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A series of diynylated tertiary trifluoromethylcarbinamines were obtained in high yields with good to excellent enantioselectivities (with up to 99% <jats:italic>ee</jats:italic>).</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380016868002112769","@type":"Researcher","foaf:name":[{"@value":"Fa‐Guang Zhang"}]},{"@id":"https://cir.nii.ac.jp/crid/1380011145590795906","@type":"Researcher","foaf:name":[{"@value":"Hai Ma"}]},{"@id":"https://cir.nii.ac.jp/crid/1380011145590795908","@type":"Researcher","foaf:name":[{"@value":"Jing Nie"}]},{"@id":"https://cir.nii.ac.jp/crid/1380011145590795905","@type":"Researcher","foaf:name":[{"@value":"Yan Zheng"}]},{"@id":"https://cir.nii.ac.jp/crid/1380011145590795904","@type":"Researcher","foaf:name":[{"@value":"Qingzhi Gao"}]},{"@id":"https://cir.nii.ac.jp/crid/1380016868002112768","@type":"Researcher","foaf:name":[{"@value":"Jun‐An Ma"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"16154150"},{"@type":"EISSN","@value":"16154169"}],"prism:publicationName":[{"@value":"Advanced Synthesis & Catalysis"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2012-04-27","prism:volume":"354","prism:number":"8","prism:startingPage":"1422","prism:endingPage":"1428"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fadsc.201100926"},{"@id":"https://advanced.onlinelibrary.wiley.com/doi/pdf/10.1002/adsc.201100926"}],"createdAt":"2012-04-27","modifiedAt":"2025-10-06","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002216660077312","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Mechanistic Studies and Expansion of the Substrate Scope of Direct Enantioselective Alkynylation of α-Ketiminoesters Catalyzed by Adaptable (Phebox)Rhodium(III) Complexes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846641612275328","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Organocatalyzed Formal [2 + 2] Cycloaddition of Ketimines with Allenoates: Facile Access to Azetidines with a Chiral Tetrasubstituted Carbon Stereogenic Center"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848658543966848","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Direct access to N-unprotected tetrasubstituted propargylamines via direct catalytic alkynylation of N-unprotected trifluoromethyl ketimines"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001205339889920","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"フェニルビスオキサゾリンロジウム（III）錯体を用いたα-ケトエステルおよびα-ケチミノエステルに対する直接的触媒的不斉アルキニル化反応の開発"},{"@language":"en","@value":"Development of Direct Enantioselective Alkynylation of α-Ketoester and α-Ketiminoesters Catalyzed by Phenylbis(oxazoline)Rh(III) Complexes"},{"@language":"ja-Kana","@value":"フェニルビスオキサゾリンロジウム(Ⅲ)サクタイ オ モチイタ a-ケトエステル オヨビ a-ケチミノエステル ニ タイスル チョクセツテキ ショクバイテキ フセイ アルキニルカ ハンノウ ノ カイハツ"}]},{"@id":"https://cir.nii.ac.jp/crid/2051714791998240896","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Recent advances in catalytic asymmetric C-C bond-forming reactions to ketimines promoted by metal-based catalysts"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/adsc.201100926"},{"@type":"CROSSREF","@value":"10.1021/ol401817q_references_DOI_J5oJ5M08m1ozA9zr6UlPwhz4qT5"},{"@type":"CROSSREF","@value":"10.5059/yukigoseikyokaishi.76.226_references_DOI_J5oJ5M08m1ozA9zr6UlPwhz4qT5"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20140302_references_DOI_J5oJ5M08m1ozA9zr6UlPwhz4qT5"},{"@type":"CROSSREF","@value":"10.1039/c7cc02194a_references_DOI_J5oJ5M08m1ozA9zr6UlPwhz4qT5"},{"@type":"CROSSREF","@value":"10.1021/jacs.6b01590_references_DOI_J5oJ5M08m1ozA9zr6UlPwhz4qT5"}]}