{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360016864748314240.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/bcsj.20220334"}},{"identifier":{"@type":"URI","@value":"https://academic.oup.com/bcsj/article-pdf/96/4/381/56318381/bcsj.20220334.pdf"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Biological Advantage of the Arrangements of C-Phycocyanin Chromophores in Phycobilisome from the Electronic Energy Transfer Viewpoint"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title>\n               <jats:p>In the present study, we report the electronic energy transfer (EET) rate and the EET dynamics in the hexamer of C-phycocyanin (C-PC). The EET rate for the Förster theory was calculated by a quantum chemical method and a master equation was used to describe the dynamics. Our calculation results suggest that the natural arrangements of phycocyanobilin (PCB) chromophores α84, β84, and β155 in C-PC are cooperatively well-adjusted to achieve the shortest EET time-length. It is the appropriate regular periodicity of the intermolecular distances and intermolecular angles of the ground and the first excited transition dipole moments of PCBs α84, β84, and β155, i.e., the three-fold symmetry and stacking order of their layers found in terrestrial plants and algae, that are some of the most important requisites in achieving such a highly efficient EET in PBS.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380016864748314368","@type":"Researcher","foaf:name":[{"@value":"Kenji Mishima"}],"jpcoar:affiliationName":[{"@value":"Center for Computational Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8577 , Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380016864748314241","@type":"Researcher","foaf:name":[{"@value":"Mitsuo Shoji"}],"jpcoar:affiliationName":[{"@value":"Center for Computational Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8577 , Japan"},{"@value":"JST-PRESTO, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012 , Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380016864748314240","@type":"Researcher","foaf:name":[{"@value":"Yasufumi Umena"}],"jpcoar:affiliationName":[{"@value":"Synchrotron Radiation Research Center, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8603 , Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380016864748314112","@type":"Researcher","foaf:name":[{"@value":"Yasuteru Shigeta"}],"jpcoar:affiliationName":[{"@value":"Center for Computational Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8577 , Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00092673"},{"@type":"EISSN","@value":"13480634"}],"prism:publicationName":[{"@value":"Bulletin of the Chemical Society of Japan"}],"dc:publisher":[{"@value":"Oxford University Press 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