{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360004233606152832.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1039/c6dt02075e"}},{"identifier":{"@type":"URI","@value":"http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT02075E"}},{"identifier":{"@type":"PMID","@value":"27383267"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"A long-tethered (P–B–P)-pincer ligand: synthesis, complexation, and application to catalytic dehydrogenation of alkanes"}],"description":[{"type":"abstract","notation":[{"@value":"<p>A new long-tethered boron-containing (P–B–P)-pincer ligand has been synthesized. This ligand was introduced to Ir to form (P–B–P)Ir(H)Cl complex. Subsequent reaction with <italic>n</italic>BuLi led to the formation of dihydride complex (P–B–P)Ir(H)<sub>2</sub>. Both complexes were found to be moderately active for the catalytic dehydrogenation of alkanes.</p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380004233606152965","@type":"Researcher","foaf:name":[{"@value":"Enrique Huang Kwan"}],"jpcoar:affiliationName":[{"@value":"Department of Applied Chemistry"},{"@value":"Faculty of Science and Engineering"},{"@value":"Chuo University"},{"@value":"112-8551 Tokyo"},{"@value":"Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004233606152707","@type":"Researcher","foaf:name":[{"@value":"Yasushi Jack Kawai"}],"jpcoar:affiliationName":[{"@value":"Department of Applied Chemistry"},{"@value":"Faculty of Science and Engineering"},{"@value":"Chuo University"},{"@value":"112-8551 Tokyo"},{"@value":"Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004233606153216","@type":"Researcher","foaf:name":[{"@value":"Sei Kamakura"}],"jpcoar:affiliationName":[{"@value":"Department of Applied Chemistry"},{"@value":"Faculty of Science and Engineering"},{"@value":"Chuo University"},{"@value":"112-8551 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This work was supported by the National Science Foundation (CHE 9800184 to M.B.H.), by the University of California Energy Institute and University of California Santa Barbara (to W.C.K.), and by the German Research Association (DFG, to M.W.H). We thank Dr. R. Mynott and Mrs. C. Wirtz, MPI für Kohlenforschung, for NMR spectroscopic investigations."}]},{"@id":"https://cir.nii.ac.jp/crid/1361418521024479744","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Efficient thermochemical alkane dehydrogenation and isomerization catalyzed by an iridium pincer complex"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418521061130240","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A short history of<i>SHELX</i>"}]},{"@id":"https://cir.nii.ac.jp/crid/1361694368368478208","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis, structure, and reactivity of pincer-type iridium complexes having gallyl- and indyl-metalloligands utilizing 2,5-bis(6-phosphino-2-pyridyl)pyrrolide as a new scaffold for metal–metal bonds"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699994875470848","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Boryl-assisted hydrogenolysis of a nickel–methyl bond"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699995502366592","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Recent Advances in Alkane Dehydrogenation Catalyzed by Pincer Complexes"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981469235412096","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Facile Insertion of Rh and Ir into a Boron–Phenyl Bond, Leading to Boryl/Bis(phosphine) PBP Pincer Complexes"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981469607204736","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A Highly Stable Adamantyl-Substituted Pincer-Ligated Iridium Catalyst for Alkane Dehydrogenation"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981470178543616","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Iridium complexes of new NCP pincer ligands: catalytic alkane dehydrogenation and alkene isomerization"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981470269805696","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A comparison of models for calculating nuclear magnetic resonance shielding tensors"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981470996425728","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"On the Mechanism of the Dehydroaromatization of Hexane to Benzene by an Iridium Pincer Catalyst"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262943701134976","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Scope and Mechanism of Homogeneous Tantalum/Iridium Tandem Catalytic Alkane/Alkene Upgrading using Sacrificial Hydrogen Acceptors"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262944545581824","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Iridium Bis(phosphinite) <i>p</i>-XPCP Pincer Complexes:  Highly Active Catalysts for the Transfer Dehydrogenation of Alkanes"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262945341368448","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Self-consistent perturbation theory of diamagnetism"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262945785151616","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Applications of PC(sp<sup>3</sup>)P Iridium Complexes in Transfer Dehydrogenation of Alkanes"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262945865304448","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Théorie quantique des courants interatomiques dans les combinaisons aromatiques"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262945911836288","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"On the Mechanism of the Palladium(II)-Catalyzed Decarboxylative Olefination of Arene Carboxylic Acids. 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