{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360004233117923712.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/acs.accounts.8b00157"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/acs.accounts.8b00157"}},{"identifier":{"@type":"PMID","@value":"29889488"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Stimuli-Responsive Supramolecular Assemblies Constructed from Pillar[<i>n</i>]arenes"}],"description":[{"notation":[{"@value":"Supramolecular assemblies are constructed from at least two molecules through various noncovalent bonding modes such as hydrogen bonding, cationic-anionic electrostatic interactions, aromatic interactions, metal-ligand bonding, hydrophobic-hydrophilic interactions, and charge-transfer interactions. Owing to the dynamic and reversible nature of these noncovalent bonds, the assembly and disassembly of these molecules are dynamic and reversible. Molecules self-assemble to form the most conformationally and thermally stable structures through these noncovalent interactions. The formation of these noncovalent interactions is affected by the properties of the environment such as its polarity, temperature, and pressure; thus, the structure of the assembled compounds is determined by the environment. The sizes and shapes of the supramolecular assemblies play an important role in determining their functions. Therefore, controlling their size and shape is important. Introducing stimuli-responsive groups into supramolecular assemblies is a useful way to control their size and shape. Controlling supramolecular structures and motions with external stimuli, i.e., periodic and rotational motions on the molecular scale, structures, and molecular weights at the nano- and micrometer scales, visible shrinking/expansion, and adhesive behavior at a macroscopic scale, is very useful. Macrocyclic host molecules are useful building blocks for the construction of stimuli-responsive supramolecular assemblies because their host ability can be tuned by changing the shape and electron density of the cavity. The size-dependent hosting ability of the cavity is similar to the lock-and-key model in biological systems. Stimuli-responsive supramolecular assemblies have been developed by using macrocyclic compounds such as cyclodextrins, cucurbit[ n]urils, calix[ n]arenes, crown ethers, and related macrocycles. We successfully developed new pillar-shaped macrocyclic hosts in 2008, which were coined pillar[ n]arenes. The unique structural features of pillar[ n]arenes allowed new properties. This year, 2018, marks one decade of research into pillar[ n]arene chemistry, and in that time the properties of pillar[ n]arenes have been widely investigated by various scientists. Thanks to their efforts, the characteristic properties of pillar[ n]arenes that result from their pillar-shaped structures have been elucidated. Their host ability, the chirality of their pillar-shaped structure, and their versatile functionality are unique features of pillar[ n]arenes not seen in other well-known hosts, and these properties are very useful for the creation of new stimuli-responsive supramolecular assemblies. In this Account, we describe photo-, pH- and redox-responsive supramolecular assemblies based on pillar[ n]arenes. First, we discuss molecular-scale stimuli-responsive supramolecular assemblies, i.e., pseudorotaxanes, pseudocatenanes, and supramolecular polymers. We also highlight subnanometer- and micrometer-scale stimuli-responsive supramolecular assembles such as particles and vesicles. Finally, we discuss the macroscopic stimuli-responsive structural changes of surfaces and gels. This Account will provide useful information for researchers working on not only pillar[ n]arene chemistry but also the chemistry of other macrocyclic hosts, and it will inspire new discoveries in the field of supramolecular assemblies and systems containing macrocyclic hosts."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380004233117923712","@type":"Researcher","foaf:name":[{"@value":"Takahiro Kakuta"}],"jpcoar:affiliationName":[{"@value":"Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa, Ishikawa 920-1192, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004233117923714","@type":"Researcher","foaf:name":[{"@value":"Tada-aki Yamagishi"}],"jpcoar:affiliationName":[{"@value":"Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa, Ishikawa 920-1192, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1420001326228290944","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"10379125"},{"@type":"NRID","@value":"1000010379125"},{"@type":"KAKEN_RESEARCHERS","@value":"00216714"},{"@type":"NRID","@value":"1000000216714"},{"@type":"KAKEN_RESEARCHERS","@value":"00447682"},{"@type":"NRID","@value":"1000000447682"},{"@type":"ORCID","@value":"0000-0002-4464-0347"},{"@type":"NRID","@value":"9000001380256"},{"@type":"NRID","@value":"9000265559158"},{"@type":"NRID","@value":"9000006148162"},{"@type":"NRID","@value":"9000018232361"},{"@type":"NRID","@value":"9000004527600"},{"@type":"NRID","@value":"9000409594003"},{"@type":"NRID","@value":"9000409594000"},{"@type":"NRID","@value":"9000401545050"},{"@type":"NRID","@value":"9000401957059"},{"@type":"NRID","@value":"9000257733178"},{"@type":"NRID","@value":"9000001995717"},{"@type":"NRID","@value":"9000394467372"},{"@type":"NRID","@value":"9000394467382"},{"@type":"NRID","@value":"9000363280133"},{"@type":"NRID","@value":"9000024532323"},{"@type":"NRID","@value":"9000022474674"},{"@type":"NRID","@value":"9000335566250"},{"@type":"NRID","@value":"9000335566249"},{"@type":"NRID","@value":"9000411031741"},{"@type":"NRID","@value":"9000283861559"},{"@type":"NRID","@value":"9000401962386"},{"@type":"NRID","@value":"9000258607912"},{"@type":"NRID","@value":"9000257732307"},{"@type":"NRID","@value":"9000002114002"},{"@type":"NRID","@value":"9000335566237"},{"@type":"NRID","@value":"9000316618972"},{"@type":"NRID","@value":"9000021962952"},{"@type":"NRID","@value":"9000414369326"},{"@type":"NRID","@value":"9000401961483"},{"@type":"NRID","@value":"9000401957094"},{"@type":"NRID","@value":"9000404109852"},{"@type":"NRID","@value":"9000396109911"},{"@type":"NRID","@value":"9000283681221"},{"@type":"NRID","@value":"9000258420325"},{"@type":"NRID","@value":"9000258682798"},{"@type":"NRID","@value":"9000016385405"},{"@type":"NRID","@value":"9000022428944"},{"@type":"NRID","@value":"9000412001883"},{"@type":"NRID","@value":"9000283902271"},{"@type":"NRID","@value":"9000401960789"},{"@type":"NRID","@value":"9000401957302"},{"@type":"NRID","@value":"9000258420724"},{"@type":"NRID","@value":"9000258678076"},{"@type":"NRID","@value":"9000000930796"},{"@type":"NRID","@value":"9000024534734"},{"@type":"NRID","@value":"9000021494575"},{"@type":"NRID","@value":"9000401958334"},{"@type":"NRID","@value":"9000258672644"},{"@type":"NRID","@value":"9000020157000"},{"@type":"NRID","@value":"9000409594017"},{"@type":"NRID","@value":"9000409779809"},{"@type":"NRID","@value":"9000409594013"},{"@type":"NRID","@value":"9000409594014"},{"@type":"NRID","@value":"9000376947743"},{"@type":"NRID","@value":"9000401543774"},{"@type":"NRID","@value":"9000258731374"},{"@type":"NRID","@value":"9000024538605"},{"@type":"NRID","@value":"9000238615762"},{"@type":"NRID","@value":"9000403403085"},{"@type":"NRID","@value":"9000257730374"},{"@type":"NRID","@value":"9000018717991"},{"@type":"NRID","@value":"9000409579451"},{"@type":"NRID","@value":"9000409579447"},{"@type":"NRID","@value":"9000409593996"},{"@type":"NRID","@value":"9000409593993"},{"@type":"NRID","@value":"9000387478232"},{"@type":"NRID","@value":"9000409594026"},{"@type":"NRID","@value":"9000387478230"},{"@type":"NRID","@value":"9000258669402"},{"@type":"NRID","@value":"9000314069203"},{"@type":"NRID","@value":"9000025004909"},{"@type":"NRID","@value":"9000023566630"},{"@type":"NRID","@value":"9000024710027"},{"@type":"NRID","@value":"9000020324307"},{"@type":"NRID","@value":"9000020736442"},{"@type":"NRID","@value":"9000020079923"},{"@type":"NRID","@value":"9000309998760"},{"@type":"NRID","@value":"9000309998761"},{"@type":"NRID","@value":"9000242099481"},{"@type":"NRID","@value":"9000396144457"},{"@type":"NRID","@value":"9000396144458"},{"@type":"NRID","@value":"9000411621719"},{"@type":"NRID","@value":"9000242142824"},{"@type":"NRID","@value":"9000321424993"},{"@type":"NRID","@value":"9000022263339"},{"@type":"NRID","@value":"9000024540427"},{"@type":"NRID","@value":"9000022421901"},{"@type":"NRID","@value":"9000335566244"},{"@type":"NRID","@value":"9000335566243"},{"@type":"NRID","@value":"9000020673126"},{"@type":"NRID","@value":"9000351078029"},{"@type":"NRID","@value":"9000401544384"},{"@type":"NRID","@value":"9000258599007"},{"@type":"NRID","@value":"9000019053629"},{"@type":"NRID","@value":"9000022436177"},{"@type":"NRID","@value":"9000409779806"},{"@type":"NRID","@value":"9000391716659"},{"@type":"NRID","@value":"9000401956462"},{"@type":"NRID","@value":"9000401957907"},{"@type":"NRID","@value":"9000255708806"},{"@type":"NRID","@value":"9000283203223"},{"@type":"NRID","@value":"9000256023052"},{"@type":"NRID","@value":"9000018940415"},{"@type":"NRID","@value":"9000370245368"},{"@type":"NRID","@value":"9000370245371"},{"@type":"NRID","@value":"9000313619150"},{"@type":"NRID","@value":"9000398399485"},{"@type":"NRID","@value":"9000398399484"},{"@type":"NRID","@value":"9000398399483"},{"@type":"NRID","@value":"9000408458804"},{"@type":"NRID","@value":"9000409650743"},{"@type":"NRID","@value":"9000283857710"},{"@type":"NRID","@value":"9000242099810"},{"@type":"NRID","@value":"9000257730590"},{"@type":"NRID","@value":"9000000209483"},{"@type":"NRID","@value":"9000412183845"},{"@type":"NRID","@value":"9000007028301"},{"@type":"NRID","@value":"9000241964918"},{"@type":"NRID","@value":"9000345398223"},{"@type":"NRID","@value":"9000345398222"},{"@type":"NRID","@value":"9000401958366"},{"@type":"NRID","@value":"9000401956293"},{"@type":"NRID","@value":"9000398281236"},{"@type":"NRID","@value":"9000404540701"},{"@type":"NRID","@value":"9000022421189"},{"@type":"NRID","@value":"9000023560405"},{"@type":"NRID","@value":"9000024341182"},{"@type":"NRID","@value":"9000020836649"},{"@type":"NRID","@value":"9000007030442"},{"@type":"NRID","@value":"9000318135412"},{"@type":"NRID","@value":"9000401957128"},{"@type":"NRID","@value":"9000401957243"},{"@type":"NRID","@value":"9000409858576"},{"@type":"NRID","@value":"9000021489297"},{"@type":"NRID","@value":"9000242784623"},{"@type":"NRID","@value":"9000016905662"},{"@type":"NRID","@value":"9000409594050"},{"@type":"NRID","@value":"9000409594053"},{"@type":"NRID","@value":"9000409594049"},{"@type":"NRID","@value":"9000375898737"},{"@type":"NRID","@value":"9000286626693"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/234mwa"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0093605"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0110052"}],"foaf:name":[{"@value":"Tomoki Ogoshi"}],"jpcoar:affiliationName":[{"@value":"Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa, Ishikawa 920-1192, Japan"},{"@value":"WPI Nano Life Science Institute, Kanazawa University, Kakuma-machi, Kanazawa, 920-1192, Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00014842"},{"@type":"EISSN","@value":"15204898"}],"prism:publicationName":[{"@value":"Accounts of Chemical Research"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"2018-06-11","prism:volume":"51","prism:number":"7","prism:startingPage":"1656","prism:endingPage":"1666"},"reviewed":"false","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/acs.accounts.8b00157"}],"createdAt":"2018-06-11","modifiedAt":"2023-04-14","project":[{"@id":"https://cir.nii.ac.jp/crid/1040000781867381760","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"15KK0185"},{"@type":"JGN","@value":"JP15KK0185"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-15KK0185/"}],"notation":[{"@language":"ja","@value":"バルク系ホスト－ゲスト化学が拓く次世代超分子マテリアルの創成（国際共同研究強化）"},{"@language":"en","@value":"Construction of new supramolecular assemblies based on host-guest chemistry in bulk state(Fostering Joint International Research)"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050287525728164736","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Pre-regulation of the planar chirality of pillar[5]arenes for preparing discrete chiral nanotubes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002214425863424","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Temperature‐Driven Planar Chirality Switching of a Pillar[5]arene‐Based Molecular Universal Joint"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004233468341376","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Molecular weight fractionation by confinement of polymer in one-dimensional pillar[5]arene channels"}]},{"@id":"https://cir.nii.ac.jp/crid/1360005518515448704","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Supramolecular self-healing materials from non-covalent cross-linking host–guest interactions"}]},{"@id":"https://cir.nii.ac.jp/crid/1360009142731534336","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Photoisomerization-induced patterning of ion-pairing materials based on anionic azobenzene and its complex with a fluorescent π-electronic system"}]},{"@id":"https://cir.nii.ac.jp/crid/1360009142739999360","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"A dual redox-responsive supramolecular polymer driven by molecular recognition between bisporphyrin and trinitrofluorenone"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011145490256000","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Stimuli-responsive blue fluorescent supramolecular polymers based on a pillar[5]arene tetramer"}]},{"@id":"https://cir.nii.ac.jp/crid/1360013168832785536","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Pillar[6]quinone: facile synthesis, crystal structures and electrochemical properties"}]},{"@id":"https://cir.nii.ac.jp/crid/1360013168863972480","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Self-assembly of neutral platinum complexes possessing chiral hydrophilic TEG chains"}]},{"@id":"https://cir.nii.ac.jp/crid/1360017282440928384","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"A theoretical analysis of the reduction and lithiation of pillar[6]quinone"}]},{"@id":"https://cir.nii.ac.jp/crid/1360017282451972864","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Biomimetic and Biological Nanoarchitectonics"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283691636699008","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Molecular Recognition with Microporous Multilayer Films Prepared by Layer-by-Layer Assembly of Pillar[5]arenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283691876080000","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The aqueous supramolecular chemistry of cucurbit[n]urils, pillar[n]arenes and deep-cavity cavitands"}]},{"@id":"https://cir.nii.ac.jp/crid/1360290617716731648","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Stereoselectivity in dehydrative cyclic trimerization of substituted 4-alkylaminobenzoic acids"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292618748273792","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Planar-Chiral Macrocyclic Host Pillar[5]arene: No Rotation of Units and Isolation of Enantiomers by Introducing Bulky Substituents"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292619347909376","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Stimuli-Responsive Supramolecular Polymers in Aqueous Solution"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292619880019584","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Solvent‐ and Achiral‐Guest‐Triggered Chiral Inversion in a Planar Chiral <i>pseudo</i>[1]Catenane"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292620139765120","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Zero-to-one (or more) nanoarchitectonics: how to produce functional materials from zero-dimensional single-element unit, fullerene"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292620154247552","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Pillar-Shaped Macrocyclic Hosts Pillar[<i>n</i>]arenes: New Key Players for Supramolecular Chemistry"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292620417894656","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Styrene Purification by Guest-Induced Restructuring of Pillar[6]arene"}]},{"@id":"https://cir.nii.ac.jp/crid/1360294643861048448","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Reversible “On/Off” Chiral Amplification of Pillar[5]arene Assemblies by Dual External Stimuli"}]},{"@id":"https://cir.nii.ac.jp/crid/1360294662753004800","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Noncovalently bound and mechanically interlocked systems using pillar[<i>n</i>]arenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360306904382166784","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Temperature‐Dependent Left‐ and Right‐Twisted Conformational Changes in 1 : 1 Host‐Guest Systems: Theoretical Modeling and Chiroptical Simulations"}]},{"@id":"https://cir.nii.ac.jp/crid/1360306906066134016","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Chiral Induction of a Tetrakis(porphyrin) in Various Chiral Solvents"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565164379596160","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Separation of Linear and Branched Alkanes Using Host–Guest Complexation of Cyclic and Branched Alkane Vapors by Crystal State Pillar[6]arene"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183452333056","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Ring shape-dependent self-sorting of pillar[n]arenes assembled on a surface"}]},{"@id":"https://cir.nii.ac.jp/crid/1360568464449480704","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Non‐Covalent Interactions Enable the Length‐Controlled Generation of Discrete Tubes Capable of Guest Exchange"}]},{"@id":"https://cir.nii.ac.jp/crid/1360572092878246144","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Vapochromism of Organic Crystals Based on Macrocyclic Compounds and Inclusion Complexes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574093557817472","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"<i>para</i>-Bridged Symmetrical Pillar[5]arenes: Their Lewis Acid Catalyzed Synthesis and Host–Guest Property"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574093598668160","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Dynamic Covalent Bond Based on Reversible Photo [4 + 4] Cycloaddition of Anthracene for Construction of Double-Dynamic Polymers"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574095088667520","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Functionalizing Pillar[<i>n</i>]arenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360580229782109568","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"High-Speed Atomic Force Microscopy Reveals Spontaneous Nucleosome Sliding of H2A.Z at the Subsecond Time Scale"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846641590543488","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Photocontrolled Reversible Guest Uptake, Storage, and Release by Azobenzene-Modified Microporous Multilayer Films of Pillar[5]arenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846641818377600","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Reversible and contrasting changes of the cloud point temperature of pillar[5]arenes with one quinone unit and tri(ethylene oxide) chains induced by redox chemistry and host–guest complexation"}]},{"@id":"https://cir.nii.ac.jp/crid/1360853567848665856","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Vapoluminescence Behavior Triggered by Crystal-State Complexation between Host Crystals and Guest Vapors Exhibiting No Visible Fluorescence"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855568545707264","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Engineering Responsive Polymer Building Blocks with Host–Guest Molecular Recognition for Functional Applications"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855568744517760","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Rotaxane-Based Molecular Muscles"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855570049750912","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Dramatically Promoted Swelling of a Hydrogel by Pillar[6]arene–Ferrocene Complexation with Multistimuli Responsiveness"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855570613883904","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Alkane-Shape-Selective Vapochromic Behavior Based on Crystal-State Host–Guest Complexation of Pillar[5]arene Containing One Benzoquinone Unit"}]},{"@id":"https://cir.nii.ac.jp/crid/1361131418419110912","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Molecular recognition of planar and non-planar aromatic hydrocarbons through multipoint Ag–π bonding in a dinuclear metallo-macrocycle"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137044048975104","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Review: A History of Cyclodextrins"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137044156229248","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Rotaxane and Catenane Host Structures for Sensing Charged Guest Species"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137046044635520","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Photo-responsive self-assembly based on a water-soluble pillar[6]arene and an azobenzene-containing amphiphile in water"}]},{"@id":"https://cir.nii.ac.jp/crid/1361412893399040384","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Obvious vapochromic color changes of a pillar[6]arene containing one benzoquinone unit with a mechanochromic change before vapor exposure"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418518578678272","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Cucurbituril Homologues and Derivatives:  New Opportunities in Supramolecular Chemistry"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418518799777920","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Photoreversible switching between assembly and disassembly of a supramolecular polymer involving an azobenzene-bridged pillar[5]arene dimer"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418519067903104","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Stimuli-responsive supramolecular polymeric materials"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418519548297216","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Regulating Molecular Recognition with C‐Shaped Strips Attained by Chirality‐Assisted Synthesis"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418521402791168","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Surveying macrocyclic chemistry: from flexible crown ethers to rigid cyclophanes"}]},{"@id":"https://cir.nii.ac.jp/crid/1361694368366742784","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Photo-responsive dimension-controlled ion-pairing assemblies based on anion complexes of π-electronic systems"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699993400296832","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Pillar[5]arene‐Based Supramolecular Organic Frameworks for Highly Selective CO<sub>2</sub>‐Capture at Ambient Conditions"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699994855852032","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Organometallic rotaxane dendrimers with fourth-generation mechanically interlocked branches"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699995938541312","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Laterally functionalized pillar[5]arene: a new building block for covalent self-assembly"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699996395386112","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Mechanized Silica Nanoparticles Based on Pillar[5]arenes for On‐Command Cargo Release"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981469126293888","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Development of Redox-Switchable Resorcin[4]arene Cavitands"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981469287356416","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The Cucurbit[<i>n</i>]uril Family"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981470665440256","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Rim-Differentiated <i>C</i><sub>5</sub>-Symmetric Tiara-Pillar[5]arenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262945004209920","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Photoresponsive Host–Guest Functional Systems"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262945266585088","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Size Switchable Supramolecular Nanoparticle Based on Azobenzene Derivative within Anionic Pillar[5]arene"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544419876497792","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Photoreversible Transformation between Seconds and Hours Time-Scales: Threading of Pillar[5]arene onto the Azobenzene-End of a Viologen Derivative"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544420039049600","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Cationic Vesicles Based on Amphiphilic Pillar[5]arene Capped with Ferrocenium: A Redox‐Responsive System for Drug/siRNA Co‐Delivery"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544420898892288","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Stimuli-Responsive Metal–Ligand Assemblies"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825893561562880","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Responsive Gel-like Supramolecular Network Based on Pillar[6]arene–Ferrocenium Recognition Motifs in Polymeric Matrix"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825894180304256","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Pillararenes, A New Class of Macrocycles for Supramolecular Chemistry"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825894706531200","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Stimuli Responsive Systems Constructed Using Cucurbit[<i>n</i>]uril-Type Molecular Containers"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825894987027200","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Redox-responsive host–guest system using redox-active pillar[5]arene containing one benzoquinone unit"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825895152606976","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Self-assembly of [2]pseudorotaxanes based on pillar[5]arene and bis(imidazolium) cations"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107368546178560","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Photoreversible Switching of the Lower Critical Solution Temperature in a Photoresponsive Host–Guest System of Pillar[6]arene with Triethylene Oxide Substituents and an Azobenzene Derivative"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107369559300992","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Reversibly Tunable Lower Critical Solution Temperature Utilizing Host–Guest Complexation of Pillar[5]arene with Triethylene Oxide Substituents"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107370242202240","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Temperature-Responsive Switch Constructed from an Anthracene-Functionalized Pillar[5]arene-Based Host–Guest System"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107370388379776","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Facile construction of organometallic rotaxane-terminated dendrimers using neutral platinum–acetylides as the main scaffold"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107370974236544","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Pillararene-based supramolecular polymers: from molecular recognition to polymeric aggregates"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388843406859520","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Cross-Linked Supramolecular Polymer Gels Constructed from Discrete Multi-pillar[5]arene Metallacycles and Their Multiple Stimuli-Responsive Behavior"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388843714527744","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Novel Cavity Design Using Calix[<i>n</i>]arene Skeletons:  Toward Molecular Recognition and Metal Binding"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951793858662784","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Stimuli-responsive metal–organic frameworks gated by pillar[5]arene supramolecular switches"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951794049574528","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"High‐Yield Diastereoselective Synthesis of Planar Chiral [2]‐ and [3]Rotaxanes Constructed from per‐Ethylated Pillar[5]arene and Pyridinium Derivatives"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951794386773504","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A novel redox-responsive pillar[6]arene-based inclusion complex with a ferrocenium guest"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951794571689472","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Stimuli-Responsive Host–Guest Systems Based on the Recognition of Cryptands by Organic Guests"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951794663816576","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Pillar[6]arene-Based Photoresponsive Host–Guest Complexation"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951795742171392","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Well‐Defined Pillararene‐Based Azobenzene Liquid Crystalline Photoresponsive Materials and Their Thin Films with Photomodulated Surfaces"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233269212833024","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Conformation-controlled emission of AIE luminogen: a tetraphenylethene embedded pillar[5]arene skeleton"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233270544676992","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Exploring Macrocycles in Functional Supramolecular Gels: From Stimuli Responsiveness to Systems Chemistry"}]},{"@id":"https://cir.nii.ac.jp/crid/1390287297543052928","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Suppression of Malachite Green-Induced Toxicity to Human Liver Cells Utilizing Host-Guest Chemistry of Cucurbit[7]uril"}]},{"@id":"https://cir.nii.ac.jp/crid/2051714792003847936","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Conformation and planar chirality of pillar[n]arenes"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1021/acs.accounts.8b00157"},{"@type":"KAKEN","@value":"PRODUCT-22504650"},{"@type":"OPENAIRE","@value":"doi_dedup___::a4cf31e8d8b723acbd69e382bf520650"},{"@type":"CROSSREF","@value":"10.1038/s41467-019-08372-1_references_DOI_GEx3WZXx4LkcXLCfLjDGpnE22Gg"},{"@type":"CROSSREF","@value":"10.1246/cl.190544_references_DOI_GEx3WZXx4LkcXLCfLjDGpnE22Gg"},{"@type":"CROSSREF","@value":"10.1039/d0cc00672f_references_DOI_GEx3WZXx4LkcXLCfLjDGpnE22Gg"},{"@type":"CROSSREF","@value":"10.2116/analsci.20scn02_references_DOI_GEx3WZXx4LkcXLCfLjDGpnE22Gg"},{"@type":"CROSSREF","@value":"10.1039/d0cc07640f_references_DOI_GEx3WZXx4LkcXLCfLjDGpnE22Gg"},{"@type":"CROSSREF","@value":"10.1039/d0cc02474k_references_DOI_GEx3WZXx4LkcXLCfLjDGpnE22Gg"},{"@type":"CROSSREF","@value":"10.1039/d1cc02413b_references_DOI_GEx3WZXx4LkcXLCfLjDGpnE22Gg"},{"@type":"CROSSREF","@value":"10.1039/d1ob00492a_references_DOI_GEx3WZXx4LkcXLCfLjDGpnE22Gg"},{"@type":"CROSSREF","@value":"10.1016/j.jelechem.2023.117170_references_DOI_GEx3WZXx4LkcXLCfLjDGpnE22Gg"},{"@type":"CROSSREF","@value":"10.3390/ijms23073577_references_DOI_GEx3WZXx4LkcXLCfLjDGpnE22Gg"},{"@type":"CROSSREF","@value":"10.1039/d0nj05368f_references_DOI_GEx3WZXx4LkcXLCfLjDGpnE22Gg"},{"@type":"CROSSREF","@value":"10.1039/d1sc00074h_references_DOI_GEx3WZXx4LkcXLCfLjDGpnE22Gg"},{"@type":"CROSSREF","@value":"10.1021/acsnano.1c06975_references_DOI_GEx3WZXx4LkcXLCfLjDGpnE22Gg"},{"@type":"CROSSREF","@value":"10.1039/d2cs00169a_references_DOI_GEx3WZXx4LkcXLCfLjDGpnE22Gg"},{"@type":"CROSSREF","@value":"10.1039/d0ma00744g_references_DOI_GEx3WZXx4LkcXLCfLjDGpnE22Gg"},{"@type":"CROSSREF","@value":"10.1002/anie.202413340_references_DOI_GEx3WZXx4LkcXLCfLjDGpnE22Gg"},{"@type":"CROSSREF","@value":"10.1002/chem.202403569_references_DOI_GEx3WZXx4LkcXLCfLjDGpnE22Gg"},{"@type":"CROSSREF","@value":"10.1038/s42004-018-0094-z_references_DOI_GEx3WZXx4LkcXLCfLjDGpnE22Gg"},{"@type":"CROSSREF","@value":"10.1002/anie.201916515_references_DOI_GEx3WZXx4LkcXLCfLjDGpnE22Gg"},{"@type":"CROSSREF","@value":"10.3390/sym12111903_references_DOI_GEx3WZXx4LkcXLCfLjDGpnE22Gg"},{"@type":"CROSSREF","@value":"10.1021/acs.nanolett.2c04346_references_DOI_GEx3WZXx4LkcXLCfLjDGpnE22Gg"},{"@type":"CROSSREF","@value":"10.1021/acs.cgd.0c00982_references_DOI_GEx3WZXx4LkcXLCfLjDGpnE22Gg"},{"@type":"CROSSREF","@value":"10.1039/c9sc02619c_references_DOI_GEx3WZXx4LkcXLCfLjDGpnE22Gg"},{"@type":"CROSSREF","@value":"10.1039/d0cc01112f_references_DOI_GEx3WZXx4LkcXLCfLjDGpnE22Gg"},{"@type":"CROSSREF","@value":"10.1039/c9cc05632g_references_DOI_GEx3WZXx4LkcXLCfLjDGpnE22Gg"}]}