshiyuki Moriuchi"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004230098416516","@type":"Researcher","foaf:name":[{"@value":"Kunihiro Morimoto"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004230098416396","@type":"Researcher","foaf:name":[{"@value":"Yuki Sakamoto"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004230098416770","@type":"Researcher","foaf:name":[{"@value":"Toshikazu Hirao"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"14341948"},{"@type":"EISSN","@value":"10990682"}],"prism:publicationName":[{"@value":"European Journal of Inorganic Chemistry"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2012-05-31","prism:volume":"2012","prism:number":"29","prism:startingPage":"4669","prism:endingPage":"4674"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fejic.201200155"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.201200155"},{"@id":"https://onlinelibrary.wiley.com/doi/full-xml/10.1002/ejic.201200155"},{"@id":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.201200155"}],"createdAt":"2012-05-31","modifiedAt":"2025-10-13","project":[{"@id":"https://cir.nii.ac.jp/crid/1040000782189958400","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"24108722"},{"@type":"JGN","@value":"JP24108722"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-24108722/"}],"notation":[{"@language":"ja","@value":"核酸塩基の自己組織化に基づく配位プログラムを活用した高次配列制御"}]},{"@id":"https://cir.nii.ac.jp/crid/1040282257117871488","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"23111711"},{"@type":"JGN","@value":"JP23111711"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-23111711/"}],"notation":[{"@language":"ja","@value":"生体分子の空間制御集積化を基軸とする動的金属錯体ナノシステムの創発"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050282677536278656","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Enhancement of the photoluminescence of a thioamide-based pincer palladium complex in the crystalline state"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011143858758016","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Light-Emitting Cyclopalladated Complexes of 6-Phenyl-2,2‘-bipyridines with Hydrogen-Bonding Functionality"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011144034930560","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Ordered conformations in bis(amino acid) derivatives of 1,1′-ferrocenedicarboxylic acid"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011144652893312","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Chirality Organization of Ferrocenes Bearing Dipeptide Chains of Heterochiral Sequence"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011144895987840","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Spectroscopic and Theoretical Study of Asymmetric 1,1′-Diaminoferrocene Conjugates of α-Amino Acids"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011145933020672","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"How Useful Is Ferrocene as a Scaffold for the Design of β‐Sheet Foldamers?"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283694085703168","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"An Efficient Epoxidation with Molecular Oxygen Catalyzed by Iron Complex of Multidentate <i>N</i>-Heterocyclic Podand Ligand. 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