{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360021390574802688.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.3390/min14030259"}},{"identifier":{"@type":"URI","@value":"https://www.mdpi.com/2075-163X/14/3/259/pdf"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Experimental Hydrothermal Alteration of Rhyolite and Andesite at 325 °C and 300 Bar: Implications for a Potential Role of Volcanic Glass in the Fluid Composition in the Okinawa Trough"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>The experimental study of water–rock reactions under high-temperature and -pressure conditions is a useful approach to constrain controlling factors of the fluid composition in a natural hydrothermal system. Previous studies have focused mainly on the mid-ocean ridge fields, and the hydrothermal alteration of intermediate-to-felsic rocks has been less emphasized despite its potential importance in the fluid chemistry in an arc/back-arc basin setting. We examined the alteration processes of fresh rhyolite and andesite rocks collected from the middle and southern Okinawa Trough, respectively, at 325 °C and 300 bar (the estimated condition at the reaction zone in the fields), especially focusing on the behavior of silica between the solid and liquid phases. The experimental fluids are characterized by the high Si concentration up to 30 mM, indicating the substantial dissolution of volcanic glass in the analyzed rocks. The high Si concentration in the fluids was presumably buffered by amorphous silica, precipitated from the fluids as a precursor of hydrothermal quartz, during the experiments. Our results emphasize a previously overlooked role of volcanic glass/amorphous silica in the fluid composition in the Okinawa Trough and are consistent with the previous model of pumice replacement mineralization for the SMS deposit formation in the trough.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380021390574802841","@type":"Researcher","foaf:name":[{"@value":"Masafumi Saitoh"}],"jpcoar:affiliationName":[{"@value":"Ore Genesis Research Unit, Project Team for Development of New-Generation Research Protocol for Submarine Resources, Japan Agency for Marine-Earth Science & Technology (JAMSTEC), 2-15 Natsushima-cho, Yokosuka 237-0061, Japan"},{"@value":"Research and Development (R&D) Center for Submarine Resources, Japan Agency for Marine-Earth Science and Technology (JAMSTEC), 2-15 Natsushima-cho, Yokosuka 237-0061, Japan"},{"@value":"The University Museum, The University of Tokyo, Hongo, Tokyo 113-0033, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021390574802690","@type":"Researcher","foaf:name":[{"@value":"Takazo Shibuya"}],"jpcoar:affiliationName":[{"@value":"Ore Genesis Research Unit, Project Team for Development of New-Generation Research Protocol for Submarine Resources, Japan Agency for Marine-Earth Science & Technology (JAMSTEC), 2-15 Natsushima-cho, Yokosuka 237-0061, Japan"},{"@value":"Research and Development (R&D) Center for Submarine Resources, Japan Agency for Marine-Earth Science and Technology (JAMSTEC), 2-15 Natsushima-cho, Yokosuka 237-0061, Japan"},{"@value":"Institute for Extra-Cutting-Edge Science and Technology Avant-Garde Research (X-Star), Super-Cutting-Edge Grand and Advanced Research (SUGAR) Program, Japan Agency for Marine-Earth Science and Technology (JAMSTEC), Natsushima-cho, Yokosuka 237-0061, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021390574802824","@type":"Researcher","foaf:name":[{"@value":"Takuya Saito"}],"jpcoar:affiliationName":[{"@value":"Institute for Extra-Cutting-Edge Science and Technology Avant-Garde Research (X-Star), Super-Cutting-Edge Grand and Advanced Research (SUGAR) Program, Japan Agency for Marine-Earth Science and Technology (JAMSTEC), Natsushima-cho, Yokosuka 237-0061, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021390574802692","@type":"Researcher","foaf:name":[{"@value":"Junji Torimoto"}],"jpcoar:affiliationName":[{"@value":"Ore Genesis Research Unit, Project Team for Development of New-Generation Research Protocol for Submarine Resources, Japan Agency for Marine-Earth Science & Technology (JAMSTEC), 2-15 Natsushima-cho, Yokosuka 237-0061, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021390574802851","@type":"Researcher","foaf:name":[{"@value":"Hisahiro Ueda"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Gakushuin University, 1-5-1 Mejiro, Toshima, Tokyo 171-8588, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021390574802832","@type":"Researcher","foaf:name":[{"@value":"Tomoki Sato"}],"jpcoar:affiliationName":[{"@value":"Volcanoes and Earth’s Interior Research Center (VERC), Research Institute for Marine Geodynamics (IMG), Japan Agency for Marine-Earth Science and Technology (JAMSTEC), 2-15 Natsushima-cho, Yokosuka 237-0061, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021390574802831","@type":"Researcher","foaf:name":[{"@value":"Katsuhiko Suzuki"}],"jpcoar:affiliationName":[{"@value":"Ore Genesis Research Unit, Project Team for Development of New-Generation Research Protocol for Submarine Resources, Japan Agency for Marine-Earth Science & Technology (JAMSTEC), 2-15 Natsushima-cho, Yokosuka 237-0061, Japan"},{"@value":"Research and Development (R&D) Center for Submarine Resources, Japan Agency for Marine-Earth Science and Technology (JAMSTEC), 2-15 Natsushima-cho, Yokosuka 237-0061, Japan"},{"@value":"Research Institute for Marine 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