General Diffusion Model for Polymeric Systems Based on Microscopic Molecular Collisions and Random Walk Movement

DOI Web Site 被引用文献1件 参考文献32件
  • Hidenori Ohashi
    Chemical Resources Laboratory, Tokyo Institute of Technology, R1-17, 4259 Nagatsuta-cho, Midori-ku, Yokohama-city, Kanagawa 226-8503, Japan
  • Takeo Yamaguchi
    Chemical Resources Laboratory, Tokyo Institute of Technology, R1-17, 4259 Nagatsuta-cho, Midori-ku, Yokohama-city, Kanagawa 226-8503, Japan

書誌事項

公開日
2013-07-09
資源種別
journal article
DOI
  • 10.1021/ie401045m
公開者
American Chemical Society (ACS)

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説明

Molecular diffusivity in polymeric systems is often the determining factor in performance and efficiency of devices and systems and thus is one of the most important dynamic properties. In polymeric systems, various penetrants, including gas, solvent, and solute molecules can diffuse, and therefore, a general model that can broadly provide their molecular diffusivity could strongly accelerate the designing of polymeric devices. On the other hand, from the microscopic viewpoint, the molecular diffusive motion can be regarded as a random walk movement subject to an enormous number of molecular collisions with neighboring molecules. Therefore, in the present study, both of the microscopic descriptions common for all penetrants in polymeric systems have been unified into one model. The resultant model is the first general diffusion model that can describe diffusivity of all penetrants, including gas, solvent, and solute molecules in rubbery polymeric systems. The applicability of the microscopic model is demo...

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