{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360004236988323968.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/bcsj.20200043"}},{"identifier":{"@type":"URI","@value":"https://academic.oup.com/bcsj/article-pdf/93/9/1086/56305230/bcsj.20200043.pdf"}},{"identifier":{"@type":"NAID","@value":"130007905662"}}],"dc:title":[{"@value":"Regioselective Hydrosilylation of Olefins Catalyzed by Co-Iminobipyridine Complexes: The Role of Cyclohexyl Substituent on the Imino Nitrogen"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title>\n               <jats:p>Regioselective hydrosilylation of aliphatic olefins catalyzed by Co-iminobipyridine complexes, Co〈R〉, were investigated, where R indicates a substituent on the imino nitrogen in an iminobipyridine ligand (iminobypyridine = [2,2′-bpy]-6-C(Me)=N-R). Syntheses of two complexes, Co〈Mes〉 (Mes = 2,4,6-trimethylphenyl) and Co〈Cy〉 (Cy = cyclohexyl), and comparison of their catalytic activity for hydrosilylation of 1-octene with diphenylsilane revealed that the reaction system using Co〈Mes〉 produced a mixture of anti-Markovnikov and Markovnikov hydrosilylation products, whereas that using Co〈Cy〉 produced the anti-Markovnikov product selectively. Crystal structures of these complexes implied that a catalytically active species derived from Co〈Cy〉 has narrower active space for hydrosilylation than that from Co〈Mes〉. According to the Chalk-Harrod mechanism, there are two types of hydrosilylated products (anti-Markovnikov and Markovnikov products), which stem from the way of terminal olefin insertion into an M-H bond (that is 1,2- or 2,1-insertion). One of the intermediates derived from Co〈Cy〉 in the Chalk-Harrod mechanism has hydride and silyl ligands. In the step of olefin insertion into the Co-H bond, 1,2-insertion is more likely to occur from the steric point of view, leading to selective formation of the anti-Markovnikov product.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1583387453073282816","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000410195887"}],"foaf:name":[{"@value":"Daisuke Taguchi"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Graduate School of Science, Osaka City University, Sumiyoshi-ku, Osaka 558-8585 , Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1030003658552873473","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"30433874"},{"@type":"NRID","@value":"1000030433874"},{"@type":"ORCID","@value":"0000-0003-1608-2752"},{"@type":"NRID","@value":"9000411767794"},{"@type":"NRID","@value":"9000257734244"},{"@type":"NRID","@value":"9000257730859"},{"@type":"NRID","@value":"9000018718077"},{"@type":"NRID","@value":"9000000878321"},{"@type":"NRID","@value":"9000016385877"},{"@type":"NRID","@value":"9000399497733"},{"@type":"NRID","@value":"9000257718921"},{"@type":"NRID","@value":"9000016603469"},{"@type":"NRID","@value":"9000412593552"},{"@type":"NRID","@value":"9000410195888"},{"@type":"NRID","@value":"9000402473519"},{"@type":"NRID","@value":"9000020983080"},{"@type":"NRID","@value":"9000018232505"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0061247"}],"foaf:name":[{"@value":"Katsuaki Kobayashi"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Graduate School of Science, Osaka City University, Sumiyoshi-ku, Osaka 558-8585 , Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1583387453073282818","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000410195889"}],"foaf:name":[{"@value":"Toshiyuki Moriuchi"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Graduate School of Science, Osaka City University, Sumiyoshi-ku, Osaka 558-8585 , Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1583387453073282819","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000410195890"}],"foaf:name":[{"@value":"Hiroshi Nakazawa"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Graduate School of Science, Osaka City University, Sumiyoshi-ku, Osaka 558-8585 , Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00092673"},{"@type":"EISSN","@value":"13480634"}],"prism:publicationName":[{"@value":"Bulletin of the Chemical Society of 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