{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360004233180656128.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/cs200388v"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/cs200388v"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Conceptual Design of Heterogeneous Oxidation Catalyst: Copper Hydroxide on Manganese Oxide-Based Octahedral Molecular Sieve for Aerobic Oxidative Alkyne Homocoupling"}],"description":[{"notation":[{"@value":"The supported copper hydroxide catalyst on manganese oxide-based octahedral molecular sieve OMS-2 (Cu(OH)x/OMS-2) was designed on the basis of the concept of coupled electron transfer. OMS-2 could act as not only a support for copper hydroxide species but also an electron-transfer mediator (cocatalyst) to generate a rapid electron-transfer path from an alkyne to dioxygen. As a result, Cu(OH)x/OMS-2 showed high catalytic performance (TOF = 540 h–1, total TON = 666, and selectivity >99%) and long life (13 times reuse) for aerobic oxidative alkyne homocoupling."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380004233180656130","@type":"Researcher","foaf:name":[{"@value":"Takamichi Oishi"}],"jpcoar:affiliationName":[{"@value":"Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004233180656129","@type":"Researcher","foaf:name":[{"@value":"Kazuya Yamaguchi"}],"jpcoar:affiliationName":[{"@value":"Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004233180656128","@type":"Researcher","foaf:name":[{"@value":"Noritaka Mizuno"}],"jpcoar:affiliationName":[{"@value":"Department of Applied Chemistry, School of Engineering, The 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