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However, most organic neutral radicals are insulators, because they cannot form sufficient intermolecular interactions due to the bulky substituent groups required for stabilization. Here we report that one-dimensional assemblies of carbon-centered neutral π-radicals, namely 4,8,12,trioxotriangulene derivatives, possess effective conducting pathways as a result of strong intermolecular interactions based on two-electron-multicenter bonding. The columns of trioxotriangulene derivatives with weak π-dimerization and uniform π-stacking exhibit semiconducting behaviors, with high conductivities of ~10<jats:sup>−3</jats:sup> S cm<jats:sup>−1</jats:sup> as a single component purely organic molecular system. We exploit this general tendency to form one-dimensional assemblies, and the large 25 π-electronic system with a robust condensed polycyclic structure, to obtain mixed-valence salts consisting of neutral radicals and the corresponding anionic species with a higher room-temperature conductivity of 1–125 S cm<jats:sup>−1</jats:sup>.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1420001326209675392","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"40535358"},{"@type":"NRID","@value":"1000040535358"},{"@type":"NRID","@value":"9000283740941"},{"@type":"NRID","@value":"9000396134302"},{"@type":"NRID","@value":"9000001128204"},{"@type":"NRID","@value":"9000283124550"},{"@type":"NRID","@value":"9000258600269"},{"@type":"NRID","@value":"9000258598059"},{"@type":"NRID","@value":"9000256026975"},{"@type":"NRID","@value":"9000256027093"},{"@type":"NRID","@value":"9000255701854"},{"@type":"NRID","@value":"9000258601358"},{"@type":"NRID","@value":"9000334734819"},{"@type":"NRID","@value":"9000255702391"},{"@type":"NRID","@value":"9000258594690"},{"@type":"NRID","@value":"9000302387422"},{"@type":"NRID","@value":"9000283122846"},{"@type":"NRID","@value":"9000002046208"},{"@type":"NRID","@value":"9000107380612"},{"@type":"NRID","@value":"9000258599348"},{"@type":"NRID","@value":"9000402248307"},{"@type":"NRID","@value":"9000258599135"},{"@type":"NRID","@value":"9000283122027"},{"@type":"NRID","@value":"9000256896585"},{"@type":"NRID","@value":"9000255702536"},{"@type":"NRID","@value":"9000256029622"},{"@type":"NRID","@value":"9000257721442"},{"@type":"NRID","@value":"9000019077628"},{"@type":"NRID","@value":"9000002105447"},{"@type":"NRID","@value":"9000405913408"},{"@type":"NRID","@value":"9000283123884"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/tsuyoshimurata"}],"foaf:name":[{"@value":"Tsuyoshi 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