{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360004233243950464.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/ma302558z"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/ma302558z"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"A Highly Efficient Catalytic System for Polycondensation of 2,7-Dibromo-9,9-dioctylfluorene and 1,2,4,5-Tetrafluorobenzene via Direct Arylation"}],"description":[{"notation":[{"@value":"Direct arylation polymerization has attracted a great deal of attention as an efficient method for synthesizing π-conjugated polymers without the use of organometallic reagents. This paper describes that Pd2(dba)3·CHCl3 (0.5 mol %) and P(C6H4-o-OMe)3 (L1, 2.0 mol %), in conjunction with a carboxylic acid (AcOH or PivOH) and a base (Cs2CO3), exhibit high catalyst performance in polycondensation of 2,7-dibromo-9,9-dioctylfluorene and 1,2,4,5-tetrafluorobenzene. Unlike conventional catalytic direct arylation systems that have need to use highly polar solvents such as DMA and DMF, the present catalytic system is sufficiently reactive in THF and toluene to afford poly[(9,9-dioctylfluorene-2,7-diyl)-alt-(2,3,5,6-tetrafluoro-1,4-phenylene)] (PDOF-TP) with extremely high molecular weight (Mn up to 347 700) in high yield."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1420564276175347072","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"50598844"},{"@type":"NRID","@value":"1000050598844"},{"@type":"ORCID","@value":"0000-0002-2437-2787"},{"@type":"NRID","@value":"9000259862904"},{"@type":"NRID","@value":"9000362823427"},{"@type":"NRID","@value":"9000415432070"},{"@type":"NRID","@value":"9000002143970"},{"@type":"NRID","@value":"9000256027215"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/7000009025"}],"foaf:name":[{"@value":"Masayuki Wakioka"}],"jpcoar:affiliationName":[{"@value":"International Research Center for Elements Science (IRCELS), Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004233243950465","@type":"Researcher","foaf:name":[{"@value":"Yutaro Kitano"}],"jpcoar:affiliationName":[{"@value":"International Research Center for Elements Science (IRCELS), Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1030003658364543616","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"40134837"},{"@type":"NRID","@value":"1000040134837"},{"@type":"CINII_AUTHOR_ID","@value":"DA18612867"},{"@type":"URI","@value":"https://ci.nii.ac.jp/author/DA18612867#entity"},{"@type":"URI","@value":"https://viaf.org/viaf/NII%7CDA18612867"},{"@type":"NRID","@value":"9000020293935"},{"@type":"NRID","@value":"9000257715421"},{"@type":"NRID","@value":"9000002014048"},{"@type":"NRID","@value":"9000362823456"},{"@type":"NRID","@value":"9000253120932"},{"@type":"NRID","@value":"9000256019209"},{"@type":"NRID","@value":"9000257708709"},{"@type":"NRID","@value":"9000022223799"},{"@type":"NRID","@value":"9000253129443"},{"@type":"NRID","@value":"9000001731146"},{"@type":"NRID","@value":"9000257710876"},{"@type":"NRID","@value":"9000018233245"},{"@type":"NRID","@value":"9000020037313"},{"@type":"NRID","@value":"9000256015920"},{"@type":"NRID","@value":"9000256030809"},{"@type":"NRID","@value":"9000256027219"},{"@type":"NRID","@value":"9000021769312"},{"@type":"NRID","@value":"9000255702632"},{"@type":"NRID","@value":"9000010100853"},{"@type":"NRID","@value":"9000009986776"},{"@type":"NRID","@value":"9000398020092"},{"@type":"NRID","@value":"9000257732518"},{"@type":"NRID","@value":"9000020954666"},{"@type":"NRID","@value":"9000253123042"},{"@type":"NRID","@value":"9000021888404"},{"@type":"NRID","@value":"9000257712575"},{"@type":"NRID","@value":"9000253123923"},{"@type":"NRID","@value":"9000252800619"},{"@type":"NRID","@value":"9000010104688"},{"@type":"NRID","@value":"9000000800988"},{"@type":"NRID","@value":"9000256046564"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/7000008315"}],"foaf:name":[{"@value":"Fumiyuki 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(ACS)"}],"prism:publicationDate":"2013-01-10","prism:volume":"46","prism:number":"2","prism:startingPage":"370","prism:endingPage":"374"},"reviewed":"false","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/ma302558z"}],"createdAt":"2013-01-10","modifiedAt":"2024-05-04","project":[{"@id":"https://cir.nii.ac.jp/crid/1040000782149863552","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"23350042"},{"@type":"JGN","@value":"JP23350042"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23350042/"}],"notation":[{"@language":"ja","@value":"π共役系高分子の精密合成を志向した高効率Ｃ－Ｈ結合アリール化触媒の開発研究"},{"@language":"en","@value":"Development of Highly Efficient Direct Arylation Catalysts for Precisely Controlled Synthesis of pi-Conjugated 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