A Macrocyclic Gold(I)–Biphenylene Complex: Triangular Molecular Structure with Twisted Au<sub>2</sub>(diphosphine) Corners and Reductive Elimination of [6]Cycloparaphenylene

DOI DOI Web Site Web Site Web Site View 3 Remaining Hide Research Data 7 Citations 72 References
  • Yoshitaka Tsuchido
    Laboratory for Chemistry and Life Science Institute of Innovative Research Tokyo Institute of Technology 4259-R1-3 Nagatsuta, Midori-ku Yokohama 226-8503 Japan
  • Ryota Abe
    Laboratory for Chemistry and Life Science Institute of Innovative Research Tokyo Institute of Technology 4259-R1-3 Nagatsuta, Midori-ku Yokohama 226-8503 Japan
  • Tomohito Ide
    Department of Chemical Science and Engineering National Institute of Technology, Tokyo College 1220-2 Kunugida-machi, Hachioji-shi Tokyo 193-0997 Japan
  • Kohtaro Osakada
    Laboratory for Chemistry and Life Science Institute of Innovative Research Tokyo Institute of Technology 4259-R1-3 Nagatsuta, Midori-ku Yokohama 226-8503 Japan

Search this article

Description

<jats:title>Abstract</jats:title><jats:p>The digold(I) complex [Au<jats:sub>2</jats:sub>Cl<jats:sub>2</jats:sub>(Cy<jats:sub>2</jats:sub>PCH<jats:sub>2</jats:sub>PCy<jats:sub>2</jats:sub>)] reacts with 4,4′‐diphenylene diboronic acid to form a triangular macrocyclic complex with twisted Au‐P‐C‐P‐Au groups at the three corners. The synthesis of the complex and its chemical oxidation produced [6]cycloparaphenylene ([6]CPP) in 59 % overall yield.</jats:p>

Journal

Citations (7)*help

See more

References(72)*help

See more

Related Data

See more

Related Projects

See more

Report a problem

Back to top