{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360004231452927488.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1007/s11356-014-2985-6"}},{"identifier":{"@type":"URI","@value":"http://link.springer.com/content/pdf/10.1007/s11356-014-2985-6.pdf"}},{"identifier":{"@type":"URI","@value":"http://link.springer.com/article/10.1007/s11356-014-2985-6/fulltext.html"}},{"identifier":{"@type":"URI","@value":"http://link.springer.com/content/pdf/10.1007/s11356-014-2985-6"}},{"identifier":{"@type":"PMID","@value":"24809497"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Polychlorinated biphenyl contamination of paints containing polycyclic- and Naphthol AS-type pigments"}],"description":[{"notation":[{"@value":"This study reports the concentrations and congener partners of polychlorinated biphenyls (PCBs) in commercially available paints. Polycyclic-type pigments containing dioxazine violet (pigment violet (PV) 23, PV37) and diketopyrrolopyrrole (PR254, PR255) were found to contain PCB-56, PCB-77, PCB-40, PCB-5, and PCB-12, and PCB-6, PCB-13, and PCB-15, respectively, as major congeners. Dioxazine violet is contaminated with by-products during synthesis from o-dichlorobenzene, which is used as a solvent during synthesis, and diketopyrrolopyrrole is contaminated with by-products during synthesis from p-chlorobenzonitrile. The concentration of PCBs in paint containing PV23 or PV37 was 0.050-29 mg/kg, and toxic equivalency (TEQ) values ranged 1.1-160 pg-TEQ/g. The concentration of PCBs in paint containing PR254 or PR255 was 0.0019-2.4 mg/kg. Naphthol AS is an azo-type pigment, and PCB-52 was detected in paint containing pigment red (PR) 9 with 2,5-dichloroaniline as its source. PCB-146, PCB-149, and PCB-153 were identified from paint containing PR112 produced from 2,4,5-trichloroaniline, as major congeners. These congeners have chlorine positions similar to aniline, indicating that these congeners are by-products obtained during the synthesis of pigments. The concentrations of PCBs in paints containing PR9 and PR112 were 0.0042-0.43 and 0.0044-3.8 mg/kg, respectively. The corresponding TEQ for PR112 was 0.0039-8.6 pg-TEQ/g."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1420845751159666176","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"20442634"},{"@type":"NRID","@value":"1000020442634"},{"@type":"NRID","@value":"9000000090794"},{"@type":"NRID","@value":"9000006495005"},{"@type":"NRID","@value":"9000399182571"},{"@type":"NRID","@value":"9000010434342"},{"@type":"NRID","@value":"9000257787350"},{"@type":"NRID","@value":"9000257788441"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0080761"}],"foaf:name":[{"@value":"Katsunori Anezaki"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004231452927504","@type":"Researcher","foaf:name":[{"@value":"Narayanan Kannan"}]},{"@id":"https://cir.nii.ac.jp/crid/1420564276169601664","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"00446791"},{"@type":"NRID","@value":"1000000446791"},{"@type":"NRID","@value":"9000003013274"},{"@type":"NRID","@value":"9000256099424"},{"@type":"NRID","@value":"9000256096367"},{"@type":"NRID","@value":"9000262356798"},{"@type":"NRID","@value":"9000256060566"},{"@type":"NRID","@value":"9000256098891"},{"@type":"NRID","@value":"9000257912215"},{"@type":"NRID","@value":"9000256096963"},{"@type":"NRID","@value":"9000345217814"},{"@type":"NRID","@value":"9000255711893"},{"@type":"NRID","@value":"9000257915125"},{"@type":"NRID","@value":"9000256097530"},{"@type":"NRID","@value":"9000345217750"},{"@type":"NRID","@value":"9000367832800"},{"@type":"NRID","@value":"9000387431102"},{"@type":"NRID","@value":"9000345217824"},{"@type":"NRID","@value":"9000345217733"},{"@type":"NRID","@value":"9000396160436"},{"@type":"NRID","@value":"9000319556282"},{"@type":"NRID","@value":"9000345349378"},{"@type":"NRID","@value":"9000345266547"},{"@type":"NRID","@value":"9000255723550"},{"@type":"NRID","@value":"9000256061801"},{"@type":"NRID","@value":"9000258216325"},{"@type":"NRID","@value":"9000378064507"},{"@type":"NRID","@value":"9000337097824"},{"@type":"NRID","@value":"9000256096207"},{"@type":"NRID","@value":"9000257187021"},{"@type":"NRID","@value":"9000237897796"},{"@type":"NRID","@value":"9000257912221"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/takeshi.nakano"}],"foaf:name":[{"@value":"Takeshi Nakano"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"09441344"},{"@type":"EISSN","@value":"16147499"}],"prism:publicationName":[{"@value":"Environmental Science and Pollution Research"}],"dc:publisher":[{"@value":"Springer Science and Business Media LLC"}],"prism:publicationDate":"2014-05-10","prism:volume":"22","prism:number":"19","prism:startingPage":"14478","prism:endingPage":"14488"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","dc:rights":["http://www.springer.com/tdm"],"url":[{"@id":"http://link.springer.com/content/pdf/10.1007/s11356-014-2985-6.pdf"},{"@id":"http://link.springer.com/article/10.1007/s11356-014-2985-6/fulltext.html"},{"@id":"http://link.springer.com/content/pdf/10.1007/s11356-014-2985-6"}],"createdAt":"2014-05-09","modifiedAt":"2019-06-01","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Molecular%20Structure","dc:title":"Molecular Structure"},{"@id":"https://cir.nii.ac.jp/all?q=Naphthols","dc:title":"Naphthols"},{"@id":"https://cir.nii.ac.jp/all?q=Polychlorinated%20Biphenyls","dc:title":"Polychlorinated Biphenyls"},{"@id":"https://cir.nii.ac.jp/all?q=Gas%20Chromatography-Mass%20Spectrometry","dc:title":"Gas Chromatography-Mass Spectrometry"},{"@id":"https://cir.nii.ac.jp/all?q=Limit%20of%20Detection","dc:title":"Limit of Detection"},{"@id":"https://cir.nii.ac.jp/all?q=Paint","dc:title":"Paint"},{"@id":"https://cir.nii.ac.jp/all?q=Environmental%20Pollutants","dc:title":"Environmental Pollutants"},{"@id":"https://cir.nii.ac.jp/all?q=Polycyclic%20Aromatic%20Hydrocarbons","dc:title":"Polycyclic Aromatic Hydrocarbons"},{"@id":"https://cir.nii.ac.jp/all?q=Coloring%20Agents","dc:title":"Coloring Agents"}],"project":[{"@id":"https://cir.nii.ac.jp/crid/1040000782225833984","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"24710016"},{"@type":"JGN","@value":"JP24710016"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-24710016/"}],"notation":[{"@language":"ja","@value":"新規ＰＣＢ汚染源の解明と定量的評価方法の確立に関する研究"},{"@language":"en","@value":"Research for the clarification of new PCB pollutants and the establishment of a quantitative evaluation method"}]},{"@id":"https://cir.nii.ac.jp/crid/1040000782263942528","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"25513003"},{"@type":"JGN","@value":"JP25513003"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-25513003/"}],"notation":[{"@language":"ja","@value":"新規の吸着剤の開発と環境モニタリングへの応用"},{"@language":"en","@value":"Development of Novel Adsorbent and Application for Environmental Monitoring"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002215443495936","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"The need for better management and control of POPs stockpiles"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004232532446208","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Characterization of steroid hormone receptor activities in 100 hydroxylated polychlorinated biphenyls, including congeners identified in humans"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011143753283712","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Complete characterization of polychlorinated biphenyl congeners in commercial Aroclor and Clophen mixtures by multidimensional gas chromatography-electron capture detection"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011145158499712","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Partial Pressures of PCB-11 in Air from Several Great Lakes Sites"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011145266784640","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"PBDEs and PCBs in sediments of the Thi Nai Lagoon (Central Vietnam) and soils from its mainland"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011145684408576","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Complete PCB congener distributions for 17 aroclor mixtures determined by 3 HRGC systems optimized for comprehensive, quantitative, congener‐specific analysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1360021389801150720","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"The first full-congener analysis of 209 polychlorinated biphenyls (PCBs) in the blubber of short-finned pilot whales (Globicephala macrorhynchus) stranded along the coast of Savu Island, Indonesia"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283690891330816","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Effects of unintentional PCBs in pigments and chemical products on transcriptional activity via aryl hydrocarbon and nuclear hormone receptors"}]},{"@id":"https://cir.nii.ac.jp/crid/1360290617556265472","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Characterization of mono- to deca-chlorinated biphenyls in a well-preserved sediment core from Beppu Bay, Southwestern Japan: Historical profiles, emission sources, and inventory"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565165396546432","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Concentration levels and congener profiles of polychlorinated biphenyls, pentachlorobenzene, and hexachlorobenzene in commercial pigments"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183076724352","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Estimation of Polychlorinated Biphenyl Sources in Industrial Port Sediments Using a Bayesian Semifactor Model Considering Unidentified Sources"}]},{"@id":"https://cir.nii.ac.jp/crid/1360572092460432768","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Unintentionally produced polychlorinated biphenyls in pigments: An updated review on their formation, emission sources, contamination status, and toxic effects"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574096400305920","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Source Apportionment of Polychlorinated Biphenyls in the Tidal Delaware River"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846641536069888","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Enantioselectivity of 2,2′,3,5′,6-Pentachlorobiphenyl (PCB 95) Atropisomers toward Ryanodine Receptors (RyRs) and Their Influences on Hippocampal Neuronal Networks"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848657209888512","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Unintentional PCB in chlorophenylsilanes as a source of contamination in environmental samples"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855569455943040","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Mono-hydroxylated polychlorinated biphenyls are potent aryl hydrocarbon receptor ligands in recombinant yeast cells"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855569469337728","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Industrial Organic Pigments"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418519047924608","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Source Apportionment of Polychlorinated Biphenyls in Chicago Air from 1996 to 2007"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418521471814144","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Structural Requirements for the Interaction of 91 Hydroxylated Polychlorinated Biphenyls with Estrogen and Thyroid Hormone Receptors"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981469999260288","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The presence of polychlorinated biphenyls in yellow pigment products in China with emphasis on 3,3′-dichlorobiphenyl (PCB 11)"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262943922295680","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Source Apportionment of Polychlorinated Biphenyls in the Sediments of the Delaware River"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262944132945536","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Preparation of a sulfoxide group and ammonium-salt bonded silica stationary phase for separation of polychlorinated biphenyls from mineral oils"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544418573772288","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Identification of a novel PCB source through analysis of 209 PCB congeners by US EPA modified method 1668"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825894851067904","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Evidence for Unique and Ubiquitous Environmental Sources of 3,3′-Dichlorobiphenyl (PCB 11)"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107368317759616","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"High Performance Pigments"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388844825902720","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Study of PCBs and PBDEs in King George Island, Antarctica, using PUF passive air sampling"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670320190554880","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Industrial Inorganic Pigments"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670320246813312","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Air−Water Exchange of Polychlorinated Biphenyls in the Delaware River"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670320555244672","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Inadvertent Polychlorinated Biphenyls in Commercial Paint Pigments"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670320823761920","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Tracing the source of 3,3′-dichlorobiphenyl found in samples collected in and around Halifax Harbour"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951794661381632","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Discovery of Non-Aroclor PCB (3,3′-Dichlorobiphenyl) in Chicago Air"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204369579648","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"All Congener Specific Analytical Method for Polychlorinated Biphenyls(PCBs) with Various Chromotographic Clean-up and HRGC/HRMS."},{"@value":"各種クリーンアップ法とＨＲＧＣ／ＨＲＭＳを用いたポリ塩化ビフェニル（ＰＣＢｓ）の全異性体詳細分析方法"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679346089088","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Elution Orders of All 209PCBs Congeners on Capillary Column \"HT8-PCB\""},{"@value":"キャピラリーカラム（ＨＴ８‐ＰＣＢ）によるＰＣＢ全２０９異性体の溶出順位"},{"@language":"ja-Kana","@value":"キャピラリー カラム HT8 PCB ニ ヨル PCB ゼン 209 イセイタイ ノ ヨウシュツ ジュンイ"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1007/s11356-014-2985-6"},{"@type":"KAKEN","@value":"PRODUCT-14823383"},{"@type":"KAKEN","@value":"PRODUCT-15096679"},{"@type":"OPENAIRE","@value":"doi_dedup___::0857faa547799a3c70b4591bbd853d13"},{"@type":"CROSSREF","@value":"10.1007/s11356-015-5162-7_references_DOI_OmRCZvwKPseonEZKDqBVTyNDDXi"},{"@type":"CROSSREF","@value":"10.1016/j.scitotenv.2023.163008_references_DOI_OmRCZvwKPseonEZKDqBVTyNDDXi"},{"@type":"CROSSREF","@value":"10.1016/j.envpol.2017.04.059_references_DOI_OmRCZvwKPseonEZKDqBVTyNDDXi"},{"@type":"CROSSREF","@value":"10.1016/j.scitotenv.2020.140767_references_DOI_OmRCZvwKPseonEZKDqBVTyNDDXi"},{"@type":"CROSSREF","@value":"10.1016/j.scitotenv.2020.142504_references_DOI_OmRCZvwKPseonEZKDqBVTyNDDXi"},{"@type":"CROSSREF","@value":"10.1021/acs.est.5b03501_references_DOI_OmRCZvwKPseonEZKDqBVTyNDDXi"},{"@type":"CROSSREF","@value":"10.1016/j.jhazmat.2015.01.026_references_DOI_OmRCZvwKPseonEZKDqBVTyNDDXi"},{"@type":"CROSSREF","@value":"10.1021/acs.est.7b04446_references_DOI_OmRCZvwKPseonEZKDqBVTyNDDXi"}]}