{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360004233236240768.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/jp507696y"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/jp507696y"}},{"identifier":{"@type":"PMID","@value":"25253240"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Collision Energy Dependent Cross Section and Rotational Alignment of NO (A <sup>2</sup>Σ<sup>+</sup>) in the Energy-Transfer Reaction of N<sub>2</sub> (A<sup>3</sup>Σ<sub>u</sub><sup>+</sup>) + NO (X <sup>2</sup>Π) → N<sub>2</sub> (X <sup>1</sup>Σ<sub>g</sub><sup>+</sup>) + NO (A <sup>2</sup>Σ<sup>+</sup>)"}],"description":[{"notation":[{"@value":"We have studied the collision energy dependent cross section and alignment of NO (A (2)Σ(+)) rotation in the energy-transfer reaction of N2 (A (3)Σ(u)(+)) + NO (X (2)Π) → N2 (X (1)Σ(g)(+)) + NO (A (2)Σ(+)) at the collision energy (E) region of 0.03-0.2 eV. NO (A (2)Σ(+)) emission in two linear polarization directions in the collision frame (parallel (∥) and perpendicular (⊥) with respect to the relative velocity vector (vR)) has been measured as a function of collision energy. NO (A (2)Σ(+)) rotation (J-vector) turns out to be aligned perpendicular to vR. In addition, collision energy is found to enhance the degree of alignment of NO (A (2)Σ(+)) rotation. The collision energy dependent cross sections σ(∥,(⊥))(E) (excitation functions) show a rapid fall-off following an initial rise with a threshold less than 0.02 eV. The excitation function at the parallel alignment of NO (A (2)Σ(+)) rotation, σ(J∥v(R), (E), is slightly shifted to the low collision energy region as compared with σ(J ⊥ vR, E). We propose that the rapid fall-off feature in the excitation function is attributed to the multidimensional nonadiabatic transitions."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380004233236240768","@type":"Researcher","foaf:name":[{"@value":"H. Ohoyama"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry,\rGraduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"10895639"},{"@type":"EISSN","@value":"15205215"}],"prism:publicationName":[{"@value":"The Journal of Physical Chemistry A"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"2014-10-02","prism:volume":"118","prism:number":"41","prism:startingPage":"9646","prism:endingPage":"9652"},"reviewed":"false","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/jp507696y"}],"createdAt":"2014-09-25","modifiedAt":"2023-04-16","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Physical%20and%20Theoretical%20Chemistry","dc:title":"Physical and Theoretical Chemistry"}],"project":[{"@id":"https://cir.nii.ac.jp/crid/1040282257126456832","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"23350008"},{"@type":"JGN","@value":"JP23350008"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23350008/"}],"notation":[{"@language":"ja","@value":"生体分子の立体異性体選別と衝突異性化反応の多次元立体効果の解明"},{"@language":"en","@value":"Selection of geometric isomer of biomolecules and study of multi-dimensional steric effect on collisional isomerization reaction"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360004233235002368","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Alignment Effect of N<sub>2</sub>(A<sup>3</sup>Σ<sub>u</sub><sup>+</sup>) in the Energy Transfer Reaction of Aligned N<sub>2</sub>(A<sup>3</sup>Σ<sub>u</sub><sup>+</sup>) + NO(X<sup>2</sup>Π) → NO(A<sup>2</sup>Σ<sup>+</sup>) + N<sub>2</sub>(X<sup>1</sup>Σ<sub>g</sub><sup>+</sup>)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004233894516352","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Rotationally correlated reactivity in the CH (v = 0, J, Fi) + O2 → OH (A) + CO reaction"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011144088986880","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Chemical reaction dynamics with molecular beams"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011144581110528","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Crossed beam reaction of the cyanogen radical, CN(X 2Σ+), with acetylene, C2H2(X 1Σg+): Observation of cyanoacetylene, HCCCN(X 1Σ+)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011144819964928","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Revealing the stereospecific chemistry of the reaction of Cl with aligned CHD3(ν1 = 1)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285708881123712","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Stereo correlated dynamics in the energy transfer process of aligned N2 (A 3Σu+) + oriented NO (X 2Π, Ω = 1/2) → NO (A 2Σ+) + N2 (X 1Σg+)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285708886255232","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Vector correlation between the alignment of reactant N2 (A 3Σu+) and the alignment of product NO (A 2Σ+) rotation in the energy transfer reaction of aligned N2 (A 3Σu+) + NO (X 2Π) → NO (A 2Σ+) + N2 (X 1Σg+)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292619013923328","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Calculations of auroral intensities from electron impact"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183187876864","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Steric Effect in the Energy Transfer Reaction of Oriented CO (a <sup>3</sup>Π, v′ = 0, Ω = 1 and 2) + NO (X <sup>2</sup>Π) → NO (A <sup>2</sup>Σ<sup>+</sup>, B <sup>2</sup>Π) + CO (X <sup>1</sup>Σ<sup>+</sup>)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574093712209664","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Stereodynamics and Active Controls in Chemical Reactions"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574095596252416","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"On the dynamics of the vibrationally selective electronic energy transfer from metastable xenon atoms to nitrogen molecules"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574096202910720","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Study of the products of the reactions of N2(A3Σu+): The effect of vibrational energy in N2(A)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574096212597376","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Excitation-transfer reactions from nitrogen N2(A3.SIGMA.u+) and carbon monoxide(a3.PI.) to hydroxyl"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855571045671552","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Preface"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855571211100032","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Orientation and Alignment of Reaction Products"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855571362455040","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Electron Transfer Reactions in Chemistry: Theory and Experiment (Nobel Lecture)"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137045925525632","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"On the interaction potentials for the electronic energy transfer reactions Xe(3P0,2)+N2(X)→Xe(1S0)+N2(B 3Πg)"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418519208816128","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Molecular Reaction Dynamics"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418519364838912","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Branching fractions of the product NO(A 2Σ+, ν=0, 1) and NO (B2Πr, ν=0) emissions observed as a function of ν′ in the energy transfer reaction N2(A3Σ+u, ν′) + NO (X2Πr, ν″=0)"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418519411526272","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Observation of anisotropic interactions between metastable atoms and target molecules by two-dimensional collisional ionization electron spectroscopy"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418519603415168","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Chemical stereodynamics: retrospect and prospect"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699996216803840","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Reactions of N<sub>2</sub>(<i>A</i><sup>3</sup>Σ)"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981468567447296","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Evaluated Chemical Kinetics Data for Reactions of N(2D), N(2P), and N2(A 3Σu+) in the Gas Phase"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981470453570944","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The study of E-E energy transfer between CO(a3Π, ν′) and NO(X2Π, ν″ = 0) in beams"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981470470863360","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Dynamical aspects of stereochemistry"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981471117531392","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The intermolecular potential in NO–N2 and (NO–N2)+ systems: implications for the neutralization of ionic molecular aggregates"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544421147805312","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Orientation and Alignment in Reactive Beam Collisions: Recent Progress"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825893780499072","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Steric effect in the energy transfer reaction of Ar(P23)+N2"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825894022600448","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Foreword"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388844822122752","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Experimental and theoretical angular and translational energy distributions for the reaction CN+D2→DCN+D"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670320448899712","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"State-to-state excitation of NO(<i>A</i> 2Σ+, <i>v</i>′=0,1,2) by N2(<i>A</i> 3Σ+<i>u</i>, <i>v</i>′=0,1,2)"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670320991543936","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Effect of Mutual Configuration between Molecular Orientation and Atomic Orientation in the Oriented Ar<mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\"><mml:mo stretchy=\"false\">(</mml:mo><mml:mmultiscripts><mml:mi>P</mml:mi><mml:mn>2</mml:mn><mml:none/><mml:mprescripts/><mml:none/><mml:mn>3</mml:mn></mml:mmultiscripts><mml:mo stretchy=\"false\">)</mml:mo><mml:mo>+</mml:mo><mml:mtext mathvariant=\"normal\">Oriented</mml:mtext></mml:math><mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\"><mml:msub><mml:mi>CF</mml:mi><mml:mn>3</mml:mn></mml:msub><mml:mi mathvariant=\"normal\">H</mml:mi></mml:math>Reaction"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670321257937152","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Crossed beam studies of four-atom reactions: The dynamics of OH+D2"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951794144669184","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Collisional alignment and orientation of atomic outer shells I. Direct excitation by electron and atom impact"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233269278999552","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Spectroscopic Study of Electronic Energy Transfer from N<sub>2</sub>(A) and CO(a) to NO in a Beam Experiment"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233269511688576","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Energy transfer reactions of N2(A3.SIGMA.u+). 5. Quenching by hydrogen halides, methyl halides, and other molecules"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233270510774016","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Improvement of the adiabatic phase integral for the Landau–Zener-type curve crossing"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1021/jp507696y"},{"@type":"KAKEN","@value":"PRODUCT-13896231"},{"@type":"OPENAIRE","@value":"doi_dedup___::d4ecd63a249dfe310f116a5a865bd870"}]}