{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360004239979425792.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.4236/ajac.2013.48045"}},{"identifier":{"@type":"URI","@value":"http://www.scirp.org/journal/PaperDownload.aspx?DOI=10.4236/ajac.2013.48045"}},{"identifier":{"@type":"URI","@value":"https://www.scirp.org/journal/paperinformation?paperid=35435"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Complex Formation of 1,6-Anhydro-&lt;i&gt;β&lt;/i&gt;-Maltose and Sodium Ions Using Single-Crystal X-Ray Crystallography and NMR Spectroscopy"}],"description":[{"notation":[{"@value":"Complex formation of 1,6-anhydro-β-maltose and sodium ions was  characterized using single-crystal X-ray crystallography and solution- and  solid-state NMR spectroscopy. The 7-coordination structure, comprising two 1,6-anhydro-β-maltoses, a  thiocyanate ion and a sodium ion, was identified in the crystal of the complex,  where a sodium ion was positioned in the center of the pentagon. In the NMR  study, the line broadening of 23Na signals and the decrease of the  spin-lattice relaxation times (T1)  of 23Na were observed in CD3OD in the presence of 1,6-anhydro-β-maltose, indicating complex  formation."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380004239979425798","@type":"Researcher","foaf:name":[{"@value":"Takashi Fujimoto"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004239979425797","@type":"Researcher","foaf:name":[{"@value":"Daisuke Miura"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004239979425794","@type":"Researcher","foaf:name":[{"@value":"Takayuki Kato"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004239979425792","@type":"Researcher","foaf:name":[{"@value":"Osamu Kamo"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004239979425795","@type":"Researcher","foaf:name":[{"@value":"Yuichi Shimoikeda"}]},{"@id":"https://cir.nii.ac.jp/crid/1380004239979425796","@type":"Researcher","foaf:name":[{"@value":"Tomoya 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