{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360004233142515072.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/acs.orglett.7b03664"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.7b03664"}},{"identifier":{"@type":"PMID","@value":"29320193"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Anionic Triflyldiazomethane: Generation and Its Application for Synthesis of Pyrazole-3-triflones via [3 + 2] Cycloaddition Reaction"}],"description":[{"notation":[{"@value":"The synthesis of pyrazole triflones containing a triflyl group at the 3-position is disclosed. Treatment of 2-diazo-1-phenyl-2-((trifluoromethyl)sulfonyl)ethan-1-one with nitroalkenes under basic conditions gave pharmaceutically attractive pyrazole 3-triflones in good to high yields. The generation of anionic triflyldiazomethane species followed by the [3 + 2] cycloaddition reaction with nitroalkenes is proposed for this transformation. 3-(Difluoromethanesulfonyl)pyrazoles were also synthesized by using a previously unknown anionic (difluoromethanesulfonyl)diazomethane species under a similar strategy."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380004233142515075","@type":"Researcher","foaf:name":[{"@value":"Pulakesh Das"}],"jpcoar:affiliationName":[{"@value":"Department\rof Nanopharmaceutical Sciences, Department of Life Science and Applied\rChemistry, Nagoya Institute of Technology, Gokiso-cho, Showa-ku Nagoya 466-8555, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004233142515073","@type":"Researcher","foaf:name":[{"@value":"Satoshi Gondo"}],"jpcoar:affiliationName":[{"@value":"Department\rof Nanopharmaceutical Sciences, Department of Life Science and Applied\rChemistry, Nagoya Institute of Technology, Gokiso-cho, Showa-ku Nagoya 466-8555, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004233142515074","@type":"Researcher","foaf:name":[{"@value":"Etsuko Tokunaga"}],"jpcoar:affiliationName":[{"@value":"Department\rof Nanopharmaceutical Sciences, Department of Life Science and Applied\rChemistry, Nagoya Institute of Technology, Gokiso-cho, Showa-ku Nagoya 466-8555, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004233142515076","@type":"Researcher","foaf:name":[{"@value":"Yuji Sumii"}],"jpcoar:affiliationName":[{"@value":"Department\rof Nanopharmaceutical Sciences, Department of Life Science and Applied\rChemistry, Nagoya Institute of Technology, Gokiso-cho, Showa-ku Nagoya 466-8555, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004233142515072","@type":"Researcher","foaf:name":[{"@value":"Norio Shibata"}],"jpcoar:affiliationName":[{"@value":"Department\rof Nanopharmaceutical Sciences, Department of Life Science and Applied\rChemistry, Nagoya Institute of Technology, Gokiso-cho, Showa-ku Nagoya 466-8555, Japan"},{"@value":"Institute\rof Advanced Fluorine-Containing Materials, Zhejiang Normal University, 688 Yingbin Avenue, 321004 Jinhua, China"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"15237060"},{"@type":"EISSN","@value":"15237052"}],"prism:publicationName":[{"@value":"Organic Letters"}],"dc:publisher":[{"@value":"American Chemical Society 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