{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360004231397494656.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1007/s10967-018-5882-5"}},{"identifier":{"@type":"URI","@value":"http://link.springer.com/article/10.1007/s10967-018-5882-5/fulltext.html"}},{"identifier":{"@type":"URI","@value":"http://link.springer.com/content/pdf/10.1007/s10967-018-5882-5.pdf"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Extraction behavior of Mo and W from H2SO4 and HF/HCl solutions into toluene with Aliquat336: sulfate and fluoride complex formation of Mo and W towards chemical studies of seaborgium (Sg)"}],"description":[{"notation":[{"@value":"We have studied extraction behavior of group-6 elements Mo and W to search for suitable conditions for an on-line extraction experiment of their heavier homolog, seaborgium (Sg). Batch-wise extraction of carrier-free radiotracers 93mMo and 177,179,181W were carried out from 0.10 – 8.6 M H2SO4 and 1.0 × 10−4 − 5.0 M HF/1.0 M HCl into toluene with a quaternary ammonium compound, Aliquat336. Anionic sulfate complexes of Mo and W with charge − 2 were extracted with Aliquat336 from H2SO4 solutions with concentrations of [H2SO4] > 2 M. In HF/1.0 M HCl, oxyfluoro complexes of Mo and W with charge − 1 were interpreted to be formed and extracted with Aliquat336. From these results, favorable conditions for the extraction of Sg are discussed."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380004231397494656","@type":"Researcher","foaf:name":[{"@value":"Atsushi Toyoshima"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004231397494787","@type":"Researcher","foaf:name":[{"@value":"Akina Mitsukai"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004231397494791","@type":"Researcher","foaf:name":[{"@value":"Kazuaki Tsukada"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004231397494659","@type":"Researcher","foaf:name":[{"@value":"Kazuhiro Ooe"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004231397494661","@type":"Researcher","foaf:name":[{"@value":"Hiromitsu Haba"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004231397494535","@type":"Researcher","foaf:name":[{"@value":"Yukiko Komori"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004231397494793","@type":"Researcher","foaf:name":[{"@value":"Masashi Murakami"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004231397494537","@type":"Researcher","foaf:name":[{"@value":"Yusuke Kaneya"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004231397494667","@type":"Researcher","foaf:name":[{"@value":"Daisuke Sato"}]},{"@id":"https://cir.nii.ac.jp/crid/1420564276171608576","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"20343931"},{"@type":"NRID","@value":"1000020343931"},{"@type":"NRID","@value":"9000398813779"},{"@type":"NRID","@value":"9000258299280"},{"@type":"NRID","@value":"9000242830854"},{"@type":"NRID","@value":"9000396134425"},{"@type":"NRID","@value":"9000256029081"},{"@type":"NRID","@value":"9000414366814"},{"@type":"NRID","@value":"9000021538452"},{"@type":"NRID","@value":"9000415064589"},{"@type":"NRID","@value":"9000256027524"},{"@type":"NRID","@value":"9000264238230"},{"@type":"NRID","@value":"9000290378203"},{"@type":"NRID","@value":"9000415083213"},{"@type":"NRID","@value":"9000380482511"},{"@type":"NRID","@value":"9000413743317"},{"@type":"NRID","@value":"9000415325472"},{"@type":"NRID","@value":"9000021646387"},{"@type":"NRID","@value":"9000239561170"},{"@type":"NRID","@value":"9000410181521"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/asai_masato"}],"foaf:name":[{"@value":"Masato Asai"}]},{"@id":"https://cir.nii.ac.jp/crid/1420001326231619200","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"40370382"},{"@type":"NRID","@value":"1000040370382"},{"@type":"KAKEN_RESEARCHERS","@value":"40370328"},{"@type":"NRID","@value":"9000388517665"},{"@type":"NRID","@value":"9000316206342"},{"@type":"NRID","@value":"9000402026393"},{"@type":"NRID","@value":"9000415083212"},{"@type":"NRID","@value":"9000413743314"},{"@type":"NRID","@value":"9000415325511"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/tetsuyaks"}],"foaf:name":[{"@value":"Tetsuya K. 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