{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360020701021994624.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1016/j.tetlet.2020.152152"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0040403920306122?httpAccept=text/xml"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0040403920306122?httpAccept=text/plain"}}],"dc:title":[{"@value":"Liebeskind-Srogl-type cross-coupling reaction of azole-2-thiones with triarylbismuthines: Synthesis of 2-arylazoles"}],"description":[{"notation":[{"@value":"Abstract   Liebeskind-Srogl-type C(HetAr)–C(Ar) bond formation using trivalent organobismuth compounds as a new class of arylating reagents is described. The reaction of benzazole-2-thiones with triarylbismuthines in the presence of 10 mol% Pd(dba)2 and 2.0 equiv. Cu(OAc)2 at 80 °C affords 2-arylbenzothiazoles, benzoxazoles, and N-methyl benzimidazole in moderate-to-high yield. The reaction is sensitive to the electronic nature of triarylbismuthines: compounds bearing an electron-withdrawing group on the phenyl ring showed higher reactivity than those having an electron-donating group."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410285300171202434","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000409499878"},{"@type":"NRID","@value":"9000366128641"},{"@type":"NRID","@value":"9000403046048"},{"@type":"NRID","@value":"9000356575744"},{"@type":"NRID","@value":"9000412195014"},{"@type":"NRID","@value":"9000402501087"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/yakka"}],"foaf:name":[{"@value":"Yuki Murata"}]},{"@id":"https://cir.nii.ac.jp/crid/1380020701021994626","@type":"Researcher","foaf:name":[{"@value":"Aki Terazoe"}]},{"@id":"https://cir.nii.ac.jp/crid/1380020701021994624","@type":"Researcher","foaf:name":[{"@value":"Misato Kiba"}]},{"@id":"https://cir.nii.ac.jp/crid/1380020701021994629","@type":"Researcher","foaf:name":[{"@value":"Yuki Kitamura"}]},{"@id":"https://cir.nii.ac.jp/crid/1410001205762943623","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000283259743"},{"@type":"NRID","@value":"9000409499880"},{"@type":"NRID","@value":"9000293841198"},{"@type":"NRID","@value":"9000366128640"},{"@type":"NRID","@value":"9000369747168"},{"@type":"NRID","@value":"9000403046052"},{"@type":"NRID","@value":"9000356575740"},{"@type":"NRID","@value":"9000402501089"},{"@type":"NRID","@value":"9000278462750"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/misyou"}],"foaf:name":[{"@value":"Mio Matsumura"}]},{"@id":"https://cir.nii.ac.jp/crid/1380020701021994625","@type":"Researcher","foaf:name":[{"@value":"Shuji Yasuike"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00404039"}],"prism:publicationName":[{"@value":"Tetrahedron Letters"}],"dc:publisher":[{"@value":"Elsevier BV"}],"prism:publicationDate":"2020-07","prism:volume":"61","prism:number":"30","prism:startingPage":"152152"},"reviewed":"false","dc:rights":["https://www.elsevier.com/tdm/userlicense/1.0/","https://www.elsevier.com/legal/tdmrep-license"],"url":[{"@id":"https://api.elsevier.com/content/article/PII:S0040403920306122?httpAccept=text/xml"},{"@id":"https://api.elsevier.com/content/article/PII:S0040403920306122?httpAccept=text/plain"}],"createdAt":"2020-06-17","modifiedAt":"2025-09-22","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1390864977281038592","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Development of Reactivity for Organobismuth (III, V) Toward Sulfur-Containing Compounds"},{"@language":"ja","@value":"多原子価有機ビスマスの含硫黄化合物に対する化学反応性の解明"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1016/j.tetlet.2020.152152"},{"@type":"OPENAIRE","@value":"doi_dedup___::3f6797d96b5a6b25abcaacd93b0d99ad"},{"@type":"CROSSREF","@value":"10.1248/yakushi.24-00121_references_DOI_O0KdmoAu8Qn4vKOyU7lohXlZG82"}]}