{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360011142932014720.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1029/gb002i004p00299"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1029%2FGB002i004p00299"}},{"identifier":{"@type":"URI","@value":"https://agupubs.onlinelibrary.wiley.com/doi/pdf/10.1029/GB002i004p00299"}},{"identifier":{"@type":"NAID","@value":"30034798526"}}],"dc:title":[{"@value":"Biogeochemical aspects of atmospheric methane"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>Methane is the most abundant organic chemical in Earth's atmosphere, and its concentration is increasing with time, as a variety of independent measurements have shown. Photochemical reactions oxidize methane in the atmosphere; through these reactions, methane exerts strong influence over the chemistry of the troposphere and the stratosphere and many species including ozone, hydroxyl radicals, and carbon monoxide. Also, through its infrared absorption spectrum, methane is an important greenhouse gas in the climate system. We describe and enumerate key roles and reactions. Then we focus on two kinds of methane production: microbial and thermogenic. Microbial methanogenesis is described, and key organisms and substrates are identified along with their properties and habitats. Microbial methane oxidation limits the release of methane from certain methanogenic areas. Both aerobic and anaerobic oxidation are described here along with methods to measure rates of methane production and oxidation experimentally. Indicators of the origin of methane, including C and H isotopes, are reviewed. We identify and evaluate several constraints on the budget of atmospheric methane, its sources, sinks and residence time. From these constraints and other data on sources and sinks we construct a list of sources and sinks, identities, and sizes. The quasi‐steady state (defined in the text) annual source (or sink) totals about 310(±60) × 10<jats:sup>12</jats:sup> mol (500(±95) × 10<jats:sup>12</jats:sup> g), but there are many remaining uncertainties in source and sink sizes and several types of data that could lead to stronger constraints and revised estimates in the future. It is particularly difficult to identify enough sources of radiocarbon‐free methane.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1583668926191265792","@type":"Researcher","foaf:name":[{"@value":"R. J. Cicerone"}]},{"@id":"https://cir.nii.ac.jp/crid/1380011142932014593","@type":"Researcher","foaf:name":[{"@value":"R. S. Oremland"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"08866236"},{"@type":"EISSN","@value":"19449224"},{"@type":"PISSN","@value":"http://id.crossref.org/issn/08866236"},{"@type":"PISSN","@value":"https://id.crossref.org/issn/08866236"},{"@type":"NCID","@value":"AA10764878"}],"prism:publicationName":[{"@value":"Global Biogeochemical Cycles"}],"dc:publisher":[{"@value":"American Geophysical Union (AGU)"}],"prism:publicationDate":"1988-12","prism:volume":"2","prism:number":"4","prism:startingPage":"299","prism:endingPage":"327"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1029%2FGB002i004p00299"},{"@id":"https://agupubs.onlinelibrary.wiley.com/doi/pdf/10.1029/GB002i004p00299"}],"createdAt":"2008-02-06","modifiedAt":"2023-09-23","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050019822484838016","@type":"Article","resourceType":"学術雑誌論文(journal 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Methanogenesis from Compounds Related with the Glyoxylate Cycle by Mixed Ruminal Microbes"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282680719821696","@type":"Article","relationType":["isCitedBy"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"大気中メタンの<sup>14</sup>C同位体比測定のための試料調製"},{"@language":"en","@value":"Preparation of trace amount of atmospheric methane for measuring <sup>14</sup>C isotopic ratio"},{"@value":"大気中メタンの14C同位体比測定のための試料調製"},{"@language":"ja-Kana","@value":"タイキチュウ メタン ノ 14C ドウイタイヒ ソクテイ ノ タメ ノ シリョ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282681482665344","@type":"Article","relationType":["isReferencedBy","isCitedBy"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"2次元大気輸送モデルと地表面濃度の観測値から導出したメタン放出量"},{"@language":"en","@value":"Methane Emissions Deduced from a Two-Dimensional Atmospheric Transport Model and Surface Measurements"},{"@language":"ja-Kana","@value":"Methane Emissions Deduced from a 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カ"}]},{"@id":"https://cir.nii.ac.jp/crid/1522543654861933056","@type":"Article","relationType":["isCitedBy"],"jpcoar:relatedTitle":[{"@value":"Use of carbon and nitrogen isotope ratios in termite research"},{"@language":"ja-Kana","@value":"Use of carbon and nitrogen isotope rati"}]},{"@id":"https://cir.nii.ac.jp/crid/1523388079733598848","@type":"Article","relationType":["isCitedBy"],"jpcoar:relatedTitle":[{"@value":"Methane in the East China Sea Water"},{"@language":"ja-Kana","@value":"Methane in the East China Sea Water"}]},{"@id":"https://cir.nii.ac.jp/crid/1523669554530608512","@type":"Article","relationType":["isCitedBy"],"jpcoar:relatedTitle":[{"@value":"Effects of forage composition and growing season on methane emission from sheep in the Inner Mongolia steppe of China"},{"@language":"ja-Kana","@value":"Effects of forage composition and growing season on methane emission from sheep in the Inner Mongolia steppe of 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