{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360011144670488448.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1080/10587259708032339"}},{"identifier":{"@type":"URI","@value":"https://www.tandfonline.com/doi/pdf/10.1080/10587259708032339"}}],"dc:title":[{"@value":"Photo- and Electro-Active Amorphous Molecular material: Morphology, Structures, and Hole Transport Properties of Tris[4-(2-Thienyl)Phenyl]Amine"}],"description":[{"notation":[{"@value":"Abstract For the purpose of developing photo- and electro-active amorphous molecular materials, tris[4-(2-thienyl)phenyl]amine (TTPA) was synthesized and its molecular and crystal structures, morphological changes, and molecular and hole-transport properties were investigated. TTPA was found to readily form an amorphous glass with a glass-transition temperature of 70 °C, as characterized by differential scanning calorimetry and X-ray diffraction. In addition to the formation of a glass, TTPA was found to exhibit polymorphism. The TTPA glass exhibited a hole drift mobility of 6.4 × 10−4 cm2V−1s−1 at an electric field of 1.0 × 105 Vcm−1at 193 K."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380011144670488321","@type":"Researcher","foaf:name":[{"@value":"J. I. Sam"}],"jpcoar:affiliationName":[{"@value":"Osaka University"}]},{"@id":"https://cir.nii.ac.jp/crid/1380011144670488448","@type":"Researcher","foaf:name":[{"@value":"H. Kageyama"}],"jpcoar:affiliationName":[{"@value":"Osaka University"}]},{"@id":"https://cir.nii.ac.jp/crid/1380011144670488320","@type":"Researcher","foaf:name":[{"@value":"S. Nomura"}],"jpcoar:affiliationName":[{"@value":"Osaka University"}]},{"@id":"https://cir.nii.ac.jp/crid/1380011144670488449","@type":"Researcher","foaf:name":[{"@value":"H. Nakano"}],"jpcoar:affiliationName":[{"@value":"Osaka University"}]},{"@id":"https://cir.nii.ac.jp/crid/1380011144670488450","@type":"Researcher","foaf:name":[{"@value":"Y. Shirota"}],"jpcoar:affiliationName":[{"@value":"Osaka University"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"1058725X"},{"@type":"PISSN","@value":"15421406"}],"prism:publicationName":[{"@value":"Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals"}],"dc:publisher":[{"@value":"Informa UK Limited"}],"prism:publicationDate":"1997-04","prism:volume":"296","prism:number":"1","prism:startingPage":"445","prism:endingPage":"463"},"reviewed":"false","url":[{"@id":"https://www.tandfonline.com/doi/pdf/10.1080/10587259708032339"}],"createdAt":"2007-07-07","modifiedAt":"2026-01-29","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1390282681266594944","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Synthesis and Properties of Hyperbranched Poly(triphenylamine)s Prepared by Palladium Catalyzed C-N Coupling Reaction."}]},{"@id":"https://cir.nii.ac.jp/crid/1390295414076890496","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Acid-responsive Emission Color Changes of Diarylaminobenzylideneanilines"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1080/10587259708032339"},{"@type":"OPENAIRE","@value":"doi_dedup___::c1c83c3ebde4ad74d3f005524b9e15b4"},{"@type":"CROSSREF","@value":"10.1295/polymj.34.550_references_DOI_Nki80oIAbtaMtbO44FhOXgOpfHx"},{"@type":"CROSSREF","@value":"10.2494/photopolymer.35.341_references_DOI_Nki80oIAbtaMtbO44FhOXgOpfHx"}]}