{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360021390569892992.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/jacs.3c06331"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/jacs.3c06331"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"<i>N</i>-Heterocyclic Carbenes with Polyfluorinated Groups at the 4- and 5-Positions from [3 + 2] Cycloadditions between Formamidinates and <i>cis</i>-1,2-Difluoroalkene Derivatives"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380021390569893123","@type":"Researcher","foaf:name":[{"@value":"Masato Ohashi"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Graduate School of Science, Osaka Metropolitan University, Sakai 599-8531 Osaka, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021390569893120","@type":"Researcher","foaf:name":[{"@value":"Kota Ando"}],"jpcoar:affiliationName":[{"@value":"Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita 565-0871 Osaka, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021390569893124","@type":"Researcher","foaf:name":[{"@value":"Shoichi Murakami"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Faculty of Science, Osaka Prefecture University, Sakai 599-8531 Osaka, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1420845751149072000","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"20838742"},{"@type":"NRID","@value":"1000020838742"},{"@type":"NRID","@value":"9000406405585"},{"@type":"NRID","@value":"9000403323582"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/kenichi_michigami"}],"foaf:name":[{"@value":"Kenichi Michigami"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Graduate School of Science, Osaka Metropolitan University, Sakai 599-8531 Osaka, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021390569893125","@type":"Researcher","foaf:name":[{"@value":"Sensuke Ogoshi"}],"jpcoar:affiliationName":[{"@value":"Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita 565-0871 Osaka, Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00027863"},{"@type":"EISSN","@value":"15205126"}],"prism:publicationName":[{"@value":"Journal of the American Chemical Society"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"2023-09-26","prism:volume":"145","prism:number":"42","prism:startingPage":"23098","prism:endingPage":"23108"},"reviewed":"false","dc:rights":["https://doi.org/10.15223/policy-029","https://doi.org/10.15223/policy-037","https://doi.org/10.15223/policy-045"],"url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/jacs.3c06331"}],"createdAt":"2023-09-26","modifiedAt":"2023-10-25","project":[{"@id":"https://cir.nii.ac.jp/crid/1040569382228042752","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"21K14632"},{"@type":"JGN","@value":"JP21K14632"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21K14632/"}],"notation":[{"@language":"ja","@value":"触媒の不活性および活性種の不安定性を克服する革新的カルベン触媒の創製"},{"@language":"en","@value":"Development of Novel Carbene Catalysts Unifying Activity and Stability of the Reaction Intermediates"}]},{"@id":"https://cir.nii.ac.jp/crid/1040862776834177152","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"23K26657"},{"@type":"JGN","@value":"JP23K26657"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23K26657/"}],"notation":[{"@language":"ja","@value":"高反応性遷移金属パーフルオロアルコキシド活性種の調製法の創出と分子変換への応用"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050282677616052352","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Nucleophilic 5-endo-trig Cyclization of 3,3-Difluoroallylic Ketone Enolates: Synthesis of 5-Fluorinated 2-Alkylidene-2,3-dihydrofurans"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002216659983360","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Copolymerization of Propylene and Polar Monomers Using Pd/IzQO Catalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002219105846400","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"1-Substituted-imidazo[1,5-<i>a</i>]pyridin-3-ylidenes as Highly Efficient Ligands for Rh- and Ir-catalyzed Transfer Hydrogenation of Carbonyl Compounds"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004229923980544","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Nickel(0)‐Mediated Transformation of Tetrafluoroethylene and Vinylarenes into Fluorinated Cyclobutyl Compounds"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004229925413760","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Fluorinated Vinylsilanes from the Copper‐Catalyzed Defluorosilylation of Fluoroalkene Feedstocks"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011144220385408","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A Cyclic Diaminocarbene with a Pyramidalized Nitrogen Atom: A Stable N‐Heterocyclic Carbene with Enhanced Electrophilicity"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011144490127744","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"An overview of N-heterocyclic carbenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011144835739904","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Reaction of octafluorocyclopentene with various carbon nucleophiles"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011144923202944","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"How Important Is Backbonding in Metal Complexes Containing N‐Heterocyclic Carbenes? Structural and NBO Analysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011145296068608","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Determining the π-Acceptor Properties of N-Heterocyclic Carbenes by Measuring the <sup>77</sup>Se NMR Chemical Shifts of Their Selenium Adducts"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011145553131776","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Steric and Electronic Properties of N-Heterocyclic Carbenes (NHC):  A Detailed Study on Their Interaction with Ni(CO)<sub>4</sub>"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011146320066432","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Copolymerization of fluorinated monomers: recent developments and future trends"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011146638782976","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Cyclic Alkyl(amino) Carbene Stabilized Complexes with Low Coordinate Metals of Enduring Nature"}]},{"@id":"https://cir.nii.ac.jp/crid/1360025431096251520","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Intense fluorescence of air-stable sodium diarylformamidinate: effective control with a novel electron-withdrawing 4-cyano-3,5-bis(trifluoromethyl)phenyl group"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283691637054464","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Copper-Catalyzed Regioselective Monodefluoroborylation of Polyfluoroalkenes en Route to Diverse Fluoroalkenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283691872514048","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Imidazo[1,5-a]pyridin-3-ylidenes as π-accepting carbene ligands: substituent effects on properties of N-heterocyclic carbenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360286993070372224","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Enantioselective Synthesis of Polycyclic γ-Lactams with Multiple Chiral Carbon Centers via Ni(0)-Catalyzed Asymmetric Carbonylative Cycloadditions without Stirring"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292618576991616","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Sterically hindered N-heterocyclic carbene/palladium(<scp>ii</scp>) catalyzed Suzuki–Miyaura coupling of nitrobenzenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292619004738688","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Quinone-Annulated N-Heterocyclic Carbene−Transition-Metal Complexes:  Observation of π-Backbonding Using FT-IR Spectroscopy and Cyclic Voltammetry"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292620929429760","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A Facile Preparation of Imidazolinium Chlorides"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292620989011200","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"An Air Stable Carbene and Mixed Carbene “Dimers”"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292621317367808","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Effective Modulation of the Donor Properties of N-Heterocyclic Carbene Ligands by “Through-Space” Communication within a Planar Chiral Scaffold"}]},{"@id":"https://cir.nii.ac.jp/crid/1360302869447907328","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A new synthetic method for the preparation of protonated-NHCs and related compounds"}]},{"@id":"https://cir.nii.ac.jp/crid/1360302869448202240","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Intramolecular “Hydroiminiumation and -amidiniumation” of Alkenes:  A Convenient, Flexible, and Scalable Route to Cyclic Iminium and Imidazolinium Salts"}]},{"@id":"https://cir.nii.ac.jp/crid/1360302869448414336","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Hydrogen bonding-enabled gold catalysis: ligand effects in gold-catalyzed cycloisomerizations in hexafluoroisopropanol (HFIP)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565164379312256","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Efficient Synthesis of Polycyclic γ‐Lactams by Catalytic Carbonylation of Ene‐Imines via Nickelacycle Intermediates"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565166612302336","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Nickel(0)-Catalyzed [2 + 2 + 1] Carbonylative Cycloaddition of Imines and Alkynes or Norbornene Leading to γ-Lactams"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567179874667136","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Regioselective CF Bond Activation of Hexafluoropropylene on Palladium(0): Formation of a Cationic η<sup>2</sup>‐Perfluoroallylpalladium Complex"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183205356416","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Carbon–Fluorine Bond Activation of Tetrafluoroethylene on Palladium(0) and Nickel(0): Heat or Lewis Acidic Additive Promoted Oxidative Addition"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183725968896","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Nucleophilic 5-endo-trig Cyclization of 3,3-Difluoroallylic Metal Enolates and Enamides: Facile Synthesis of Ring-Fluorinated Dihydroheteroles"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574093861699712","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Palladium-Catalyzed Coupling Reactions of Tetrafluoroethylene with Arylzinc Compounds"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574095516371840","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Anti-Bredt N-heterocyclic carbene: an efficient ligand for the gold(i)-catalyzed hydroamination of terminal alkynes with parent hydrazine"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574096049539584","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Well-Designed <i>N</i>-Heterocyclic Carbene Ligands for Palladium-Catalyzed Denitrative C–N Coupling of Nitroarenes with Amines"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574096424664320","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The Organometallic Chemistry of N‐heterocyclic Carbenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846644027292544","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Transfer Semihydrogenation of Alkynes Catalyzed by Imidazo[1,5-<i>a</i>]pyrid-3-ylidene–Pd Complexes: Positive Effects of Electronic and Steric Features on N-Heterocyclic Carbene Ligands"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848654920558720","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Palladium‐Catalyzed Coupling Reaction of Perfluoroarenes with Diarylzinc Compounds"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848658182020736","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"N-Heterocyclic Carbenes with a<i>N</i>-2,4-Dinitrophenyl Substituent: Comparison with PPh<sub>3</sub>and IPr"}]},{"@id":"https://cir.nii.ac.jp/crid/1360853567793030912","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Direct Transformation of Tetrafluoroethylene to Trifluorovinylzinc via sp<sup>2</sup> C–F Bond Activation"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855568544912000","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855569767246720","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Samb<i>V</i>ca: A Web Application for the Calculation of the Buried Volume of N‐Heterocyclic Carbene Ligands"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855569788369792","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Anatomy of gold catalysts: facts and myths"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855570764718080","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Relativistic effects in homogeneous gold catalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1360857593805288064","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Synthesis and photoluminescence properties of fluorine‐containing poly(phenylene vinylene) bearing hexafluorocyclopentene‐fused phenanthrene unit"}]},{"@id":"https://cir.nii.ac.jp/crid/1360865818475396736","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Optimizing Catalyst and Reaction Conditions in Gold(I) Catalysis–Ligand Development"}]},{"@id":"https://cir.nii.ac.jp/crid/1360865818724399616","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Filling a Niche in “Ligand Space” with Bulky, Electron‐Poor Phosphorus(III) Alkoxides"}]},{"@id":"https://cir.nii.ac.jp/crid/1360865818724401536","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Intramolecular Ring‐Expansion Reaction (RER) and Intermolecular Coordination of In Situ Generated Cyclic (Amino)(aryl)carbenes (cAArCs)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360865818725212928","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"<i>N</i>-Cyclopropenio-imidazol-2-ylidene: An N-heterocyclic carbene bearing an <i>N</i>-cationic substituent"}]},{"@id":"https://cir.nii.ac.jp/crid/1360865820410788096","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Access to a Cationic, Electron-Poor <i>N</i>-Heterocyclic Carbene with a Quinazolinium Core by Postsynthetic Modification of Related Neutral Derivatives"}]},{"@id":"https://cir.nii.ac.jp/crid/1360865820410789376","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Direct Access to IMes<sup>F</sup> and IMes<sup>F<sub>2</sub></sup> by Electrophilic Fluorination of Abnormal N-Heterocyclic Carbenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360865820410951552","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Air stable NHCs: a study of stereoelectronics and metallorganic catalytic activity"}]},{"@id":"https://cir.nii.ac.jp/crid/1360865821077184512","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"What Wanzlick Did Not Dare To Dream: Cyclic (Alkyl)(amino)carbenes (cAACs) as New Key Players in Transition‐Metal Chemistry"}]},{"@id":"https://cir.nii.ac.jp/crid/1360865821078040320","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Synthesis of N-heterocyclic carbene gold(I) complexes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360865821078114560","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Polyhalogenoheterocyclic compounds. Part 38. Reactions of fluorinated-alkenes and -cycloalkenes with difunctional nucleophiles"}]},{"@id":"https://cir.nii.ac.jp/crid/1360865821078123776","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Transformation of Tetrafluoroethylene Using Transition-Metal Complexes"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137044138792704","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"THE REACTION OF METHOXIDE ION WITH PERFLUOROCYCLOPENTENE"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137044675299968","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"An <i>N</i>,<i>N</i>′-Diamidocarbene: Studies in C−H Insertion, Reversible Carbonylation, and Transition-Metal Coordination Chemistry"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137045233931904","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Silver-free Gold(I) Catalysts for Organic Transformations"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137045447020544","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Quantifying and understanding the electronic properties of N-heterocyclic carbenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1361412893389985792","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Pd/NHC-catalyzed cross-coupling reactions of nitroarenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418519712339456","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Gold Catalysis:  Mild Conditions for the Synthesis of Oxazoles from <i>N</i>-Propargylcarboxamides and Mechanistic Aspects"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418519716843392","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Perfluorocyclopentenyl (PFCP) Aryl Ether Polymers via Polycondensation of Octafluorocyclopentene with Bisphenols"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699993469563520","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Ruthenium- and gold-catalysed sequential reactions: a straightforward synthesis of substituted oxazoles from propargylic alcohols and amides"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981470757034624","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Imidazolylidenes, imidazolinylidenes and imidazolidines"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981471216129664","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Direct Measure of Metal–Ligand Bonding Replacing the Tolman Electronic Parameter"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262943877289472","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Hyflon Ion Membranes for Fuel Cells"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262944026329856","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Gold-Catalyzed Organic Reactions"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262944092492544","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Cyclic (Alkyl)- and (Aryl)-(amino)carbene Coinage Metal Complexes and Their Applications"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262944623586560","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Imidazo[1,5-a]pyridine-3-ylidenes—pyridine derived N-heterocyclic carbene ligands"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262944724134016","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"N-Heterocyclic Carbenes in Late Transition Metal Catalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262945644968064","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Heterocyclic Carbenes: Synthesis and Coordination Chemistry"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262945668158208","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Imidazo[1,5-a]pyridine:  A Versatile Architecture for Stable N-Heterocyclic Carbenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544419427694080","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Electronic Properties of N-Heterocyclic Carbenes and Their Experimental Determination"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825894438976256","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Quantifying and understanding the steric properties of N-heterocyclic carbenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825895398120960","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"N-Heterocyclic Carbenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107369511246848","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107370020181376","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"N-Heterocyclic carbenes: deducing σ- and π-contributions in Rh-catalyzed hydroboration and Pd-catalyzed coupling reactions"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107370102602240","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Insights into the Catalytic Activity of [Pd(NHC)(cin)Cl] (NHC=IPr, IPr<sup>Cl</sup>, IPr<sup>Br</sup>) Complexes in the Suzuki–Miyaura Reaction"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107370256343680","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Exploring the Coordination of Cyclic Selenoureas to Gold(I)"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107370461871360","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Highly Electrophilic, Catalytically Active and Redox‐Responsive Cobaltoceniumyl and Ferrocenyl Triazolylidene Coinage Metal Complexes"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107370659864320","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Chemistry of trifluorostyrenes and their dimers: 2. Synthesis of substituted α, β, β-trifluorostyrenes and α, β, β-trifluoroethenylnaphthalenes. Hammett correlations of their NMR parameters and the concept of “distorted π-electron clouds”"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107371158351360","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Cyclic (Amino)(aryl)carbenes (CAArCs) as Strong σ‐Donating and π‐Accepting Ligands for Transition Metals"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107371170519680","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Room temperature hydroamination of alkynes with anilines catalyzed by anti-Bredt di(amino)carbene gold(<scp>i</scp>) complexes"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107371175793408","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A Ruthenium Catalyst for Olefin Metathesis Featuring an Anti‐Bredt N‐Heterocyclic Carbene Ligand"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388843714454016","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Gold Catalysis: Isolation of Vinylgold Complexes Derived from Alkynes"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388843855455872","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The Nucleophilic 5<i>-endo-trig</i> Cyclization of 1,1<i>-</i>Difluoro-1-alkenes: Ring-Fluorinated \nHetero- and Carbocycle Synthesis and Remarkable Effect of \nthe Vinylic Fluorines on the Disfavored Process"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388844651512960","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Steric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388845767801728","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Stable Cyclic (Alkyl)(Amino)Carbenes as Rigid or Flexible, Bulky, Electron‐Rich Ligands for Transition‐Metal Catalysts: A Quaternary Carbon Atom Makes the Difference"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670318464064384","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Skeleton Decoration of NHCs by Amino Groups and its Sequential Booster Effect on the Palladium‐Catalyzed Buchwald–Hartwig Amination"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670319798040576","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951793298415104","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Preparation of tetrafluoroethylene from the pyrolysis of pentafluoropropionate salts"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951793796897920","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"An [(NHC)(NHC<sub>EWG</sub>)RuCl<sub>2</sub>(CHPh)] Complex for the Efficient Formation of Sterically Hindered Olefins by Ring‐Closing Metathesis"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951794762234368","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Synthesis and Characterization of<i>N</i>-Trifluoromethyl N-Heterocyclic Carbene Ligands and Their Complexes"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951794777656832","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"SambVca 2. A Web Tool for Analyzing Catalytic Pockets with Topographic Steric Maps"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951795929572992","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Steering the Surprisingly Modular π‐Acceptor Properties of N‐Heterocyclic Carbenes: Implications for Gold Catalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233268560393728","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"An N-Heterocyclic Carbene Ligand with an Oxalamide Backbone"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233269306586624","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Intramolecular “Hydroiminiumation” of Alkenes: Application to the Synthesis of Conjugate Acids of Cyclic Alkyl Amino Carbenes (CAACs)"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233269656434304","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Gold-Catalyzed Organic Transformations"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233270507629184","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Elimination Reaction of Fluoroölefins with Organolithium Compounds"}]},{"@id":"https://cir.nii.ac.jp/crid/2050025942153333632","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Imidazo[1,5-a]pyridinylidenes as π-accepting NHC ligands in catalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/2051433317034566656","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Silver-free catalysis with gold(Ⅰ) chloride complexes"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1021/jacs.3c06331"},{"@type":"KAKEN","@value":"PRODUCT-25298431"},{"@type":"KAKEN","@value":"PRODUCT-24792875"},{"@type":"OPENAIRE","@value":"doi_________::5df621af4477d166ea2893a648e50ca4"},{"@type":"CROSSREF","@value":"10.1039/d4tc03533j_references_DOI_YAbPkc1QrcoV7Dz9ABWh8howX4T"}]}