{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360004239508315648.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.3390/molecules23112769"}},{"identifier":{"@type":"URI","@value":"https://www.mdpi.com/1420-3049/23/11/2769/pdf"}},{"identifier":{"@type":"PMID","@value":"30366430"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Selective Double Addition Reaction of an E‒H Bond (E = Si, B) to a C≡N Triple Bond of Organonitriles"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>The catalytic double hydrometalation such as hydrosilylation and hydroborylation of organonitriles has attracted considerable attention because the obtained products are widely used in organic synthesis and it is thought to be one of the effective methods for reduction of organonitriles. However, the examples of these reactions are quite limited to date. This paper summarizes the development of selective double hydrosilylation, double hydroborylation, and dihydroborylsilylation of organonitriles, including their reaction mechanisms and the role of the metal species in the catalytic cycle.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1420564276187275136","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"60382032"},{"@type":"NRID","@value":"1000060382032"},{"@type":"ORCID","@value":"0000-0002-1430-8677"},{"@type":"NRID","@value":"9000347163318"},{"@type":"NRID","@value":"9000256024633"},{"@type":"NRID","@value":"9000400162379"},{"@type":"NRID","@value":"9000256024739"},{"@type":"NRID","@value":"9000001585260"},{"@type":"NRID","@value":"9000243894921"},{"@type":"NRID","@value":"9000411490264"},{"@type":"NRID","@value":"9000406034299"},{"@type":"NRID","@value":"9000001623922"},{"@type":"NRID","@value":"9000241491617"},{"@type":"NRID","@value":"9000001624519"},{"@type":"NRID","@value":"9000010389599"},{"@type":"NRID","@value":"9000257724157"},{"@type":"NRID","@value":"9000387917145"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0069671"}],"foaf:name":[{"@value":"Masumi Itazaki"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Graduate School of Science, Osaka City University, Sumiyoshi-ku, Osaka 558-8585, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004239508315649","@type":"Researcher","foaf:name":[{"@value":"Hiroshi Nakazawa"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Graduate School of Science, Osaka City University, Sumiyoshi-ku, Osaka 558-8585, Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"EISSN","@value":"14203049"}],"prism:publicationName":[{"@value":"Molecules"}],"dc:publisher":[{"@value":"MDPI AG"}],"prism:publicationDate":"2018-10-25","prism:volume":"23","prism:number":"11","prism:startingPage":"2769"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","dc:rights":["https://creativecommons.org/licenses/by/4.0/"],"url":[{"@id":"https://www.mdpi.com/1420-3049/23/11/2769/pdf"}],"createdAt":"2018-10-26","modifiedAt":"2025-10-11","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Silicon","dc:title":"Silicon"},{"@id":"https://cir.nii.ac.jp/all?q=dihydroborylsilylation","dc:title":"dihydroborylsilylation"},{"@id":"https://cir.nii.ac.jp/all?q=hydrosilylation","dc:title":"hydrosilylation"},{"@id":"https://cir.nii.ac.jp/all?q=Organic%20chemistry","dc:title":"Organic chemistry"},{"@id":"https://cir.nii.ac.jp/all?q=Review","dc:title":"Review"},{"@id":"https://cir.nii.ac.jp/all?q=Catalysis","dc:title":"Catalysis"},{"@id":"https://cir.nii.ac.jp/all?q=hydroborylation","dc:title":"hydroborylation"},{"@id":"https://cir.nii.ac.jp/all?q=QD241-441","dc:title":"QD241-441"}],"project":[{"@id":"https://cir.nii.ac.jp/crid/1040282256888253184","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"16K05728"},{"@type":"JGN","@value":"JP16K05728"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-16K05728/"}],"notation":[{"@language":"ja","@value":"鉄触媒による不飽和結合への典型元素－水素結合の不斉付加反応の開発"},{"@language":"en","@value":"Development of asymmetric addition reactions of E-H bond (E = main group elements) to unsaturated bonds catalyzed by an iron complex"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050303951699430912","@type":"Article","resourceType":"学術雑誌論文(journal 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