{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360004233574819968.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1039/c3cc48198k"}},{"identifier":{"@type":"URI","@value":"http://pubs.rsc.org/en/content/articlepdf/2014/CC/C3CC48198K"}},{"identifier":{"@type":"DOI","@value":"10.1002/chin.201415045"}},{"identifier":{"@type":"PMID","@value":"24310477"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Synthesis and properties of cycloparaphenylene-2,7-pyrenylene: a pyrene-containing carbon nanoring"}],"description":[{"notation":[{"@value":"The first synthesis of a pyrene-containing carbon nanoring, cyclo[12]paraphenylene[2]-2,7-pyrenylene ([12,2]CPPyr), is described. Through a sequence of stepwise macrocyclization using Pd and Ni catalysts followed by aromatization of L-shaped cyclohexane units afforded a [12,2]CPPyr in five steps from commercially available compounds. The UV-vis absorption and fluorescence spectra as well as TD-DFT calculations clarified the unique photophysical and electronic properties of the [12,2]CPPyr."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380004233574819841","@type":"Researcher","foaf:name":[{"@value":"Akiko Yagi"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004233574819968","@type":"Researcher","foaf:name":[{"@value":"Gandikota Venkataramana"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004233574819978","@type":"Researcher","foaf:name":[{"@value":"Yasutomo Segawa"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004233574819988","@type":"Researcher","foaf:name":[{"@value":"Kenichiro Itami"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"13597345"},{"@type":"EISSN","@value":"1364548X"},{"@type":"PISSN","@value":"09317597"},{"@type":"EISSN","@value":"15222667"}],"prism:publicationName":[{"@value":"Chem. 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