{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360004233191744256.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/ic401924d"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/ic401924d"}},{"identifier":{"@type":"PMID","@value":"24016100"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"In Situ Generation of Functionality in a Reactive Haloalkane-Based Ligand for the Design of New Porous Coordination Polymers"}],"description":[{"notation":[{"@value":"Herein, we report new porous coordination polymers (PCPs) via a facile synthetic approach called \"in situ generation of functionality in the ligand\". Upon a synthetic process of PCPs, a neutral (-CH2OH) or a cationic functionality (-CH2-[4,4'-bipyridine](+)) was generated on a isophthalate ligand from a reactive haloalkane (-CH2Br) moiety, affording two new PCPs. The PCPs have two-dimensional layered structures with large potential solvent-accessible voids for CO2 adsorption."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380004233191744256","@type":"Researcher","foaf:name":[{"@value":"Prakash Kanoo"}],"jpcoar:affiliationName":[{"@value":"Institute for Integrated\rCell-Material Sciences (WPI-iCeMS), Kyoto University, Nishikyo-ku, Katsura, Kyoto 615-8510, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1420001326227256704","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"00402959"},{"@type":"NRID","@value":"1000000402959"},{"@type":"NRID","@value":"9000018232881"},{"@type":"NRID","@value":"9000023452232"},{"@type":"NRID","@value":"9000414810784"},{"@type":"NRID","@value":"9000401949289"},{"@type":"NRID","@value":"9000283394647"},{"@type":"NRID","@value":"9000265565578"},{"@type":"NRID","@value":"9000023555349"},{"@type":"NRID","@value":"9000399532914"},{"@type":"NRID","@value":"9000017358997"},{"@type":"NRID","@value":"9000406228170"},{"@type":"NRID","@value":"9000412115411"},{"@type":"NRID","@value":"9000364779680"},{"@type":"NRID","@value":"9000362203131"},{"@type":"NRID","@value":"9000324661179"},{"@type":"NRID","@value":"9000399010693"},{"@type":"NRID","@value":"9000257732048"},{"@type":"NRID","@value":"9000344126691"},{"@type":"NRID","@value":"9000345247929"},{"@type":"NRID","@value":"9000399524238"},{"@type":"NRID","@value":"9000023396753"},{"@type":"NRID","@value":"9000321629804"},{"@type":"NRID","@value":"9000020282687"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/rmatsuda"}],"foaf:name":[{"@value":"Ryotaro Matsuda"}],"jpcoar:affiliationName":[{"@value":"Institute for Integrated\rCell-Material Sciences (WPI-iCeMS), Kyoto University, Nishikyo-ku, Katsura, Kyoto 615-8510, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004233191744261","@type":"Researcher","foaf:name":[{"@value":"Hiroshi Sato"}],"jpcoar:affiliationName":[{"@value":"Institute for Integrated\rCell-Material Sciences (WPI-iCeMS), Kyoto University, Nishikyo-ku, Katsura, Kyoto 615-8510, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004233191744260","@type":"Researcher","foaf:name":[{"@value":"Liangchun Li"}],"jpcoar:affiliationName":[{"@value":"Institute for Integrated\rCell-Material Sciences (WPI-iCeMS), Kyoto University, Nishikyo-ku, Katsura, Kyoto 615-8510, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004233191744258","@type":"Researcher","foaf:name":[{"@value":"Hyung Joon Jeon"}],"jpcoar:affiliationName":[{"@value":"Institute for Integrated\rCell-Material Sciences (WPI-iCeMS), Kyoto University, Nishikyo-ku, Katsura, Kyoto 615-8510, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004233191744257","@type":"Researcher","foaf:name":[{"@value":"Susumu Kitagawa"}],"jpcoar:affiliationName":[{"@value":"Institute for Integrated\rCell-Material Sciences (WPI-iCeMS), Kyoto University, Nishikyo-ku, Katsura, Kyoto 615-8510, Japan"},{"@value":"Department of Synthetic\rChemistry and Biological Chemistry, Graduate School of\rEngineering, Kyoto University, Nishikyo-ku,\rKatsura, Kyoto 615-8510, Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00201669"},{"@type":"EISSN","@value":"1520510X"}],"prism:publicationName":[{"@value":"Inorganic Chemistry"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"2013-09-09","prism:volume":"52","prism:number":"19","prism:startingPage":"10735","prism:endingPage":"10737"},"reviewed":"false","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/ic401924d"}],"createdAt":"2013-09-09","modifiedAt":"2023-04-04","project":[{"@id":"https://cir.nii.ac.jp/crid/1040000782266314880","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"25620187"},{"@type":"JGN","@value":"JP25620187"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-25620187/"}],"notation":[{"@language":"ja","@value":"革新的室温ガス吸着物質を指向したナノ空間中のパーフルオロアルカン疑似液相の実現"},{"@language":"en","@value":"Creation of pseudo liquid phase of perfluoroalkane in the nanospace realizing an innovative gas adsorption at room 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