{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360004232425593344.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1016/j.pepi.2012.09.001"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0031920112001549?httpAccept=text/xml"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0031920112001549?httpAccept=text/plain"}},{"identifier":{"@type":"DOI","@value":"10.1016/j.pepi.2012.07.008"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0031920112001380?httpAccept=text/xml"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0031920112001380?httpAccept=text/plain"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Element partitioning between olivine and melt up to 10 GPa: Implications for the effect of pressure"}],"description":[{"notation":[{"@value":"Abstract   In order to investigate the effect of pressure on crystal–melt element partitioning, we have conducted partitioning experiments between olivine and coexisting peridotite melt up to 10 GPa determining minor and trace compositions using electron microprobe and laser-ablation inductively coupled plasma-mass spectrometry (ICP-MS). Partitioning data for monovalent and trivalent cations suggest a significant pressure effect. For monovalent cations, partition coefficients increase with pressure. In contrast, for trivalent cations, partition coefficients of smaller cations (Al, Ga) increase while those of large cations (Sc, REEs) decrease with pressure. To discuss the pressure effect on olivine–melt partitioning, data are interpreted using partition coefficient – ionic radii (PC–IR) diagrams, in conjunction with the lattice strain model. The results show that the optimum ionic radius ( r  0 ) and apparent Young’s modulus ( E ) of the M-site in olivine both decrease with pressure. The decrease in  r  0  can be explained by compression of the M-site in olivine. In contrast, the observed decrease in  E  of the M-site (width of the parabola increases with pressure) cannot be explained by the pressure and temperature effects on the crystal structure. The apparent softening of a crystal site at high pressures is hard to reconcile with a change in crystal structure. We suggest that this effect may be explained by considering the change in structure of silicate melt at pressures that may increase the apparent “Young’s modulus of the M-site in the melt”."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380004232425593472","@type":"Researcher","foaf:name":[{"@value":"Takamasa Imai"}]},{"@id":"https://cir.nii.ac.jp/crid/1030003658321186304","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"40144779"},{"@type":"NRID","@value":"1000040144779"},{"@type":"NRID","@value":"9000362203126"},{"@type":"NRID","@value":"9000262359155"},{"@type":"NRID","@value":"9000288834151"},{"@type":"NRID","@value":"9000265247142"}],"foaf:name":[{"@value":"Eiichi Takahashi"}]},{"@id":"https://cir.nii.ac.jp/crid/1420564276173623808","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"40235974"},{"@type":"NRID","@value":"1000040235974"}],"foaf:name":[{"@value":"Toshihiro 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Hirata"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00319201"}],"prism:publicationName":[{"@value":"Physics of the Earth and Planetary Interiors"}],"dc:publisher":[{"@value":"Elsevier BV"}],"prism:publicationDate":"2012-12","prism:volume":"212-213","prism:startingPage":"64","prism:endingPage":"75"},"reviewed":"false","dc:rights":["https://www.elsevier.com/tdm/userlicense/1.0/","https://www.elsevier.com/legal/tdmrep-license"],"url":[{"@id":"https://api.elsevier.com/content/article/PII:S0031920112001549?httpAccept=text/xml"},{"@id":"https://api.elsevier.com/content/article/PII:S0031920112001549?httpAccept=text/plain"},{"@id":"https://api.elsevier.com/content/article/PII:S0031920112001380?httpAccept=text/xml"},{"@id":"https://api.elsevier.com/content/article/PII:S0031920112001380?httpAccept=text/plain"}],"createdAt":"2012-09-20","modifiedAt":"2025-09-21","project":[{"@id":"https://cir.nii.ac.jp/crid/1040000782062828544","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"21109001"},{"@type":"JGN","@value":"JP21109001"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-ORGANIZER-21109001/"}],"notation":[{"@language":"ja","@value":"地殻流体：　その実態と沈み込み変動への役割"},{"@language":"en","@value":"Geofluid: Nature and dynamics of fluids in subduction zones"}]},{"@id":"https://cir.nii.ac.jp/crid/1040000782065699584","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"21244082"},{"@type":"JGN","@value":"JP21244082"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21244082/"}],"notation":[{"@language":"ja","@value":"地球内部進化に果たすマグマの役割"},{"@language":"en","@value":"Role of magma in chemical evolution of the Earth"}]},{"@id":"https://cir.nii.ac.jp/crid/1040000782488895104","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"10J09386"},{"@type":"JGN","@value":"JP10J09386"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-10J09386/"}],"notation":[{"@language":"ja","@value":"地球マグマオーシャンの化学分化解明に向けた実験的研究"}]},{"@id":"https://cir.nii.ac.jp/crid/1040282257039562368","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"21109004"},{"@type":"JGN","@value":"JP21109004"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PLANNED-21109004/"}],"notation":[{"@language":"ja","@value":"地殻流体の起源と化学"},{"@language":"en","@value":"Origin and chemistry of geofluids"}]},{"@id":"https://cir.nii.ac.jp/crid/1040282257138263296","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"23540566"},{"@type":"JGN","@value":"JP23540566"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23540566/"}],"notation":[{"@language":"ja","@value":"鉱物－珪酸塩メルト間元素分配挙動に対する圧力効果の解明"},{"@language":"en","@value":"Pressure effect on element partitioning between minerals and silicate melt"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050001335841052544","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Major element composition of an Early Enriched Reservoir: Constraints from 142Nd/144Nd isotope systematics in the early Earth and high pressure melting experiments of a primitive 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