{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360004239507078400.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.3390/molecules191016477"}},{"identifier":{"@type":"URI","@value":"https://www.mdpi.com/1420-3049/19/10/16477/pdf"}},{"identifier":{"@type":"PMID","@value":"25314607"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Design of Composite Photocatalyst of TiO2 and Y-Zeolite for Degradation of 2-Propanol in the Gas Phase under UV and Visible Light Irradiation"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>Hydrophobic Y-zeolite (SiO2/Al2O3 = 810) and TiO2 composite photocatalysts were designed by using two different types of TiO2 precursors, i.e., titanium ammonium oxalate and ammonium hexafluorotitanate. The porous structure, surface property and state of TiO2 were investigated by various characterization techniques. By using an ammonium hexafluorotitanate as a precursor, hydrophobic modification of the Y-zeolite surface and realizing visible light sensitivity was successfully achieved at the same time after calcination at 773 K in the air. The prepared sample still maintained the porous structure of Y-zeolite and a large surface area. Highly crystalline anatase TiO2 was also formed on the Y-zeolite surface by the role of fluorine in the precursor. The usages of ammonium hexafluorotitanate were effective for the improvement of the photocatalytic performance of the composite  in the degradation of 2-propanol in the gas phase under UV and visible light  (λ > 420 nm) irradiation.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1420564276186330240","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"50525136"},{"@type":"NRID","@value":"1000050525136"},{"@type":"NRID","@value":"9000016416486"},{"@type":"NRID","@value":"9000324638971"},{"@type":"NRID","@value":"9000287291609"},{"@type":"NRID","@value":"9000408910016"},{"@type":"NRID","@value":"9000258690285"},{"@type":"NRID","@value":"9000020341675"},{"@type":"NRID","@value":"9000347184561"},{"@type":"NRID","@value":"9000256029666"},{"@type":"NRID","@value":"9000257735508"},{"@type":"NRID","@value":"9000347169895"},{"@type":"NRID","@value":"9000258691170"},{"@type":"NRID","@value":"9000258690101"},{"@type":"NRID","@value":"9000257731089"},{"@type":"NRID","@value":"9000316688754"},{"@type":"NRID","@value":"9000402400593"},{"@type":"NRID","@value":"9000258689907"},{"@type":"NRID","@value":"9000329003726"},{"@type":"NRID","@value":"9000413697052"},{"@type":"NRID","@value":"9000379609804"},{"@type":"NRID","@value":"9000016386415"},{"@type":"NRID","@value":"9000016386374"},{"@type":"NRID","@value":"9000258690311"},{"@type":"NRID","@value":"9000258690850"},{"@type":"NRID","@value":"9000257784804"},{"@type":"NRID","@value":"9000019077738"},{"@type":"NRID","@value":"9000413738950"},{"@type":"NRID","@value":"9000256029040"},{"@type":"NRID","@value":"9000289261755"},{"@type":"NRID","@value":"9000262366779"},{"@type":"NRID","@value":"9000345291551"},{"@type":"NRID","@value":"9000286626509"},{"@type":"NRID","@value":"9000258690800"},{"@type":"NRID","@value":"9000257734046"},{"@type":"NRID","@value":"9000107384896"},{"@type":"NRID","@value":"9000345257241"},{"@type":"NRID","@value":"9000329017198"},{"@type":"NRID","@value":"9000256028056"},{"@type":"NRID","@value":"9000258690961"},{"@type":"NRID","@value":"9000257731108"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/takashi_kamegawa"}],"foaf:name":[{"@value":"Takashi 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Yamashita"}],"jpcoar:affiliationName":[{"@value":"Division of Materials and Manufacturing Science, Graduate School of Engineering,  Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan"},{"@value":"Elements Strategy Initiative for Catalysts and Batteries (ESICB), Kyoto University, Katsura,  Kyoto 615-8520, Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"EISSN","@value":"14203049"}],"prism:publicationName":[{"@value":"Molecules"}],"dc:publisher":[{"@value":"MDPI AG"}],"prism:publicationDate":"2014-10-13","prism:volume":"19","prism:number":"10","prism:startingPage":"16477","prism:endingPage":"16488"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","dc:rights":["https://creativecommons.org/licenses/by/4.0/"],"url":[{"@id":"https://www.mdpi.com/1420-3049/19/10/16477/pdf"}],"createdAt":"2014-10-14","modifiedAt":"2025-10-11","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Titanium","dc:title":"Titanium"},{"@id":"https://cir.nii.ac.jp/all?q=photocatalyst","dc:title":"photocatalyst"},{"@id":"https://cir.nii.ac.jp/all?q=Surface%20Properties","dc:title":"Surface Properties"},{"@id":"https://cir.nii.ac.jp/all?q=Ultraviolet%20Rays","dc:title":"Ultraviolet Rays"},{"@id":"https://cir.nii.ac.jp/all?q=Y-zeolite","dc:title":"Y-zeolite"},{"@id":"https://cir.nii.ac.jp/all?q=Organic%20chemistry","dc:title":"Organic chemistry"},{"@id":"https://cir.nii.ac.jp/all?q=Silicon%20Dioxide","dc:title":"Silicon Dioxide"},{"@id":"https://cir.nii.ac.jp/all?q=Article","dc:title":"Article"},{"@id":"https://cir.nii.ac.jp/all?q=Catalysis","dc:title":"Catalysis"},{"@id":"https://cir.nii.ac.jp/all?q=hydrophobic%20modification","dc:title":"hydrophobic modification"},{"@id":"https://cir.nii.ac.jp/all?q=2-Propanol","dc:title":"2-Propanol"},{"@id":"https://cir.nii.ac.jp/all?q=QD241-441","dc:title":"QD241-441"},{"@id":"https://cir.nii.ac.jp/all?q=decomposition%20of%202-propanol%20gas","dc:title":"decomposition of 2-propanol gas"},{"@id":"https://cir.nii.ac.jp/all?q=Zeolites","dc:title":"Zeolites"},{"@id":"https://cir.nii.ac.jp/all?q=TiO2","dc:title":"TiO2"},{"@id":"https://cir.nii.ac.jp/all?q=composite","dc:title":"composite"},{"@id":"https://cir.nii.ac.jp/all?q=TiO%3Csub%3E2%3C/sub%3E","dc:title":"TiO<sub>2</sub>"},{"@id":"https://cir.nii.ac.jp/all?q=Hydrophobic%20and%20Hydrophilic%20Interactions","dc:title":"Hydrophobic and Hydrophilic Interactions"},{"@id":"https://cir.nii.ac.jp/all?q=visible%20light","dc:title":"visible light"}],"project":[{"@id":"https://cir.nii.ac.jp/crid/1040000782299616640","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"26420786"},{"@type":"JGN","@value":"JP26420786"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-26420786/"}],"notation":[{"@language":"ja","@value":"階層的ナノ空間を持つ無機多孔体の触媒機能化と環境浄化反応への応用"},{"@language":"en","@value":"Functionalization of Hierarchically Structured Inorganic Porous Materials as Heterogeneous Catalysts for Environmental Purification"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050025031480291456","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Correlation between some physical properties of titanium dioxide particles and their photocatalytic activity for some probe reactions in aqueous 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