{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360004233149054976.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/acscatal.6b02767"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/acscatal.6b02767"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Supported Palladium–Gold Alloy Catalysts for Efficient and Selective Hydrosilylation under Mild Conditions with Isolated Single Palladium Atoms in Alloy Nanoparticles as the Main Active Site"}],"description":[{"notation":[{"@value":"Supported Pd–Au alloy catalysts were developed for the highly efficient and selective hydrosilylation of α,β-unsaturated ketones and alkynes. The Pd/Au atomic ratio of the Pd–Au alloy and the supporting material affected the catalytic activity, and supported Pd–Au alloy nanoparticles with a low Pd/Au atomic ratio functioned as highly active heterogeneous catalysts under mild reaction conditions. Structural characterization of supported Pd–Au alloy catalysts by X-ray diffraction, X-ray absorption spectroscopy (XAS), and transmission electron microscopy revealed the formation of random Pd–Au alloy nanoparticles with a uniform size of around 3 nm on the support. Furthermore, XAS and X-ray photoelectron spectroscopy elucidated the charge transfer from Pd to Au and the formation of isolated single Pd atoms in random Pd–Au alloys with a low Pd/Au ratio, which enabled efficient hydrosilylation of a variety of substrates under mild reaction conditions."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1420282801184291968","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"20633267"},{"@type":"NRID","@value":"1000020633267"},{"@type":"NRID","@value":"9000398150608"},{"@type":"NRID","@value":"9000413573368"},{"@type":"NRID","@value":"9000347169734"},{"@type":"NRID","@value":"9000258689787"},{"@type":"NRID","@value":"9000381959448"},{"@type":"NRID","@value":"9000367858683"},{"@type":"NRID","@value":"9000347197599"},{"@type":"NRID","@value":"9000345323857"},{"@type":"NRID","@value":"9000017477123"},{"@type":"NRID","@value":"9000347198137"},{"@type":"NRID","@value":"9000411514221"},{"@type":"NRID","@value":"9000347197715"},{"@type":"NRID","@value":"9000347197822"},{"@type":"NRID","@value":"9000345322977"},{"@type":"NRID","@value":"9000412353983"},{"@type":"NRID","@value":"9000347197730"},{"@type":"NRID","@value":"9000329017232"},{"@type":"NRID","@value":"9000347198110"},{"@type":"NRID","@value":"9000258691425"},{"@type":"NRID","@value":"9000023260953"},{"@type":"NRID","@value":"9000380131179"},{"@type":"NRID","@value":"9000347197216"},{"@type":"NRID","@value":"9000345322922"},{"@type":"NRID","@value":"9000258690061"},{"@type":"NRID","@value":"9000258690491"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/hirokimiura"}],"foaf:name":[{"@value":"Hiroki 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