{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360004233180730880.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/cs500082g"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/cs500082g"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Chemoselective Hydrogenation of Nitrostyrene to Aminostyrene over Pd- and Rh-Based Intermetallic Compounds"}],"description":[{"notation":[{"@value":"A noble catalytic system based on intermetallic compounds was developed for the chemoselective hydrogenation of p-nitrostyrene (NS) to p-aminostyrene (AS). The main concept of the catalyst design was to construct polar active sites consisting of two types of metals with different electronegativities. We prepared a series of Pd- and Rh-based intermetallics and investigated their catalytic properties in detail in the catalytic transfer hydrogenation of nitrobenzene and NS in the presence of 4-methyl-1-cyclohexene (MC) or methanol as a hydrogen donor. FT-IR studies of adsorbed CO confirmed that the number of Pd ensembles exposed on a surface was greatly decreased by the formation of an intermetallic phase; hence, the particle surface consisted of two metal elements being coadjacent at the atomic level. The product distribution achieved with Pd catalysts was dependent on the electronegativity of the second metal element: more electronegative metals gave higher AS selectivity and lower p-ethylnitrobenzene 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Furukawa"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, ‡Department of Chemistry and Materials Science, Tokyo Institute of Technology, 2-12-1-E1-10 Ookayama, Meguro-ku, Tokyo 152-8551, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004233180730882","@type":"Researcher","foaf:name":[{"@value":"Yurika Yoshida"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, ‡Department of Chemistry and Materials Science, Tokyo Institute of Technology, 2-12-1-E1-10 Ookayama, Meguro-ku, Tokyo 152-8551, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004233180730881","@type":"Researcher","foaf:name":[{"@value":"Takayuki Komatsu"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, ‡Department of Chemistry and Materials Science, Tokyo Institute of Technology, 2-12-1-E1-10 Ookayama, Meguro-ku, Tokyo 152-8551, Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"21555435"},{"@type":"EISSN","@value":"21555435"}],"prism:publicationName":[{"@value":"ACS Catalysis"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"2014-04-09","prism:volume":"4","prism:number":"5","prism:startingPage":"1441","prism:endingPage":"1450"},"reviewed":"false","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/cs500082g"}],"createdAt":"2014-03-24","modifiedAt":"2023-04-15","project":[{"@id":"https://cir.nii.ac.jp/crid/1040000782151005696","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"23360353"},{"@type":"JGN","@value":"JP23360353"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23360353/"}],"notation":[{"@language":"ja","@value":"金属間化合物の触媒作用の解明およびナノ粒子化による新規な高機能触媒の創成"},{"@language":"en","@value":"Preparation and characterization of intermetallic compound nanoparticles to create novel catalysts having high 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